Reinforcing fillers are of great importance in tribological performance and tribofilm formation of polymeric composites.In this study,the tribological properties of aramid particle(AP)and short carbon fiber(SCF)reinfo...Reinforcing fillers are of great importance in tribological performance and tribofilm formation of polymeric composites.In this study,the tribological properties of aramid particle(AP)and short carbon fiber(SCF)reinforced polyimide(PI)composites were added to hexagonal boron nitride(h-BN),and silica(SiO_(2))nanoparticles sliding against alumina were comprehensively investigated.When sliding occurred with AP-reinforced PI composites,the tribological properties were not closely depended on the pressure×velocity(p×v)factors and the nanoparticles.The interactions between AP and its counterpart could not induce tribo-sintering of the transferred wear debris.As such,the tribofilm seemed to be in a viscous state,leading to higher friction and wear.However,the inclusion of hard SCF into the PI matrix changed the interfacial interactions with alumina.A robust tribofilm consisting of a high fraction of silica was generated when the SCF-reinforced PI was added to the SiO_(2) nanoparticles.It exhibited a high load-carrying capability and was easily sheared.This caused a significant decrease in the friction and wear of the PI composite at 8 MPa·1m/s.Moreover,due to their high melting point,few h-BN nanoparticles were observed in the tribofilm of the SCF-reinforced PI when hexagonal boron nitride was added.展开更多
基金The authors are grateful for the financial support received from National Natural Science Foundation of China(Grant Nos.51475446 and 51975492)the Research Foundation of Southwest University of Science and Technology(Grant Nos.18zx7162 and 18zx7125)Sichuan Science and Technology Program(Grant No.18YYJC0905).
文摘Reinforcing fillers are of great importance in tribological performance and tribofilm formation of polymeric composites.In this study,the tribological properties of aramid particle(AP)and short carbon fiber(SCF)reinforced polyimide(PI)composites were added to hexagonal boron nitride(h-BN),and silica(SiO_(2))nanoparticles sliding against alumina were comprehensively investigated.When sliding occurred with AP-reinforced PI composites,the tribological properties were not closely depended on the pressure×velocity(p×v)factors and the nanoparticles.The interactions between AP and its counterpart could not induce tribo-sintering of the transferred wear debris.As such,the tribofilm seemed to be in a viscous state,leading to higher friction and wear.However,the inclusion of hard SCF into the PI matrix changed the interfacial interactions with alumina.A robust tribofilm consisting of a high fraction of silica was generated when the SCF-reinforced PI was added to the SiO_(2) nanoparticles.It exhibited a high load-carrying capability and was easily sheared.This caused a significant decrease in the friction and wear of the PI composite at 8 MPa·1m/s.Moreover,due to their high melting point,few h-BN nanoparticles were observed in the tribofilm of the SCF-reinforced PI when hexagonal boron nitride was added.
