Highly effident metal-free, carbon-based, bi-functional electrocatalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) have attracted increased attention for use in electrochemical en...Highly effident metal-free, carbon-based, bi-functional electrocatalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) have attracted increased attention for use in electrochemical energy conversion systems, owing to their low cost and high activity. In this work, N-doped carbon nanocages (N-CCs) with a porous self-supported architecture and high specific surface area are synthesized by a facile interfacial assembly synthetic route. The materials are comprehensively characterized by scanning electron microscop36 transmission electron microscopy, nitrogen adsorption-desorption experiments, X-ray diffraction, and X-ray photoelectron spectroscopy. Cyclic voltammetry , chronoamperometry, and linear sweep voltammetry demonstrate that the as-prepared N-CC could serve as an effective metal-free electrocatalyst with excellent catalytic activity, long-term operation durability, and excellent methanol tolerance for the ORR in alkaline media. In the presence of 3 mM methanol, the half wave potential of the N-CCs for the ORR is 190 mV; this is more positive than that of the commercial Pt/C electrocatalyst. Meanwhile, the N-CCs also show an OER activity comparable to that of the commercial Ru/C electrocatalyst, revealing their bifunctional property.展开更多
Approach to highly efficient dye-sensitized solar cells(DSSCs)by co-sensitization of organic dyes,AZ6+AZ5 with co-adsorbent chenodeoxycholic acid(CDCA)is presented.The power conversion efficiencies(PCEs)of 8.55%and 8....Approach to highly efficient dye-sensitized solar cells(DSSCs)by co-sensitization of organic dyes,AZ6+AZ5 with co-adsorbent chenodeoxycholic acid(CDCA)is presented.The power conversion efficiencies(PCEs)of 8.55%and 8.31%are obtained from DSSCs co-sensitized by AZ6(0.3 mmol/L)+AZ5(0.1 mmol/L)with CDCA concentration of 5 and 20 mmol/L in one step cocktail,respectively.The latter shows high stability in a period of 653 h under ambient conditions.展开更多
基金This research was sponsored by Key Technologies R&D Program of Shaanxi Province (Nos. 2014K10-06 and 2015XT-18), the National Natural Science Foundation of China (Nos. 51373092 and 21543012), the Funda-mental Research Funds for the Central Universities (Nos. GK201503038 and GK201501002), Program for Key Science & Technology Innovation Team of Shaanxi Province (No. 2015KCT-13), and the 111 Project (No. B14041).
文摘Highly effident metal-free, carbon-based, bi-functional electrocatalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) have attracted increased attention for use in electrochemical energy conversion systems, owing to their low cost and high activity. In this work, N-doped carbon nanocages (N-CCs) with a porous self-supported architecture and high specific surface area are synthesized by a facile interfacial assembly synthetic route. The materials are comprehensively characterized by scanning electron microscop36 transmission electron microscopy, nitrogen adsorption-desorption experiments, X-ray diffraction, and X-ray photoelectron spectroscopy. Cyclic voltammetry , chronoamperometry, and linear sweep voltammetry demonstrate that the as-prepared N-CC could serve as an effective metal-free electrocatalyst with excellent catalytic activity, long-term operation durability, and excellent methanol tolerance for the ORR in alkaline media. In the presence of 3 mM methanol, the half wave potential of the N-CCs for the ORR is 190 mV; this is more positive than that of the commercial Pt/C electrocatalyst. Meanwhile, the N-CCs also show an OER activity comparable to that of the commercial Ru/C electrocatalyst, revealing their bifunctional property.
基金Research was supported by the Changjiang Scholars and Innovative Research Team in University(No.IRT1070)the Natural Science Foundation of China(No.51373092)+2 种基金the Specialized Research Fund for the Doc-toral Program of Higher Education of China(No.20130202120010)the Key Science and Technology Program of Shaanxi Province,China(No.2012K08-09)the State Education Ministry and the Fundamental Re-search Funds for the Central Universities(Nos.GK201302036,GK201302037).Our special thanks are also for the Fund of New Energy Devices and Materials provided by Mr.He Chong Ben,Hong Kong.
文摘Approach to highly efficient dye-sensitized solar cells(DSSCs)by co-sensitization of organic dyes,AZ6+AZ5 with co-adsorbent chenodeoxycholic acid(CDCA)is presented.The power conversion efficiencies(PCEs)of 8.55%and 8.31%are obtained from DSSCs co-sensitized by AZ6(0.3 mmol/L)+AZ5(0.1 mmol/L)with CDCA concentration of 5 and 20 mmol/L in one step cocktail,respectively.The latter shows high stability in a period of 653 h under ambient conditions.