Many researchers have developed new calculation methods to analyze seismic slope stability problems, but the conventional pseudo-static method is still widely used in engineering design due to its simplicity. Based on...Many researchers have developed new calculation methods to analyze seismic slope stability problems, but the conventional pseudo-static method is still widely used in engineering design due to its simplicity. Based on the Technical Code for Building Slope Engineering(GB 50330-2013) of China and the Guidelines for Evaluating and Mitigating Seismic Hazards in California(SP117), a comparative study on the pseudo-static method was performed. The results indicate that the largest difference between these two design codes lies in determination of the seismic equivalence reduction factor( f;). The GB 50330-2013 code specifies a single value for f;of 0.25. In SP117, numerous factors,such as magnitude and distance, are considered in determining f;. Two case studies show that the types of slope stability status evaluated by SP117 are in agreement with those evaluated by the seismic time-history stability analysis and Newmark displacement analysis. The factors of safety evaluated by SP117 can be used in practice for safe design. However, the factors of safety evaluated by GB 50330-2013 are risky for slope seismic design.展开更多
A new series of solid solutions Lu2W3-xMoxO12 (0.5≤r≤2.5) were successfully synthesized by the solid-state method. Their crystal structure and negative thermal expansion properties were studied using high-temperat...A new series of solid solutions Lu2W3-xMoxO12 (0.5≤r≤2.5) were successfully synthesized by the solid-state method. Their crystal structure and negative thermal expansion properties were studied using high-temperature X-ray powder diffraction and the Rietveld method. All samples of rare-earth ttmgstates and molybdates are found to crystallize in the same orthorhombic structure with space group Pnca and show the negative thermal expansion phenomena related to transverse vibration of bridging oxygen atoms in the structure. Thermal expansion coefficients (TEC) of Lu2W3_xMoxO12 are determined as -20.0× 10^-6 K^-1 for x=0.5 and -16.1×10^-6 K^-1 for x=2.5 but -18.6× 10^-6 and -16.9× 10^-6K^-1 for unsubstituted Lu2W3012 and Lu2M03012 in the identical temperature range of 200 to 800℃. High-temperature X-ray diffraction (XRD) data and bond length analysis suggest that the difference between W-O and Mo-O bond is responsible for the change of TECs after the element substitution in this series of solid solutions.展开更多
Crystal structures and thermal expansion properties of Yb2-xFexMo3O12(x=0.0,0.6,1.0,1.1,1.4) solid solutions have been studied by X-ray powder diffraction(XRPD) at different temperatures.Rietveld analysis of the X...Crystal structures and thermal expansion properties of Yb2-xFexMo3O12(x=0.0,0.6,1.0,1.1,1.4) solid solutions have been studied by X-ray powder diffraction(XRPD) at different temperatures.Rietveld analysis of the XRPD data shows that Yb2-xFexMo3O12 solid solutions adopt orthorhombic structure and have variable thermal expansion coefficients controlled by the ratio of Yb^3+ to Fe^3+.Yb2Mo3O12 shows anisotropic negative thermal expansion property,induced by the reductions in average Yb-O-Mo angle and average apparent Mo2-O bond length with increasing temperatures.As more Yb^3+ substituted by Fe^3+,the linear thermal expansion coefficients of Yb2-xFexMo3O12 increase from negative to positive.A near-zero thermal expansion coefficient of 0.55×10^-6K^-1 for Yb0.6Fe1.4Mo3O12 is observed in the temperature range of 573-873 K.展开更多
基金supported by the National Key R&D Program of China(Grant No.2017YFC0404804)the National Natural Science Foundation of China(Grant No.51509019)
文摘Many researchers have developed new calculation methods to analyze seismic slope stability problems, but the conventional pseudo-static method is still widely used in engineering design due to its simplicity. Based on the Technical Code for Building Slope Engineering(GB 50330-2013) of China and the Guidelines for Evaluating and Mitigating Seismic Hazards in California(SP117), a comparative study on the pseudo-static method was performed. The results indicate that the largest difference between these two design codes lies in determination of the seismic equivalence reduction factor( f;). The GB 50330-2013 code specifies a single value for f;of 0.25. In SP117, numerous factors,such as magnitude and distance, are considered in determining f;. Two case studies show that the types of slope stability status evaluated by SP117 are in agreement with those evaluated by the seismic time-history stability analysis and Newmark displacement analysis. The factors of safety evaluated by SP117 can be used in practice for safe design. However, the factors of safety evaluated by GB 50330-2013 are risky for slope seismic design.
基金supported by the China Postdoctoral Science Foundation (No.20080430556)the Major State Basic Research and Development Program of China (No.2006CB705600)
文摘A new series of solid solutions Lu2W3-xMoxO12 (0.5≤r≤2.5) were successfully synthesized by the solid-state method. Their crystal structure and negative thermal expansion properties were studied using high-temperature X-ray powder diffraction and the Rietveld method. All samples of rare-earth ttmgstates and molybdates are found to crystallize in the same orthorhombic structure with space group Pnca and show the negative thermal expansion phenomena related to transverse vibration of bridging oxygen atoms in the structure. Thermal expansion coefficients (TEC) of Lu2W3_xMoxO12 are determined as -20.0× 10^-6 K^-1 for x=0.5 and -16.1×10^-6 K^-1 for x=2.5 but -18.6× 10^-6 and -16.9× 10^-6K^-1 for unsubstituted Lu2W3012 and Lu2M03012 in the identical temperature range of 200 to 800℃. High-temperature X-ray diffraction (XRD) data and bond length analysis suggest that the difference between W-O and Mo-O bond is responsible for the change of TECs after the element substitution in this series of solid solutions.
基金supported by the National Natural Science Foundation of China (No. 21403129)the Project of Shandong Province Higher Educational Science and Technology Program (No.J13LD13 & J15LC09)"Hundred Talents Project" of the Chinese Academy of Sciences
文摘Crystal structures and thermal expansion properties of Yb2-xFexMo3O12(x=0.0,0.6,1.0,1.1,1.4) solid solutions have been studied by X-ray powder diffraction(XRPD) at different temperatures.Rietveld analysis of the XRPD data shows that Yb2-xFexMo3O12 solid solutions adopt orthorhombic structure and have variable thermal expansion coefficients controlled by the ratio of Yb^3+ to Fe^3+.Yb2Mo3O12 shows anisotropic negative thermal expansion property,induced by the reductions in average Yb-O-Mo angle and average apparent Mo2-O bond length with increasing temperatures.As more Yb^3+ substituted by Fe^3+,the linear thermal expansion coefficients of Yb2-xFexMo3O12 increase from negative to positive.A near-zero thermal expansion coefficient of 0.55×10^-6K^-1 for Yb0.6Fe1.4Mo3O12 is observed in the temperature range of 573-873 K.