Metal halide perovskites have recently emerged as promising candidates for the next generation of X-ray detectors due to their excellent optoelectronic properties.Especially,two-dimensional(2D)perovskites afford many ...Metal halide perovskites have recently emerged as promising candidates for the next generation of X-ray detectors due to their excellent optoelectronic properties.Especially,two-dimensional(2D)perovskites afford many distinct properties,including remarkable structural diversity,high generation energy,and balanced large exciton binding energy.With the advantages of 2D materials and perovskites,it successfully reduces the decomposition and phase transition of perovskite and effectively suppresses ion migration.Meanwhile,the existence of a high hydrophobic spacer can block water molecules,thus making 2D perovskite obtain excellent stability.All of these advantages have attracted much attention in the field of X-ray detection.This review introduces the classification of 2D halide perovskites,summarizes the synthesis technology and performance characteristics of 2D perovskite X-ray direct detector,and briefly discusses the application of 2D perovskite in scintillators.Finally,this review also emphasizes the key challenges faced by 2D perovskite X-ray detectors in practical application and presents our views on its future development.展开更多
Tin halide perovskites(THPs)have received extensive attention due to their low toxicity and excellent optoelectronic properties,and are considered to be the most promising alternatives to develop efficient lead-free p...Tin halide perovskites(THPs)have received extensive attention due to their low toxicity and excellent optoelectronic properties,and are considered to be the most promising alternatives to develop efficient lead-free perovskite solar cells.However,due to the unique and inherent characteristics of Sn^(2+)being easily oxidized to Sn^(4+)and fast crystallization,tin perovskite solar cells(TPSCs)show relatively poor performance and stability,compared to the lead counterparts.Recently,the introduction of bulky organic spacers into three-dimensional(3D)THPs for dimensional regulation can not only prevent the intrusion of water and oxygen,but also inhibit the self-doping effect and ion migration.In this review,we will detail how dimensional regulation enables TPSCs with high performance and superior stability.First,we summarize the intrinsic properties of THPs and analyze the root causes of their poor performance and instability.Next,we discuss the specific structure and types of the dimensional regulation strategy.Then,the mechanism of dimensional regulation is discussed in detail,mainly from inhibiting the Sn^(2+)oxidation,optimizing crystallization,passivating defects,and improving energy level alignment.Finally,future challenges and prospects for dimensional regulation are elaborated to help researchers develop more efficient and stable TPSCs.展开更多
The rapid development of low-bandgap(LBG)nonfullerene acceptors and wide-bandgap(WBG)copolymer donors in recent years has boosted the power conversion efficiency(PCE)of organic solar cells(OSCs)to the 18%level[1−21].T...The rapid development of low-bandgap(LBG)nonfullerene acceptors and wide-bandgap(WBG)copolymer donors in recent years has boosted the power conversion efficiency(PCE)of organic solar cells(OSCs)to the 18%level[1−21].The commercialization of OSCs is highly expected.However,critical issues like the cost and the stability also determine whether OSCs can enter the market or not[22].展开更多
By designing and fabricating thin film electronic devices on a flexible substrate instead of more commonly used rigid substrate, flexible electronics produced has opened a field of special applications. In this articl...By designing and fabricating thin film electronic devices on a flexible substrate instead of more commonly used rigid substrate, flexible electronics produced has opened a field of special applications. In this article, we first reviewed available products that may be used as flexible substrates, their characteristics and unique advantages as supporting material for flexible electronic devices. Secondly, flexible perovskite solar cell is examined in detail, with special focus on its potential large-scale fabrication processes. In particular, a comprehensive review is provided on low cost solution printing techniques that is viewed highly as a viable tool for potential commercialization of the perovskite solar cells. Furthermore, a summary is given on green processing for the solution printing production of flexible perovskite devices.展开更多
Pectobacterium carotovorum is the causal agent of bacterial soft rot in a wide range of vegetable host species.Once P.carotovorum infects the plant,the spread of the disease is difficult to control.In this study,a rap...Pectobacterium carotovorum is the causal agent of bacterial soft rot in a wide range of vegetable host species.Once P.carotovorum infects the plant,the spread of the disease is difficult to control.In this study,a rapid and sensitive method based on loop-mediated isothermal amplification(LAMP)was developed for detecting P.carotovorum in celery with soft rot using a primer set designed from the pmrA conserved sequence of P.carotovorum.The specificity of the LAMP primer set for P.carotovorum was extensively validated on both P.carotovorum strains and nontarget strains.The sensitivity was 1 pg of P.carotovorum genomic DNA,which demonstrated 10 times more sensitive than the conventional PCR assay.LAMP was also used to detect P.carotovorum in bacterial suspension.The lowest detection concentration was 104 CFU·mL^−1.In addition,a LAMP assay,in conjunction with a crude DNA extraction method,was successfully performed on P.carotovorum-infected samples derived from both artificially and naturally infected plants.In summary,the LAMP assay established in this study constitutes a simple,sensitive,and rapid method for the detection of P.carotovorum,and has potential application in the control of celery soft rot disease through early detection.展开更多
Perovskite materials have made a great progress in terms of the power conversion efficiency(PCE), rising from 3.8% to 25.2%. To obtain pinhole-free, superior crystal, and high-quality perovskite films with less defect...Perovskite materials have made a great progress in terms of the power conversion efficiency(PCE), rising from 3.8% to 25.2%. To obtain pinhole-free, superior crystal, and high-quality perovskite films with less defect, intermediates transformation is important, which has been clearly studied and widely applied.In this review, we systematically summarize the commonly formed intermediates and detailedly analyze their mechanisms from five aspects:(1) Solvent-induced intermediate;(2) HI-induced intermediate;(3)CH3NH2-induced intermediate;(4) MAAc-induced intermediate;(5) other intermediates. Finally, we also provide some prospects on high-quality perovskite fabrication based on using intermediates prudently.展开更多
The rapid rise in the power conversion efficiency(PCE)of CsPbBr_(2)I-based perovskite solar cells(PSCs),from 4.7%in 2016 to 11.08%in 2020,render it a promising material for use in photovoltaic devices.However,the phas...The rapid rise in the power conversion efficiency(PCE)of CsPbBr_(2)I-based perovskite solar cells(PSCs),from 4.7%in 2016 to 11.08%in 2020,render it a promising material for use in photovoltaic devices.However,the phase stability and current hysteresis caused by photo-induced phase segregation in CsPbBr_(2)I represent major obstacles to further improvements in the PCE for such devices.In this review,we describe the basic structure and optical properties of CsPbBr_(2)I,and systematically elaborate on the mechanism of the phase transition.We then discuss the strategies in progress to suppress phase transition in CsPbBr_(2)I,and their potential application in the photovoltaic field.Finally,challenges and application prospects for CsPbBr2I PSCs are summarized in the final section of this article.展开更多
Recently,perovskite solar cells(PSCs) have flourished,and their power conversion efficiency(PCE) has increased from the initial 3.8% to 25.2% in 2019,which is an unprecedented advance.However,usually high-efficiency a...Recently,perovskite solar cells(PSCs) have flourished,and their power conversion efficiency(PCE) has increased from the initial 3.8% to 25.2% in 2019,which is an unprecedented advance.However,usually high-efficiency and stable PSCs are small-area devices prepared by spin coating.This method is not suitable for the preparation of large-area devices in commercialization.Therefore,there is an urgent need to develop new materials and methods for the scalable fabrication of PSCs.In this review,we first describe the common small-area PSCs preparation methods,understand the nucleation and crystal growth kinetics of perovskite,and analyze the reasons that hinder the development of small-area devices to large-area devices.Next,in order to meet the challenges of PSC’s scalable fabrication,we summarize and analyze four strategies:scaling up precursor solutions,scalable deposition methods for large-area films,scaling up charge-transport layers and back electrodes,developing solar modules.Finally,challenges and prospects are proposed to help researchers prepare high-efficiency large-area PSCs.展开更多
Nowadays,inorganic CsPbI3 perovskite solar cells(PSCs)have become one of the most attractive research hotspots in photovoltaic field for its superior chemical stability and excellent photo-electronic properties.Since ...Nowadays,inorganic CsPbI3 perovskite solar cells(PSCs)have become one of the most attractive research hotspots in photovoltaic field for its superior chemical stability and excellent photo-electronic properties.Since the first independent report in 2015,the power conversion efficiency(PCE)of CsPbI3 based PSCs has sharply increased from 3.9%to 19.03%.Importantly,during the developing process of CsPbI3 PSCs,HI hydrolysis-derived intermediate plays an important role:from stabilizing the crystal structure,optimizing the fabricated film to boosting the device performance.In this review,the different crystal and electronic structures of CsPbI3 are introduced.We then trace the history and disputes of HI hydrolysis-derived intermediate to make this review more logical.Meanwhile,we highlight the functions of HI hydrolysis-derived intermediate,and systematically summarize the advanced works on CsPbI3 PSCs.Finally,the bottlenecks and prospects are revealed to further increase the CsPbI3 PSCs performance.展开更多
To better utilize the infrared(IR)region in sunlight for photovoltaic devices(PVs),upconversion nanoparticles(UCNPs)have been proposed to improve power conversion efficiency(PCE).However,researchers recently have foun...To better utilize the infrared(IR)region in sunlight for photovoltaic devices(PVs),upconversion nanoparticles(UCNPs)have been proposed to improve power conversion efficiency(PCE).However,researchers recently have found that the upconversion(UC)effect is negligible in PVs performance improvement for their ultra-low UC photoluminescence quantum yields of UCNPs solid film,while the real mechanism of UCNPs in PVs has not been clearly studied.Herein,based on the material inorganic perovskitesγ-CsPbI_(3),NaYF_(4):20%Yb^(3+),2%Er^(3+)UCNPs were integrated into different transport layer to optimize device performance.Compared with reference device,the short-circuit current density and PCE of optimized device reached 20.87 mA/cm^(2)(20.39 mA/cm^(2))and 18.34%(17.72%),respectively,without sacrificing open-circuit voltage and filling factor.Further experimental characterizations verified that the improved performance was attributable to enhanced visible light absorption instead of IR.To theoretically explain the statement,the light field distribution in device was simulated and the absorption in different layers was calculated.The results revealed that the introduction of UCNPs with different refractive index from other layers caused light field disturbance,and improved visible light captured by γ-CsPbI_(3).Importantly,through experiments and theoretical calculation,the research deeply explored the potential mechanism of UCNPs in optimizing PVs performance.展开更多
Perovskite quantum-dots (PQDs) have emerged as prominent candidates for intriguing photovoltaic application due to their superior optoelectronic properties such as multiple exciton generation, bandgap tunability, elec...Perovskite quantum-dots (PQDs) have emerged as prominent candidates for intriguing photovoltaic application due to their superior optoelectronic properties such as multiple exciton generation, bandgap tunability, electronic and surface chemistry properties, as well as flexible composition [1–5].展开更多
Bandgap-graded materials present varying spectral responses at different positions,making them possible to be used as an alternative to photoactive materials array in multi-spectral responsive devices,thus miniaturizi...Bandgap-graded materials present varying spectral responses at different positions,making them possible to be used as an alternative to photoactive materials array in multi-spectral responsive devices,thus miniaturizing the apparatus.However,the preparation of bandgap-graded materials usually requires complicated deposition process.Here we report a facile lowtemperature solution process to make films with lateral bandgap gradients,which form spontaneously via self-spreading and interdiffusion of solutions.We show lead halide perovskite films with MAPbCl_(3)-MAPbBr_(3)and MAPbBr_(3)-MAPbI_(3)gradients,which exhibit light absorption onsets ranging from 410 to 781 nm.The bandgap-graded films were used to make self-powered multiband photodetectors,which show different spectral responses at different positions without applying bias voltage.Furthermore,self-powered spectrometers were made by using the multiband photodetectors.展开更多
Organic solar cells have attracted academic and industrial interests due to the advantages like lightweight,flexibility and roll-to-roll fabrication.Nowadays,18%power conversion efficiency has been achieved in the sta...Organic solar cells have attracted academic and industrial interests due to the advantages like lightweight,flexibility and roll-to-roll fabrication.Nowadays,18%power conversion efficiency has been achieved in the state-of-the-art organic solar cells.The recent rapid progress in organic solar cells relies on the continuously emerging new materials and device fabrication technologies,and the deep understanding on film morphology,molecular packing and device physics.Donor and acceptor materials are the key materials for organic solar cells since they determine the device performance.The past 25 years have witnessed an odyssey in developing high-performance donors and acceptors.In this review,we focus on those star materials and milestone work,and introduce the molecular structure evolution of key materials.These key materials include homopolymer donors,D-A copolymer donors,A-D-A small molecular donors,fullerene acceptors and nonfullerene acceptors.At last,we outlook the challenges and very important directions in key materials development.展开更多
Recently,great progress has been made in organic solar cells due to the emergence of high-performance nonfullerene acceptors[1-6].Over 16%and 17%power conversion efficiencies(PCEs)were achieved for nonfullerene-accept...Recently,great progress has been made in organic solar cells due to the emergence of high-performance nonfullerene acceptors[1-6].Over 16%and 17%power conversion efficiencies(PCEs)were achieved for nonfullerene-acceptor-based single-junction and tandem cells,respectively[7,8].Owing to complementary light absorption,wide-bandgap donor-acceptor(D-A)copolymers are ideal electron-donating partners for nonfullerene acceptors.However,efficient D-A copolymer donors are still limited.展开更多
Organic-inorganic halide perovskite (ABX3) solar cells (PSCs)have made great progress in recent years [1]. The power conversion efficiency (PCE) has increased up to 25.2%(NREL Best Research-Cell Efficiency Chart, http...Organic-inorganic halide perovskite (ABX3) solar cells (PSCs)have made great progress in recent years [1]. The power conversion efficiency (PCE) has increased up to 25.2%(NREL Best Research-Cell Efficiency Chart, https://www.nrel.gov/pv/cell-efficiency.html, Accessed August 2019). However, they suffer from poor thermal stability due to the volatile A-site organic cations.展开更多
基金This work was funded by the National Natural Science Foundation of China(22279049 and 12247101)the Fundamental Research Funds for the Central Universities(lzujbky-2021-it31,lzujbky-2021-ct15 and lzujbky-2021-sp69)+1 种基金the calculation work was supported by Supercomputing Center of Lanzhou Universitythe Gansu Province Outstanding Doctoral Student Program(22JR5RA435).
文摘Metal halide perovskites have recently emerged as promising candidates for the next generation of X-ray detectors due to their excellent optoelectronic properties.Especially,two-dimensional(2D)perovskites afford many distinct properties,including remarkable structural diversity,high generation energy,and balanced large exciton binding energy.With the advantages of 2D materials and perovskites,it successfully reduces the decomposition and phase transition of perovskite and effectively suppresses ion migration.Meanwhile,the existence of a high hydrophobic spacer can block water molecules,thus making 2D perovskite obtain excellent stability.All of these advantages have attracted much attention in the field of X-ray detection.This review introduces the classification of 2D halide perovskites,summarizes the synthesis technology and performance characteristics of 2D perovskite X-ray direct detector,and briefly discusses the application of 2D perovskite in scintillators.Finally,this review also emphasizes the key challenges faced by 2D perovskite X-ray detectors in practical application and presents our views on its future development.
基金financially supported by the National Natural Science Foundation of China(51702038)the Science&Technology Department of Sichuan Province(2020YFG0061)+2 种基金the Recruitment Program for Young Professionalsthe National Key Research and Development Program of China(2017YFA0206600)the National Natural Science Foundation of China(51773045,21772030,51922032,21961160720)for financial support。
文摘Tin halide perovskites(THPs)have received extensive attention due to their low toxicity and excellent optoelectronic properties,and are considered to be the most promising alternatives to develop efficient lead-free perovskite solar cells.However,due to the unique and inherent characteristics of Sn^(2+)being easily oxidized to Sn^(4+)and fast crystallization,tin perovskite solar cells(TPSCs)show relatively poor performance and stability,compared to the lead counterparts.Recently,the introduction of bulky organic spacers into three-dimensional(3D)THPs for dimensional regulation can not only prevent the intrusion of water and oxygen,but also inhibit the self-doping effect and ion migration.In this review,we will detail how dimensional regulation enables TPSCs with high performance and superior stability.First,we summarize the intrinsic properties of THPs and analyze the root causes of their poor performance and instability.Next,we discuss the specific structure and types of the dimensional regulation strategy.Then,the mechanism of dimensional regulation is discussed in detail,mainly from inhibiting the Sn^(2+)oxidation,optimizing crystallization,passivating defects,and improving energy level alignment.Finally,future challenges and prospects for dimensional regulation are elaborated to help researchers develop more efficient and stable TPSCs.
基金We thank the National Key Research and Development Program of China(2017YFA0206600)the National Natural Science Foundation of China(51773045,21772030,51922032,21961160720,62074022)+1 种基金Fundamental Research Funds for the Central Universities(2020CDJQY-A055)the Youth Association for Promoting Innovation(CAS)for financial support.
文摘The rapid development of low-bandgap(LBG)nonfullerene acceptors and wide-bandgap(WBG)copolymer donors in recent years has boosted the power conversion efficiency(PCE)of organic solar cells(OSCs)to the 18%level[1−21].The commercialization of OSCs is highly expected.However,critical issues like the cost and the stability also determine whether OSCs can enter the market or not[22].
基金the financial support of the National Key Research and Development Project funding from the Ministry of Science and Technology of China(Grants Nos.2016YFA0202400and 2016YFA0202404)the Peacock Team Project funding from Shenzhen Science and Technology Innovation Committee(Grant No.KQTD2015033110182370)
文摘By designing and fabricating thin film electronic devices on a flexible substrate instead of more commonly used rigid substrate, flexible electronics produced has opened a field of special applications. In this article, we first reviewed available products that may be used as flexible substrates, their characteristics and unique advantages as supporting material for flexible electronic devices. Secondly, flexible perovskite solar cell is examined in detail, with special focus on its potential large-scale fabrication processes. In particular, a comprehensive review is provided on low cost solution printing techniques that is viewed highly as a viable tool for potential commercialization of the perovskite solar cells. Furthermore, a summary is given on green processing for the solution printing production of flexible perovskite devices.
基金the earmarked fund for Beijing Innovation Consortium of Agriculture Research System(Grant No.BAIC-2019)Key Laboratory of Biology and Genetic Improvement of Horticultural Crops,Ministry of Agriculture,P.R.China,and Science and Technology Innovation Program of the Chinese Academy of Agricultural Sciences(Grant No.CAAS-ASTIPIVFCAAS).
文摘Pectobacterium carotovorum is the causal agent of bacterial soft rot in a wide range of vegetable host species.Once P.carotovorum infects the plant,the spread of the disease is difficult to control.In this study,a rapid and sensitive method based on loop-mediated isothermal amplification(LAMP)was developed for detecting P.carotovorum in celery with soft rot using a primer set designed from the pmrA conserved sequence of P.carotovorum.The specificity of the LAMP primer set for P.carotovorum was extensively validated on both P.carotovorum strains and nontarget strains.The sensitivity was 1 pg of P.carotovorum genomic DNA,which demonstrated 10 times more sensitive than the conventional PCR assay.LAMP was also used to detect P.carotovorum in bacterial suspension.The lowest detection concentration was 104 CFU·mL^−1.In addition,a LAMP assay,in conjunction with a crude DNA extraction method,was successfully performed on P.carotovorum-infected samples derived from both artificially and naturally infected plants.In summary,the LAMP assay established in this study constitutes a simple,sensitive,and rapid method for the detection of P.carotovorum,and has potential application in the control of celery soft rot disease through early detection.
基金funded by the National Natural Science Foundation of China (51902148, 61704099, 51801088 and 11664001)the Fundamental Research Funds for the Central Universities (lzujbky-2020-61, lzujbky-2019-88 and lzujbky-2020-kb06)the Special Funding for Open and Shared Large-Scale Instruments and Equipments of Lanzhou University (LZU-GXJJ-2019C023 and LZU-GXJJ-2019C019)。
文摘Perovskite materials have made a great progress in terms of the power conversion efficiency(PCE), rising from 3.8% to 25.2%. To obtain pinhole-free, superior crystal, and high-quality perovskite films with less defect, intermediates transformation is important, which has been clearly studied and widely applied.In this review, we systematically summarize the commonly formed intermediates and detailedly analyze their mechanisms from five aspects:(1) Solvent-induced intermediate;(2) HI-induced intermediate;(3)CH3NH2-induced intermediate;(4) MAAc-induced intermediate;(5) other intermediates. Finally, we also provide some prospects on high-quality perovskite fabrication based on using intermediates prudently.
基金the National Natural Science Foundation of China(52073131,51902148,61704099,61874166,U1832149,51801088 and 51802024)the Natural Science Foundation of Gansu Province(20JR5RA227,20JR5RA217,20JR5RA278)the Fundamental Research Funds for the Central Universities(lzujbky-2020-61,lzujbky-2019-88 and lzujbky-2020-kb06).
文摘The rapid rise in the power conversion efficiency(PCE)of CsPbBr_(2)I-based perovskite solar cells(PSCs),from 4.7%in 2016 to 11.08%in 2020,render it a promising material for use in photovoltaic devices.However,the phase stability and current hysteresis caused by photo-induced phase segregation in CsPbBr_(2)I represent major obstacles to further improvements in the PCE for such devices.In this review,we describe the basic structure and optical properties of CsPbBr_(2)I,and systematically elaborate on the mechanism of the phase transition.We then discuss the strategies in progress to suppress phase transition in CsPbBr_(2)I,and their potential application in the photovoltaic field.Finally,challenges and application prospects for CsPbBr2I PSCs are summarized in the final section of this article.
基金funded by the National Natural Science Foundation of China(51902148,61704099,51801088 and 51802024)the Fundamental Research Funds for the Central Universities(lzujbky2020-61,lzujbky-2019-88 and lzujbky-2020-kb06)the Special Funding for Open and Shared Large-Scale Instruments and Equipments of Lanzhou University(LZU-GXJJ-2019C023 and LZU-GXJJ-2019C019)。
文摘Recently,perovskite solar cells(PSCs) have flourished,and their power conversion efficiency(PCE) has increased from the initial 3.8% to 25.2% in 2019,which is an unprecedented advance.However,usually high-efficiency and stable PSCs are small-area devices prepared by spin coating.This method is not suitable for the preparation of large-area devices in commercialization.Therefore,there is an urgent need to develop new materials and methods for the scalable fabrication of PSCs.In this review,we first describe the common small-area PSCs preparation methods,understand the nucleation and crystal growth kinetics of perovskite,and analyze the reasons that hinder the development of small-area devices to large-area devices.Next,in order to meet the challenges of PSC’s scalable fabrication,we summarize and analyze four strategies:scaling up precursor solutions,scalable deposition methods for large-area films,scaling up charge-transport layers and back electrodes,developing solar modules.Finally,challenges and prospects are proposed to help researchers prepare high-efficiency large-area PSCs.
基金funded by the National Natural Science Foundation of China(51902148,61704099 and 51801088)the Fundamental Research Funds for the Central Universities(lzujbky-2020-61,lzujbky-2019-88 and lzujbky-2020-kb06)the Special Funding for Open and Shared Large-Scale Instruments and Equipments of Lanzhou University(LZU-GXJJ2019C023 and LZU-GXJJ-2019C019).
文摘Nowadays,inorganic CsPbI3 perovskite solar cells(PSCs)have become one of the most attractive research hotspots in photovoltaic field for its superior chemical stability and excellent photo-electronic properties.Since the first independent report in 2015,the power conversion efficiency(PCE)of CsPbI3 based PSCs has sharply increased from 3.9%to 19.03%.Importantly,during the developing process of CsPbI3 PSCs,HI hydrolysis-derived intermediate plays an important role:from stabilizing the crystal structure,optimizing the fabricated film to boosting the device performance.In this review,the different crystal and electronic structures of CsPbI3 are introduced.We then trace the history and disputes of HI hydrolysis-derived intermediate to make this review more logical.Meanwhile,we highlight the functions of HI hydrolysis-derived intermediate,and systematically summarize the advanced works on CsPbI3 PSCs.Finally,the bottlenecks and prospects are revealed to further increase the CsPbI3 PSCs performance.
基金funded by the National Natural Science Foundation of China(52073131,51902148,61874166,51802024,11974069 and U1832149)the Fundamental Research Funds for the Central Universities(lzujbky-2020-61,lzujbky-2020-64,lzujbky-2021-it31,lzujbky-2021-ct15 and lzujbky-2021-ct01)+2 种基金the Natural Science Foundation of Gansu Province(20JR5RA278 and 20JR5RA24)the LiaoNing Revitalization Talents Program(XLYC1902113)the Science and Technology Program of Qinghai Province(2020-HZ-809)。
文摘To better utilize the infrared(IR)region in sunlight for photovoltaic devices(PVs),upconversion nanoparticles(UCNPs)have been proposed to improve power conversion efficiency(PCE).However,researchers recently have found that the upconversion(UC)effect is negligible in PVs performance improvement for their ultra-low UC photoluminescence quantum yields of UCNPs solid film,while the real mechanism of UCNPs in PVs has not been clearly studied.Herein,based on the material inorganic perovskitesγ-CsPbI_(3),NaYF_(4):20%Yb^(3+),2%Er^(3+)UCNPs were integrated into different transport layer to optimize device performance.Compared with reference device,the short-circuit current density and PCE of optimized device reached 20.87 mA/cm^(2)(20.39 mA/cm^(2))and 18.34%(17.72%),respectively,without sacrificing open-circuit voltage and filling factor.Further experimental characterizations verified that the improved performance was attributable to enhanced visible light absorption instead of IR.To theoretically explain the statement,the light field distribution in device was simulated and the absorption in different layers was calculated.The results revealed that the introduction of UCNPs with different refractive index from other layers caused light field disturbance,and improved visible light captured by γ-CsPbI_(3).Importantly,through experiments and theoretical calculation,the research deeply explored the potential mechanism of UCNPs in optimizing PVs performance.
基金supported by the National Natural Science Foundation of China (51702038)National Natural Science Foundation of China (51773045, 21772030, 51922032, 21961160720) for financial support+1 种基金the Recruitment Program for Young ProfessionalsNational Key Research and Development Program of China (2017YFA0206600)。
文摘Perovskite quantum-dots (PQDs) have emerged as prominent candidates for intriguing photovoltaic application due to their superior optoelectronic properties such as multiple exciton generation, bandgap tunability, electronic and surface chemistry properties, as well as flexible composition [1–5].
基金We thank the National Natural Science Foundation of China(Nos.52203217 and 21961160720)the National Key Research and Development Program of China(No.2022YFB3803300)the Open Research Fund of Songshan Lake Materials Laboratory(No.2021SLABFK02)for financial support.
文摘Bandgap-graded materials present varying spectral responses at different positions,making them possible to be used as an alternative to photoactive materials array in multi-spectral responsive devices,thus miniaturizing the apparatus.However,the preparation of bandgap-graded materials usually requires complicated deposition process.Here we report a facile lowtemperature solution process to make films with lateral bandgap gradients,which form spontaneously via self-spreading and interdiffusion of solutions.We show lead halide perovskite films with MAPbCl_(3)-MAPbBr_(3)and MAPbBr_(3)-MAPbI_(3)gradients,which exhibit light absorption onsets ranging from 410 to 781 nm.The bandgap-graded films were used to make self-powered multiband photodetectors,which show different spectral responses at different positions without applying bias voltage.Furthermore,self-powered spectrometers were made by using the multiband photodetectors.
基金supported by the National Natural Science Foundation of China(51773045,21772030,51922032,21961160720)。
文摘Organic solar cells have attracted academic and industrial interests due to the advantages like lightweight,flexibility and roll-to-roll fabrication.Nowadays,18%power conversion efficiency has been achieved in the state-of-the-art organic solar cells.The recent rapid progress in organic solar cells relies on the continuously emerging new materials and device fabrication technologies,and the deep understanding on film morphology,molecular packing and device physics.Donor and acceptor materials are the key materials for organic solar cells since they determine the device performance.The past 25 years have witnessed an odyssey in developing high-performance donors and acceptors.In this review,we focus on those star materials and milestone work,and introduce the molecular structure evolution of key materials.These key materials include homopolymer donors,D-A copolymer donors,A-D-A small molecular donors,fullerene acceptors and nonfullerene acceptors.At last,we outlook the challenges and very important directions in key materials development.
基金the National Key Research and Development Program of China (2017YFA0206600)the National Natural Science Foundation of China (51773045, 21772030, 51922032 and 21961160720)+1 种基金Fundamental Research Funds for the Central Universities (2020CDJQY-A055)the Youth Association for Promoting Innovation (CAS) for financial support。
基金the National Key Research and Development Program of China (2017YFA0206600)the National Natural Science Foundation of China (51773045, 21572041, 21772030, 51922032 and 21875286)+1 种基金the Youth Association for Promoting Innovation (CAS) for financial supportthe Science Fund for Distinguished Young Scholars of Hunan Province (2017JJ1029)
文摘Recently,great progress has been made in organic solar cells due to the emergence of high-performance nonfullerene acceptors[1-6].Over 16%and 17%power conversion efficiencies(PCEs)were achieved for nonfullerene-acceptor-based single-junction and tandem cells,respectively[7,8].Owing to complementary light absorption,wide-bandgap donor-acceptor(D-A)copolymers are ideal electron-donating partners for nonfullerene acceptors.However,efficient D-A copolymer donors are still limited.
基金the National Key Research and Development Program of China (2017YFA0206600)the National Natural Science Foundation of China (51773045, 21572041 and 21772030) for financial support
文摘Organic-inorganic halide perovskite (ABX3) solar cells (PSCs)have made great progress in recent years [1]. The power conversion efficiency (PCE) has increased up to 25.2%(NREL Best Research-Cell Efficiency Chart, https://www.nrel.gov/pv/cell-efficiency.html, Accessed August 2019). However, they suffer from poor thermal stability due to the volatile A-site organic cations.
基金the National Key Research and Development Program of China(2017YFA0206600)the National Natural Science Foundation of China(51773045,21772030,51922032 and 21961160720)the Youth Association for Promoting Innovation(CAS)for financial support。