The safety of natural gas pipeline is often severely threatened by the transverse landslide. At home and abroad, it is the first time to study the safe length of the pipeline when affected by landslide, and take ...The safety of natural gas pipeline is often severely threatened by the transverse landslide. At home and abroad, it is the first time to study the safe length of the pipeline when affected by landslide, and take the safe length of the pipeline as an engineering practical index. Therefore, it is of great significance to study the influence of transverse landslide affecting the safety of natural gas pipeline when a certain length of pipeline is thrusted, and to establish practical index and simulation method for prediction and prevention of the landslide hazards to gas pipeline. Based on the current research results, this study could be divided into three steps: First of all, with the help of ANSYS finite element software, the model of transverse landslide acting on the gas pipeline can be set up, then the length value of gas pipeline safely withstanding transverse landslide can be calculated;Secondly, using the strength reduction method, which is commonly used in the research of landslide stability, can establish three-dimensional model of the landslide and pipes in the ABAQUS finite element software, next, under the same landslide pushed length, the calculation results will be obtained;Finally, to draw reliable conclusions, all calculated results of the former two methods will be linked to synthetically and comparatively analyze, then the length value of common X80 gas pipeline safely bearing transverse landslide can be got. All results can provide some references for engineering and design.展开更多
Due to good nutritional properties and potential health benefits,quinoa has gained an increasing attention.The study aimed to analyze the effect of pressure cooking on the composition,antioxidant activity,antibacteria...Due to good nutritional properties and potential health benefits,quinoa has gained an increasing attention.The study aimed to analyze the effect of pressure cooking on the composition,antioxidant activity,antibacterial activity and bioavailability of phenolic compounds in four types of quinoa,and to evaluate the correlation between phenolics and its biological activities by correlation analysis.The results showed that different varieties of quinoa contained different phenolic components and their biological activities were different.Pressure cooking could significantly increase(P<0.05)the phenolic contents of quinoa,and decrease in vitro digestibility of protein.The antioxidant activity,antibacterial activity and bioavailability of quinoa were also enhanced which were positively related with phenolic contents.HPLC analysis indicated that at least twelve phenolic compounds were found in quinoa,and hyperoside,sinapic acid,rutin and ferulic acid occupied a majority of them.Correlation analysis suggested that hyperoside,quercetin,sinapic acid,ferulic acid and gallic acid made the key contribution to antioxidant and antibacterial activities of phenolic compounds of quinoa.The results provided valuable information for quinoa processing with phenolics as functional ingredient.展开更多
Nonreciprocal optical devices are essential for laser protection,modern optical communication and quantum information processing by enforcing one-way light propagation.The conventional Faraday magneto-optical nonrecip...Nonreciprocal optical devices are essential for laser protection,modern optical communication and quantum information processing by enforcing one-way light propagation.The conventional Faraday magneto-optical nonreciprocal devices rely on a strong magnetic field,which is provided by a permanent magnet.As a result,the isolation direction of such devices is fixed and severely restricts their applications in quantum networks.In this work,we experimentally demonstrate the simultaneous one-way transmission and unidirectional reflection by using a magneto-optical Fabry-Pérot cavity and a magnetic field strength of 50 mT.An optical isolator and a three-port quasi-circulator are realized based on this nonreciprocal cavity system.The isolator achieves an isolation ratio of up to 22 dB and an averaged insertion loss down to 0.97 dB.The quasi-circulator is realized with a fidelity exceeding 99% and an overall survival probability of 89.9%,corresponding to an insertion loss of~0.46 dB.The magnetic field is provided by an electromagnetic coil,thereby allowing for reversing the light circulating path.The reversible quasi-circulator paves the way for building reconfigurable quantum networks.展开更多
To address the problem of flexible drive control of gastrointestinal(GI)tract micro-capsule robot posture,a novel dual helix magnetorheological fluid(MRF)micro-robot(DHMRFMR)is proposed and developed in this paper.Bas...To address the problem of flexible drive control of gastrointestinal(GI)tract micro-capsule robot posture,a novel dual helix magnetorheological fluid(MRF)micro-robot(DHMRFMR)is proposed and developed in this paper.Based on the mechanical properties of magnetorheological fluid,the relationship model of magnetic field force is obtained,and the thrust model is established.Double micro DC deceleration motor is used to drive the two ends of the helical actuator to make the DHMRFMR forward and backward,by changing the external magnetic field rotation speed,direction and distance,adjust the attitude direction of the robot.Numerical simulation software ANSYS is used to analyze the motion law of external fluid of DHMRFMR,and the visualization of fluid velocity and pressure distribution is realized.The front-end helix actuator can change the flow path of the fluid,and the middle and tail of the DHMRFMR bear less pressure,which improves the stability and flexibility of the robot.The novel DHMRFMR is suitable for internal drive in bending environment,and has a good application prospect in biomedical engineering field in human intestinal unstructured environment.展开更多
2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction ti...2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction time is typically in hours or days.Herein,we developed a green route for the continuous and high-throughput synthesis of 2-hydroxycarbazole and 4-hydroxycarbazole via photochemical intramolecular cyclization of 3–hydroxy-2–chloro-diphenylamine using a self-designed millimeter scale photoreactor,which was designed based on sizing-up and numbering-up strategies for a decent liquid holdup(6.8 m L)and fabricated via femtosecond laser engraving technique.The photochemical synthesis was carried out continuously under the illumination of 365 nm UV-LED with dimethyl sulfoxide as solvent and potassium t-butoxide as catalyst.It was found that under optimized conditions a 2-hydroxycarbazole yield of 31.6%and a 4-hydroxycarbazole yield of 11.1%were obtained with a residence time of 1 min.Compared to semibatch operations,the reaction time was shortened by 1–2 orders of magnitude.As a result,a throughput of 11.3 g/day 2-hydroxycarbazole and 4.0 g/day 4-hydroxycarbazole can be achieved from the photoreactor.It was proposed that the short reaction time and high product yield are resulted from higher photon transfer rates and more uniform photon distribution provided by the millimeter scale photoreactor,which enhances the reaction rates and mitigates overreaction.展开更多
Spiral springs have a wide range of applications in various fields.As a result of the complexity of friction,few theoretical analyses of spring belts under static loading have been carried out.Considering the piecewis...Spiral springs have a wide range of applications in various fields.As a result of the complexity of friction,few theoretical analyses of spring belts under static loading have been carried out.Considering the piecewise smooth property of the whole contact area,a simplified static model of spiral springs under loading is established in this paper.Besides,three main stress and friction distribution areas of the spring belt are proposed,namely,internal,transitional,and external regions.Since the outermost side of the spring is not subject to any pressure,a recursive method is adopted from the outside to the inside.The model provides the parameter conditions,i.e.,the internal and external forces are independent or dependent.Therefore,the case that the whole contact region of the spring belt has one subregion,two subregions,and three subregions is obtained.The model gives a theoretical basis for the parameter optimization of spiral springs.展开更多
Using palygorskite(PAL)as template,the PAL/TiO_(2)/PANI nano-rods were synthesized by heterogeneous precipitation and in-situ polymerization.The synthesized PAL/TiO_(2)/PANI nanorods were used as a novel electrorheolo...Using palygorskite(PAL)as template,the PAL/TiO_(2)/PANI nano-rods were synthesized by heterogeneous precipitation and in-situ polymerization.The synthesized PAL/TiO_(2)/PANI nanorods were used as a novel electrorheological(ER)fluid by mixing with silicone oil,which showed excellent ER effect.The yield stress of the PAL/TiO_(2)/PANI based ER fluid(15 vol%)reached 8.8 kPa under 4 kV mm^(−1) electric field.The dynamic shear stress of the PAL/TiO_(2)/PANI based ER fluid could maintain a stable level in the shear rate range of 0.1–100 s^(−1).Furthermore,the PAL/TiO_(2)/PANI ER fluid exhibited excellent suspension stability.展开更多
Photovoltaic cells are one of the most promising renewable energy sources to address energy and environmental issues.Amongst the many photovoltaic technologies,organic solar cells(OSCs)have numerous advantages,such as...Photovoltaic cells are one of the most promising renewable energy sources to address energy and environmental issues.Amongst the many photovoltaic technologies,organic solar cells(OSCs)have numerous advantages,such as low cost,light weight,semi-transparency,and flexibility.This last is a special merit of OSCs,arising due to the intrinsic flexibility of organic active layers.With promising applications in fields such as building-integrated photovoltaics and wearable electronics,flexible OSCs(F-OSCs)have developed rapidly,and significant process has been made in recent years.In this review,we summarize the recent progress in F-OSCs from the perspective of flexible transparent electrodes.In addition,large-area F-OSCs and their potential applications are briefly dis-cussed.Finally,challenges for the further development of F-OSCs are presented.展开更多
Keystroke dynamics is the process to identify or authenticate individuals based on their typing rhythm behaviors. Several classifications have been proposed to verify a user's legitimacy, and the performances of thes...Keystroke dynamics is the process to identify or authenticate individuals based on their typing rhythm behaviors. Several classifications have been proposed to verify a user's legitimacy, and the performances of these classifications should be confirmed to identify the most promising research direction. However, classification research contains several experiments with different conditions such as datasets and methodologies. This study aims to benchmark the algorithms to the same dataset and features to equally measure all performances. Using a dataset that contains the typing rhythm of 51 subjects, we implement and evaluate 15 classifiers measured by Fl-measure, which is the harmonic mean of a false-negative identification rate and false-positive identification rate. We also develop a methodology to process the typing data. By considering a case in which the model will reject the outsider, we tested the algorithms on an open set. Additionally, we tested different parameters in random forest and k nearest neighbors classifications to achieve better results and explore the cause of their high performance. We also tested the dataset on one-class classification and explained the results of the experiment. The top-performing classifier achieves an Fl-measure rate of 92% while using the normalized typing data of 50 subjects to train and the remaining data to test. The results, along with the normalization methodology, constitute a benchmark for comparing the classifiers and measuring the performance of keystroke dynamics for insider detection.展开更多
文摘The safety of natural gas pipeline is often severely threatened by the transverse landslide. At home and abroad, it is the first time to study the safe length of the pipeline when affected by landslide, and take the safe length of the pipeline as an engineering practical index. Therefore, it is of great significance to study the influence of transverse landslide affecting the safety of natural gas pipeline when a certain length of pipeline is thrusted, and to establish practical index and simulation method for prediction and prevention of the landslide hazards to gas pipeline. Based on the current research results, this study could be divided into three steps: First of all, with the help of ANSYS finite element software, the model of transverse landslide acting on the gas pipeline can be set up, then the length value of gas pipeline safely withstanding transverse landslide can be calculated;Secondly, using the strength reduction method, which is commonly used in the research of landslide stability, can establish three-dimensional model of the landslide and pipes in the ABAQUS finite element software, next, under the same landslide pushed length, the calculation results will be obtained;Finally, to draw reliable conclusions, all calculated results of the former two methods will be linked to synthetically and comparatively analyze, then the length value of common X80 gas pipeline safely bearing transverse landslide can be got. All results can provide some references for engineering and design.
基金the project of the Program of Beijing Advanced Innovation Center for Food Nutrition and Human Health(20181037)the project of Science and Technology Department of Shanxi Province(202102140601014)。
文摘Due to good nutritional properties and potential health benefits,quinoa has gained an increasing attention.The study aimed to analyze the effect of pressure cooking on the composition,antioxidant activity,antibacterial activity and bioavailability of phenolic compounds in four types of quinoa,and to evaluate the correlation between phenolics and its biological activities by correlation analysis.The results showed that different varieties of quinoa contained different phenolic components and their biological activities were different.Pressure cooking could significantly increase(P<0.05)the phenolic contents of quinoa,and decrease in vitro digestibility of protein.The antioxidant activity,antibacterial activity and bioavailability of quinoa were also enhanced which were positively related with phenolic contents.HPLC analysis indicated that at least twelve phenolic compounds were found in quinoa,and hyperoside,sinapic acid,rutin and ferulic acid occupied a majority of them.Correlation analysis suggested that hyperoside,quercetin,sinapic acid,ferulic acid and gallic acid made the key contribution to antioxidant and antibacterial activities of phenolic compounds of quinoa.The results provided valuable information for quinoa processing with phenolics as functional ingredient.
基金supported by the National Key R&D Program of China(Grant No.2019YFA0308700)the National Natural Science Foundation of China(Grant Nos.11890704,92365107,and 12305020)+2 种基金the Program for Innovative Talents and Teams in Jiangsu(Grant No.JSSCTD202138)the Shccig-Qinling Program,the China Postdoctoral Science Foundation(Grant No.2023M731613)the Jiangsu Funding Program for Excellent Postdoctoral Talent(Grant No.2023ZB708)。
文摘Nonreciprocal optical devices are essential for laser protection,modern optical communication and quantum information processing by enforcing one-way light propagation.The conventional Faraday magneto-optical nonreciprocal devices rely on a strong magnetic field,which is provided by a permanent magnet.As a result,the isolation direction of such devices is fixed and severely restricts their applications in quantum networks.In this work,we experimentally demonstrate the simultaneous one-way transmission and unidirectional reflection by using a magneto-optical Fabry-Pérot cavity and a magnetic field strength of 50 mT.An optical isolator and a three-port quasi-circulator are realized based on this nonreciprocal cavity system.The isolator achieves an isolation ratio of up to 22 dB and an averaged insertion loss down to 0.97 dB.The quasi-circulator is realized with a fidelity exceeding 99% and an overall survival probability of 89.9%,corresponding to an insertion loss of~0.46 dB.The magnetic field is provided by an electromagnetic coil,thereby allowing for reversing the light circulating path.The reversible quasi-circulator paves the way for building reconfigurable quantum networks.
基金supported by the Key Research Development and Promotion Special Project of Henan Province,under Grant 212102310119 and 212102210358Scientific Research Foundation for High-level Talents of Henan Institute of Technology,under Grant KQ1869+6 种基金Research and Practice Project of Higher Education Teaching Reform in Henan Province,under Grant 2021SJGLX289University-Industry Collaborative Education Program,under Grant 202101187010 and 202102120046Innovation and Entrepreneurship Training Program for College Students of Henan Province,under Grant 202211329011Educational and Teaching Reform Research and Practice Project of Henan Institute of Technology,under Grant 2021-YB023 and JJXY-2021005Innovative Education Curriculum Construction Project of Henan Institute of Technology,under Grant CX-2021-0052022 Xinxiang Federation of Social Sciences Research topic,under Grant SKL-2022-254 and SKL-2022-2282022 Annual Research Topic of Henan Federation of Social Sciences,under Grant SKL-2022-2692.
文摘To address the problem of flexible drive control of gastrointestinal(GI)tract micro-capsule robot posture,a novel dual helix magnetorheological fluid(MRF)micro-robot(DHMRFMR)is proposed and developed in this paper.Based on the mechanical properties of magnetorheological fluid,the relationship model of magnetic field force is obtained,and the thrust model is established.Double micro DC deceleration motor is used to drive the two ends of the helical actuator to make the DHMRFMR forward and backward,by changing the external magnetic field rotation speed,direction and distance,adjust the attitude direction of the robot.Numerical simulation software ANSYS is used to analyze the motion law of external fluid of DHMRFMR,and the visualization of fluid velocity and pressure distribution is realized.The front-end helix actuator can change the flow path of the fluid,and the middle and tail of the DHMRFMR bear less pressure,which improves the stability and flexibility of the robot.The novel DHMRFMR is suitable for internal drive in bending environment,and has a good application prospect in biomedical engineering field in human intestinal unstructured environment.
基金funded by the National Natural Science Foundation of China(Nos.21991103,21991104,22008074,22008072)Natural Science Foundation of Shanghai(No.20ZR1415700)China Postdoctoral Science Foundation(Nos.2020M671025,2019TQ0093)。
文摘2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction time is typically in hours or days.Herein,we developed a green route for the continuous and high-throughput synthesis of 2-hydroxycarbazole and 4-hydroxycarbazole via photochemical intramolecular cyclization of 3–hydroxy-2–chloro-diphenylamine using a self-designed millimeter scale photoreactor,which was designed based on sizing-up and numbering-up strategies for a decent liquid holdup(6.8 m L)and fabricated via femtosecond laser engraving technique.The photochemical synthesis was carried out continuously under the illumination of 365 nm UV-LED with dimethyl sulfoxide as solvent and potassium t-butoxide as catalyst.It was found that under optimized conditions a 2-hydroxycarbazole yield of 31.6%and a 4-hydroxycarbazole yield of 11.1%were obtained with a residence time of 1 min.Compared to semibatch operations,the reaction time was shortened by 1–2 orders of magnitude.As a result,a throughput of 11.3 g/day 2-hydroxycarbazole and 4.0 g/day 4-hydroxycarbazole can be achieved from the photoreactor.It was proposed that the short reaction time and high product yield are resulted from higher photon transfer rates and more uniform photon distribution provided by the millimeter scale photoreactor,which enhances the reaction rates and mitigates overreaction.
基金the National Natural Science Foundation of China(No.11972055)the National Defense Science and Technology Fund in the Technical Field of the Foundation Strengthening Plan(No.2020-JCJQ-JJ-009)the Civil Aerospace Pre-research Project(No.D020206)。
文摘Spiral springs have a wide range of applications in various fields.As a result of the complexity of friction,few theoretical analyses of spring belts under static loading have been carried out.Considering the piecewise smooth property of the whole contact area,a simplified static model of spiral springs under loading is established in this paper.Besides,three main stress and friction distribution areas of the spring belt are proposed,namely,internal,transitional,and external regions.Since the outermost side of the spring is not subject to any pressure,a recursive method is adopted from the outside to the inside.The model provides the parameter conditions,i.e.,the internal and external forces are independent or dependent.Therefore,the case that the whole contact region of the spring belt has one subregion,two subregions,and three subregions is obtained.The model gives a theoretical basis for the parameter optimization of spiral springs.
基金support by the Jiangsu Key R&D program(BE2019072)the Ningbo Natural Science Foundation(2018A610167,2018A610322).
文摘Using palygorskite(PAL)as template,the PAL/TiO_(2)/PANI nano-rods were synthesized by heterogeneous precipitation and in-situ polymerization.The synthesized PAL/TiO_(2)/PANI nanorods were used as a novel electrorheological(ER)fluid by mixing with silicone oil,which showed excellent ER effect.The yield stress of the PAL/TiO_(2)/PANI based ER fluid(15 vol%)reached 8.8 kPa under 4 kV mm^(−1) electric field.The dynamic shear stress of the PAL/TiO_(2)/PANI based ER fluid could maintain a stable level in the shear rate range of 0.1–100 s^(−1).Furthermore,the PAL/TiO_(2)/PANI ER fluid exhibited excellent suspension stability.
基金The authors gratefully acknowledge the financial support from NSFC(52025033 and 21935007),MoST(2019YFA0705900)of China,Tianjin city(20JCZDJC00740),111 Project(B12015)Haihe Laboratory of Sustainable Chemical Transformations.
文摘Photovoltaic cells are one of the most promising renewable energy sources to address energy and environmental issues.Amongst the many photovoltaic technologies,organic solar cells(OSCs)have numerous advantages,such as low cost,light weight,semi-transparency,and flexibility.This last is a special merit of OSCs,arising due to the intrinsic flexibility of organic active layers.With promising applications in fields such as building-integrated photovoltaics and wearable electronics,flexible OSCs(F-OSCs)have developed rapidly,and significant process has been made in recent years.In this review,we summarize the recent progress in F-OSCs from the perspective of flexible transparent electrodes.In addition,large-area F-OSCs and their potential applications are briefly dis-cussed.Finally,challenges for the further development of F-OSCs are presented.
基金supported by the National Natural Science Foundation of China (Nos. 61403301 and 61773310)the China Postdoctoral Science Foundation (Nos. 2014M560783 and 2015T81032)+1 种基金the Natural Science Foundation of Shaanxi Province (No. 2015JQ6216)the Fundamental Research Funds for the Central Universities (No. xjj2015115)
文摘Keystroke dynamics is the process to identify or authenticate individuals based on their typing rhythm behaviors. Several classifications have been proposed to verify a user's legitimacy, and the performances of these classifications should be confirmed to identify the most promising research direction. However, classification research contains several experiments with different conditions such as datasets and methodologies. This study aims to benchmark the algorithms to the same dataset and features to equally measure all performances. Using a dataset that contains the typing rhythm of 51 subjects, we implement and evaluate 15 classifiers measured by Fl-measure, which is the harmonic mean of a false-negative identification rate and false-positive identification rate. We also develop a methodology to process the typing data. By considering a case in which the model will reject the outsider, we tested the algorithms on an open set. Additionally, we tested different parameters in random forest and k nearest neighbors classifications to achieve better results and explore the cause of their high performance. We also tested the dataset on one-class classification and explained the results of the experiment. The top-performing classifier achieves an Fl-measure rate of 92% while using the normalized typing data of 50 subjects to train and the remaining data to test. The results, along with the normalization methodology, constitute a benchmark for comparing the classifiers and measuring the performance of keystroke dynamics for insider detection.