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Synthesis and Crystal Structure of[(n-Bu)_4N]_2[Mo_4O_(10)(OC_(10)H_6O)_2(OCH_3)_2] 被引量:2
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作者 Lu Xiao-Ming zhu hui-ju +2 位作者 Yang Ning Liu Shun-Cheng Jin Xiang-Lin(Department of Chemistry, Capital Normal University, Beijing 100037) (Experiment Center, Capital Normal University, Beijing 100037)(Institute of Physical Chemistry, Peking University , Beij 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1995年第2期135-138,共4页
n-Bu )_4N]_2 [Mo_4O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2 ] crystallizes in the monoclinic, space group P21/c, a= 10. 926 (6) , b= 17. 861 (7) . c= 16. 258 (7) ,β=91. 16(4)°, V= 3172 (2)  ̄3, Z = 2, M_r = 1407. 0, D_... n-Bu )_4N]_2 [Mo_4O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2 ] crystallizes in the monoclinic, space group P21/c, a= 10. 926 (6) , b= 17. 861 (7) . c= 16. 258 (7) ,β=91. 16(4)°, V= 3172 (2)  ̄3, Z = 2, M_r = 1407. 0, D_c =1. 473 g/cm ̄3 , μ= 0. 814mm ̄(-1), F(000) = 1448. T= 298K , final R= 0. 043 and R_w= 0. 058 for 3291 observed reflections. The structure of the complex consists of two (n-Bu)_4N ̄+ cations and one [Mo_4 O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2] ̄(2-) anion having crystallographic C_i symmetry, with a tetranuclear core of [Mo_4 O_(10)(OCH_3 )_2] ̄(2+) . 展开更多
关键词 POLYOXOMOLYBDATE 2 3-dihydroxynaphthalene crystal structure
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