Synthesis, characterization, antibacterial and photocatalytic performance of Ag/AgI/TiO2 hollow sphere composites

Dispersed TiO2 hollow spheres were successfully prepared which was obtained via Ostwald ripening under solvothermal conditions without any templates or surfactants. Then, the AgI/TiO2 was synthesized by the deposition-precipitation process. Finally, Ag/AgI/TiO2 was obtained by a photocatalytic reduction way. Their characteristics were analyzed by XRD, SEM, HRTEM, N2 adsorption-desorption measurements and UV-vis absorption spectra. To demonstrate the potential applications of such composites, their antibacterial activity against Escherichia coli (E. coli) was studied by microcalorimetry for the first time, and their photocatalytic performance for degradation of different organic dyes under simulated UV and visible light was discussed. The results indicated that Ag/AgI/TiO2 hollow spheres revealed elevated antibacterial and photocatalytic activity because of their unique morphology, hollow structure and high surface area. The mechanism of the excellent antibacterial and photocatalytic activity of Ag/AgI/TiO2 hollow spheres are discussed which are attributed to the synergetic effect of Ag, AgI and TiO2. It suggested that the new Ag/AgI/TiO2 photocatalyst has broad application prospects in solar cell, sensor, antibacterial, catalysis and nanotechnology.

Construction of ternary heterojunction Agl/C-MoS_(2) nanosheets with enhanced visible-light photocatalytic property and self-cleaning performance

Carbon-molybdenum disulfide(C-MoS_(2))ultrathin nanosheets were prepared by a hydrothermal process,and then Agl/C-MoS_(2) were synthesized via an/n-situ deposition method.This ternary heterojunction composite exhibited better photo-catalytic activity compared with those of one-component(pristine MoS_(2))and bicomponent(Agl/MoS_(2) and C-MoS_(2))materials for the degradation of organic dyes under the visible-light irradiation.In particular,by comparing with Agl/MoS_(2),the significant role of conductive amorphous carbon in Agl/C-MoS_(2) in enhancing the charge transfer during the photocatalytic degradation of dyes was first confirmed by photocurrent response and electrochemical impedance spectroscopy(EIS).A possible photocatalytic mechanism was proposed based on the capture experiment results.Furthermore,a straightforward and interesting way had been applied to test the recycled/newly-prepared Agl/C-MoS_(2) composite for revealing its distinctive self-cleaning performance and recyclability characteristic besides its good photocatalytic activity.This work could provide a reference for the design of other new ternary heterojunction composite materials with special structures and properties.