The solid state reactions of p-nitroacetophenone, acetyl-ferrocene with indole were catalyzed by anhydrous zinc chloride or aluminum chloride, and gave exclusively the 1:2 condensation products. The solid state conden...The solid state reactions of p-nitroacetophenone, acetyl-ferrocene with indole were catalyzed by anhydrous zinc chloride or aluminum chloride, and gave exclusively the 1:2 condensation products. The solid state condensation of aromatic ketones with 1-phenyl-3-methyl-5-pyrazolone was also investigated, and the 1:1 and 2:1 condensation products were obtained. The structures of eleven new products were determined by IR, MS, H-1 NMR and elemental analysis.展开更多
基金Project supported by the National Natural Science Foundation of China and State Key Laboratory of Applied Organic Chemistry of Lanzhou University.
文摘The solid state reactions of p-nitroacetophenone, acetyl-ferrocene with indole were catalyzed by anhydrous zinc chloride or aluminum chloride, and gave exclusively the 1:2 condensation products. The solid state condensation of aromatic ketones with 1-phenyl-3-methyl-5-pyrazolone was also investigated, and the 1:1 and 2:1 condensation products were obtained. The structures of eleven new products were determined by IR, MS, H-1 NMR and elemental analysis.
