基于再生对苯二甲酸二甲酯制备阻燃聚酯纤维

文中以再生对苯二甲酸二甲酯(r-DMT)和乙二醇(EG)为原料、以2-羧乙基苯基次磷酸(CEPPA)为阻燃剂,采取共聚合的策略合成了阻燃再生聚对苯二甲酸乙二醇酯(rFR-PET)切片,并通过熔融纺丝技术制备了83 dtex/36 f规格的阻燃再生聚酯纤维。研究发现,CEPPA的引入使得聚酯的缩聚变得困难,阻燃再生PET相较于未改性的再生PET端羧基含量增大、二甘醇含量降低、亮度L值下降、黄蓝色度b值增大、热稳定性和结晶性下降。通过极限氧指数(LOI)测试和垂直燃烧性能(UL-94)分析得知,再生PET经阻燃改性后,LOI值由22.1%提高至32.7%,UL-94垂直燃烧等级从V-2级提升至V-0级,阻燃性能大幅提升。阻燃再生PET切片可纺性优异,通过熔融纺丝工艺制备的纤维具有良好的力学性能。为利用r-DMT开发下游高值化再生聚酯材料提供了有益参考。

Regional Brand and High-quality Development of Fruits in Ethnic Areas of the Yangtze River Economic Belt under the Greater Food Approach

Establishing the Greater Food Approach and promoting the Yangtze River Economic Belt s national major regional development strategy can better support and serve the agricultural power and Chinese-style modernization.This paper introduces the characteristics of fruit industry in 16 autonomous prefectures and 47 autonomous counties under the jurisdiction of the Yangtze River Economic Belt.It studies the intellectual property resources of brand marks from the aspects of geographical indications,collective trademarks,certification trademarks,well-known trademarks in China and national design patents,and analyzes the main problems of brand and high-quality development of fruit industry in these ethnic autonomous areas.Finally,it puts forward some strategies,such as improving the protection of intellectual property rights of geographical indications,using intellectual property rights of brand signs,building modern seed industry upgrading project,drawing lessons from the experience of thousand villages demonstration project,ensuring that large-scale poverty does not occur,and building a diversified food supply system.

Promoting High-quality Development of Grain and Oil in Ethnic Areas of the Yangtze River Economic Belt from the Perspective of Agricultural Power

Accelerating the construction of agricultural power,further promoting the high-quality development of the Yangtze River Economic Belt,and better supporting and serving Chinese-style modernization are the key issues at present.This paper first introduces the Yangtze River Economic Belt and its ethnic areas,and studies the characteristics of the grain and oil industry in the ethnic autonomous areas of the economic belt,as well as the current situation of various types of intellectual property resources,such as industrial cultural heritage,scientific and tech-nological innovation,and brand marking intellectual property.Besides,it analyzes the main problems in the high-quality development of grain and oil in the Yangtze River Economic Belt ethnic areas.Finally,it comes up with recommendations,including protecting the intellectual prop-erty rights of cultural heritage in the field of grain and oil,leading the inheritance and development of excellent traditional Chinese culture,use scientific and technological innovation intellectual property rights to promote the innovation-driven development strategy of the grain and oil in-dustry,and providing counterpart assistance to ethnic autonomous areas in the Yangtze River Economic Belt to further promote the high-quality development of the Yangtze River Economic Belt.

Inheritance,Innovation and Development of Wuling Mountain Area in Hubei Province Based on Intellectual Property Rights

Using the methods of field survey and literature collection,this paper firstly introduces the intellectual property resources of the Wuling Mountain Area in Hubei Province from folk literature and arts,traditional knowledge,biological genetic resources,new plant varieties,patents,geographical indications,and trademarks.Then,it analyzes the main problems in the protection and inheritance,innovation and development of intellectual property rights(IPRs).In addition,it discusses the strategy of inheritance,innovation and high-quality development of this ethnic area in the context of the strategy of strengthening the country with intellectual property rights and the strategy of rural revitalization.Finally,it comes up with recommendations including carrying forward and inheriting folk literature and art,protecting traditional knowledge of traditional craftsmanship,inheriting and innovating to develop traditional Chinese medicine and ethnic medicine,improving the protection and use of geographical indications,and strengthening the IPR protection.

Indoor Positioning Using Public FM and DTMB Signals Based on Compressive Sensing

Location-Based Services have become an indispensable part of our daily life, the sparsity of location finding makes it possible to estimate specific position by Compressive Sensing(CS). Using public Frequency Modulation(FM) broadcasting and Digital Television Terrestrial Multimedia Broadcasting(DTMB) signals, this paper presents an indoor positioning scheme, which is consisted of an offline stage and an online stage. In the offline stage, the Received Signal Strength(RSS) at the Reference Points(RPs) is measured, including the average and variance of public FM broadcasting and DTMB signals. In the online stage, the K-Weighted Nearest Neighbor algorithm is used to fulfill coarse positioning, which is able to narrow the selection scope of locations and choose partial RPs for accurate positioning. Then, the accurate positioning is implemented through CS. Experiment shows that the average positioning error of the proposed scheme is 1.63 m. What’s more, a CS-based method has been proposed in this paper to reduce the labor cost when collecting data. Experiment shows the average positioning error is 2.04 m, with the advantage of a 34% labor cost reduction. Experiment results indicate that the proposed system is a practical indoor positioning scheme.

Energetic electron detection packages on board Chinese navigation satellites in MEO

Energetic electron measurements and spacecraft charging are of great significance for theoretical research in space physics and space weather applications.In this paper,the energetic electron detection package(EEDP)deployed on three Chinese navigation satellites in medium Earth orbit(MEO)is reviewed.The instrument was developed by the space science payload team led by Peking University.The EEDP includes a pinhole medium-energy electron spectrometer(MES),a high-energy electron detector(HED)based onΔE-E telescope technology,and a deep dielectric charging monitor(DDCM).The MES measures the energy spectra of 50−600 keV electrons from nine directions with a 180°×30°field of view(FOV).The HED measures the energy spectrum of 0.5−3.0 MeV electrons from one direction with a 30°cone-angle FOV.The ground test and calibration results indicate that these three sensors exhibit excellent performance.Preliminary observations show that the electron spectra measured by the MES and HED are in good agreement with the results from the magnetic electron-ion spectrometer(MagEIS)of the Van Allen Probes spacecraft,with an average relative deviation of 27.3%for the energy spectra.The charging currents and voltages measured by the DDCM during storms are consistent with the highenergy electron observations of the HED,demonstrating the effectiveness of the DDCM.The observations of the EEDP on board the three MEO satellites can provide important support for theoretical research on the radiation belts and the applications related to space weather.

The in-situ Ti alloying of aluminum alloys and its application in A356 alloys

This research has investigated the in-situ Ti alloying of aluminum alloys and its application to A356 alloys and wheels through the evaluation of microstructure and mechanical properties. The results showed that stable titanium content can be obtained by adding a small quantity of TiO2 into electrolyte of pure aluminum. Under this approach, a greater than 95% absorptivity of titanium was achieved, and the microstructure of the specimens was changed to fine equiaxed grains from coarse columnar grains in the pure aluminum. In comparison with the tradition A356 alloys and wheels, the corresponding microstructure in the testing A356 alloys and wheels was finer. Although the tensile strength was similar between the testing and the tradition A356 alloys and wheels, the ductility of the former (testing) is superior to that of the later (tradition), leading to an excellent combination of strength and ductility from the testing alloys and wheels.

Geographical Indication Protection and Brand Cultivation of Hefeng Tea in Wuling Mountain Area

Located in Wuling mountain area which is the main battlefield for poverty alleviation in the new stage,Hefeng County of Hubei Province has been recognized as a " National Key Tea-producing County in 2013"( ranking 17th) and one of the " Top Ten Ecological Rea Counties of China in 2012". As the first county of tea export in Hubei Province,it has been awarded the " Town of the Chinese Tea" certificate by the State Forestry Bureau. This paper introduced the characteristics of geographical indication and the current situation of brand of Hefeng Tea. Later,it analyzed its geographical indication protection and brand cultivation strategies and puts forward 9 suggestions.

Research on the Geographical Indication and Cultural Heritage of China's Yellow Tea

The yellow tea falls within one of the six basic categories of tea,and it is a type of unique and ancient tea in China. Junshan Yinzhen is one of China's Top Ten Teas,and Yueyang City in Hunan Province is the hometown of yellow tea. The yellow tea now has 2 national geographical indication products,4 national geographical indication trademarks,1 national geographical indication of agricultural products,and 3 items of provincial intangible cultural heritage. The famous brand of yellow tea is just the brand cultural heritage. This article expounds the current situation of geographical indication and cultural heritage protection,and put forth the corresponding recommendations.

The Protection of Chinese Traditional Villages and Construction of Beautiful Countryside in the Wuling Mountain Area

Chinese traditional villages have the characteristics of both intangible and tangible cultural heritage,and are the largest cultural heritage left by farming civilization in China. Under the synchronous propulsion of new four modernizations and the coordinated development of urban and rural areas,the important issues we face are to protect the Chinese traditional villages,inherit the agricultural heritage,and develop the farming culture resources. There are 60 Chinese traditional villages in the Wuling Mountain area. This article introduces the Chinese traditional villages in the area,analyzes its Chinese traditional village protection and beautiful village construction,and puts forward corresponding recommendations.

Inheritance,Innovation,Development and Intellectual Property Protection of Tea Industry in Wuling Mountain Area of Hubei Province

Wuling Mountain Area of Hubei Province is a key tea-producing area in China,and the tea industry is its agricultural pillar industry.First,this paper introduces the tea industry in Wuling Mountain Area.Then,from traditional knowledge,biological genetic resources,new plant varieties,patents,geographical indications,trademarks,etc.,it studies the intellectual property resources of its tea industry.Next,it analyzes main problems of its intellectual property protection and inheritance,innovation and development.It also discusses the strategy of inheritance,innovation and high-quality development of the tea industry in this ethnic area in the context of the strategy of strengthening the country with intellectual property rights and the strategy of rural revitalization.Finally,it comes up with pertinent recommendations,including implementing the traditional tea production process and technical protection project,protecting the biological genetic resources of tea trees,cultivating new varieties of tea plants bred independently,creating high value patents,building regional public brands,and strengthening intellectual property protection.

Trip to IEC

For long impressed by the time-cherished IEC, I have been inspired to learn more about this international organization since my first interview with Mr. James Matthews Ill, the Vice-President of IEC in March 2012, which was followed by several more important interviews with IEC senior officers including former IEC President Dr. Klaus Wucherer, IEC Vice-President Shu Yinbiao and IEC General Secretary ＆ CEO Frans Vreeswijk. I was really looking forward to visiting and exploring the IEC someday by myself.

Bionic Design and Experimental Validation of a Robotic Airship Inspired by the Physalia physalis

The robotic airship is one of the most unique and promising green aircraft,however,as a“lighter-than-air aircraft”and“thermal aircraft”,its long-endurance flight has great difficulties in decreasing drag and controlling buoyancy and pressure under thermal effects.In this work,we reported a robotic airship inspired by the Physalia physalis,imitating its morphology,physiological structure,and biological behaviors.The hull is designed by imitating the morphology of the Physalia physalis,and the gasbags including a helium balloon,two ballonets,and a thermoregulation gasbag are designed by imitating the physiological structure and biological behaviors of the pneumatophore,bladder,and gland of the Physalia physalis,respectively.Experimental results show that the bionic airship has an increase of about 40%in lift-to-drag and decreases the pressure in helium balloon by 47.5%under thermal effects,and has better aerodynamic performances and thermoregulation performances than conventional airships.

3D printed modular Bouligand dissipative structures with adjustable mechanical properties for gradient energy absorbing

Three-dimensional(3D)printing allows for the creation of complex,layered structures with precise micro and macro architectures that are not achievable through traditional methods.By designing 3D structures with geometric precision,it is possible to achieve selective regulation of mechanical properties,enabling efficient dissipation of mechanical energy.In this study,a series of modular samples inspired by the Bouligand structure were designed and produced using a direct ink writing system,along with a classical printable polydimethylsiloxane ink.By altering the angles of filaments in adjacent layers(from 30◦to 90◦)and the filament spacing during printing(from 0.8 mm to 2.4 mm),the mechanical properties of these modular samples can be adjusted.Compression mechanical testing revealed that the 3D printed modular Bouligand structures exhibit stress-strain responses that enable multiple adjustments of the elastic modulus from 0.06 MPa to over 0.8 MPa.The mechanical properties were adjusted more than 10 times in printed samples prepared using uniform materials.The gradient control mechanism of mechanical properties during this process was analyzed using finite element analysis.Finally,3D printed customized modular Bouligand structures can be assembled to create an array with Bouligand structures displaying various orientations and interlayer details tailored to specific requirements.By decomposing the original Bouligand structure and then assembling the modular samples into a specialized array,this research aims to provide parameters for achieving gradient energy absorption structures through modular 3D printing.

聚集诱导发光型光敏剂用于线粒体靶向光动力治疗

光动力治疗是一种基于光敏剂和光照的安全无创性治疗方法,在癌症治疗和杀菌等方面具有广阔的应用前景。光敏剂在光照激发下与氧气作用会生成高反应活性的活性氧。在细胞中过量的活性氧会氧化损伤蛋白质、核酸和脂质等细胞组分,诱导细胞凋亡或坏死。新兴的聚集诱导发光型光敏剂在分子聚集状态下光照激发能发射强的荧光,同时高效地产生活性氧,解决了传统光敏剂在分子聚集时荧光猝灭的问题,易实现成像指导的光动力治疗,近年来备受关注。线粒体作为细胞能量工厂富含氧气,是理想的光动力治疗靶点。本文总结了靶向癌细胞线粒体的聚集诱导发光型光敏剂的分子类型和设计策略,以及其在光动力治疗肿瘤方面的应用。

金融机构股东和债权人利益关系——基于不同风险状态的研究

文章以中国上市金融机构为研究样本,使用金融市场交易数据,运用多元GARCH模型,在控制金融机构风险状态的前提下研究金融机构股东和债权人之间是否存在利益冲突。实证分析表明,在高风险状态下,样本内21家金融机构股东和债权人之间能够同舟共济,尤其是当风险超过一个拐点时,金融机构股东和债权人有动机相互配合,最大化双方共同利益。但同时实证分析显示,样本内有24家金融机构股东和债权人在高风险状态下没有表现出"共苦"的精神。因此在高风险状态下,金融机构股东与债权人之间的关系表现具有异质性特征。在低风险状态下,股东会在风险上升缓冲地区内增加公司经营风险,导致债权人对未来风险的担忧,进而会增加债券折现率,降低债券价值,股东和债权人之间存在更为明显的冲突。总体上,本文实证结论表明股东和债权人之间存在利益冲突的可能性更大。