The Huanghe River(Yellow River)Delta has a wide distribution of fine-grained soils.Fluvial alluviation,erosion,and wave loads affect the shoal area,resulting complex physical and mechanical properties to sensitive fin...The Huanghe River(Yellow River)Delta has a wide distribution of fine-grained soils.Fluvial alluviation,erosion,and wave loads affect the shoal area,resulting complex physical and mechanical properties to sensitive finegrained soil located at the river-sea boundary.The cone penetration test(CPT)is a convenient and effective in situ testing method which can accurately identify various soil parameters.Studies on undrained shear strength only roughly determine the fine content(FC)without making the FC effect clear.We studied four stations formed in different the Huanghe River Delta periods.We conducted in situ CPT and corresponding laboratory tests,examined the fine content influence on undrained shear strength(S_(u)),and determined the cone coefficient(N_(k)).The conclusions are as follows.(1)The fine content in the area exceeded 90%,and the silt content was high,accounting for more than 70%of all fine particle compositions.(2)The undrained shear strength gradually increased with depth with a maximum of approximately 250 kPa.When the silt content was lower than 60%–70%,the undrained shear strength decreased.(3)The silt and clay content influenced undrained shear strength,and the fitted f_(s)h/q_(t) function model was established,which could be applied to strata with a high fine content.The cone coefficients were between 20 and 25,and the overconsolidated soil layer had a greater cone coefficient.展开更多
Poor electron conductivity is the key issue influencing the rate capability of NaTi_(2)(PO_(4))_(3)(NTP).Hence,herein,polyacrylonitrile(PAN)was utilized as a NTP modifier by simply mixing NTP in a liquid PAN suspensio...Poor electron conductivity is the key issue influencing the rate capability of NaTi_(2)(PO_(4))_(3)(NTP).Hence,herein,polyacrylonitrile(PAN)was utilized as a NTP modifier by simply mixing NTP in a liquid PAN suspension,followed by sintering at 850℃ for 5 h.The product with a PAN/NTP mass ratio of 0.3 delivered splendid rate capabilities(achieving lithiation capacities of 282.9,243.0,207.1,173.1,133.5,and 257.5 mAh g^(−1) at 0.1,0.2,0.4,0.8,1.6,and 0.1 A^(−1),respectively)and excellent long cycling life(capacity retention of 165.5 mAh g^(−1) after 1200 cycles at 0.5 A g−1).Based on detailed structural and compositional characterizations,as well as cyclic voltammetry(CV)and electrochemical impedance spectroscopy(EIS),the uniform N-doped carbon coating stemming from PAN carbonization around the NTP particles promoted electron transfer,while the oxygen vacancies induced by N-doping in NTP facilitated Li+diffusion.The boosted and well matched electronic and ionic conductivities give rise to the optimized electrochemical performance.展开更多
基金The National Natural Science Foundation of China under contract Nos S42177153,U2006213 and 41806075the Shandong Province Focused Research and Development Program under contract No.2019GHY112075the National Major Scientific Research Instrument Development Project under contract No.41627801.
文摘The Huanghe River(Yellow River)Delta has a wide distribution of fine-grained soils.Fluvial alluviation,erosion,and wave loads affect the shoal area,resulting complex physical and mechanical properties to sensitive finegrained soil located at the river-sea boundary.The cone penetration test(CPT)is a convenient and effective in situ testing method which can accurately identify various soil parameters.Studies on undrained shear strength only roughly determine the fine content(FC)without making the FC effect clear.We studied four stations formed in different the Huanghe River Delta periods.We conducted in situ CPT and corresponding laboratory tests,examined the fine content influence on undrained shear strength(S_(u)),and determined the cone coefficient(N_(k)).The conclusions are as follows.(1)The fine content in the area exceeded 90%,and the silt content was high,accounting for more than 70%of all fine particle compositions.(2)The undrained shear strength gradually increased with depth with a maximum of approximately 250 kPa.When the silt content was lower than 60%–70%,the undrained shear strength decreased.(3)The silt and clay content influenced undrained shear strength,and the fitted f_(s)h/q_(t) function model was established,which could be applied to strata with a high fine content.The cone coefficients were between 20 and 25,and the overconsolidated soil layer had a greater cone coefficient.
基金This work was supported by Project ZR2022QE165 of Shandong Provincial Natural Science Foundation,China.
文摘Poor electron conductivity is the key issue influencing the rate capability of NaTi_(2)(PO_(4))_(3)(NTP).Hence,herein,polyacrylonitrile(PAN)was utilized as a NTP modifier by simply mixing NTP in a liquid PAN suspension,followed by sintering at 850℃ for 5 h.The product with a PAN/NTP mass ratio of 0.3 delivered splendid rate capabilities(achieving lithiation capacities of 282.9,243.0,207.1,173.1,133.5,and 257.5 mAh g^(−1) at 0.1,0.2,0.4,0.8,1.6,and 0.1 A^(−1),respectively)and excellent long cycling life(capacity retention of 165.5 mAh g^(−1) after 1200 cycles at 0.5 A g−1).Based on detailed structural and compositional characterizations,as well as cyclic voltammetry(CV)and electrochemical impedance spectroscopy(EIS),the uniform N-doped carbon coating stemming from PAN carbonization around the NTP particles promoted electron transfer,while the oxygen vacancies induced by N-doping in NTP facilitated Li+diffusion.The boosted and well matched electronic and ionic conductivities give rise to the optimized electrochemical performance.
