Magnetic topological semimetals(TSMs)are topological quantum materials with broken time-reversal symmetry(TRS)and isolated nodal points or lines near the Fermi level.Their topological properties would typically reveal...Magnetic topological semimetals(TSMs)are topological quantum materials with broken time-reversal symmetry(TRS)and isolated nodal points or lines near the Fermi level.Their topological properties would typically reveal from the bulk-edge correspondence principle as nontrivial surface states such as Fermi arcs or drumhead states,etc.Depending on the degeneracies and distribution of the nodes in the crystal momentum space,TSMs are usually classified into Weyl semimetals(WSMs),Dirac semimetals(DSMs),nodal-line semimetals(NLSMs),triple-point semimetals(TPSMs),etc.In this review article,we present the recent advances of magnetic TSMs from a computational perspective.We first review the early predicted magnetic WSMs such as pyrochlore iridates and HgCr_(2)Se_(4),as well as the recently proposed Heusler,Kagome layers,and honeycomb lattice WSMs.Then we discuss the recent developments of magnetic DSMs,especially CuMnAs in Type-III and EuCd_(2)As_(2) in Type-IV magnetic space groups(MSGs).Then we introduce some magnetic NLSMs that are robust against spin–orbit coupling(SOC),namely Fe_(3)GeTe_(2) and LaCl(LaBr).Finally,we discuss the prospects of magnetic TSMs and the interesting directions for future research.展开更多
Methacrolein(MACR) and methyl vinyl ketone(MVK) are two major intermediate products from the photochemical oxidation of isoprene, the most important biogenic volatile organic compound. In addition, MACR and MVK have p...Methacrolein(MACR) and methyl vinyl ketone(MVK) are two major intermediate products from the photochemical oxidation of isoprene, the most important biogenic volatile organic compound. In addition, MACR and MVK have primary emissions. Investigating the sources and evolution of MACR and MVK could provide helpful information for the oxidative capacity of the atmosphere. In this study, hourly measurements of isoprene, MACR, and MVK were conducted at a receptor site in the Pearl River Delta region(PRD), i.e., the Heshan site(HS), from 22 October to 20 November, 2014. The average mixing ratios of isoprene,MACR and MVK were 151 ± 17, 91 ± 6 and 79 ± 6 pptv, respectively. The daily variations and the ratios of MVK/MACR during daytime and nighttime suggested that other sources besides isoprene photooxidation influenced the MACR and MVK abundances at the HS.Positive matrix factorization was utilized to resolve the sources of MACR and MVK. Five sources were identified and quantified, including biogenic emissions, biomass burning,secondary formation, diesel, and gasoline vehicular emissions. Among them, secondary formation made the greatest contribution to observed MACR and MVK with average contributions of ~ 45% and ~ 70%, respectively. Through the yields of secondary products from the oxidation of MACR and MVK by the OH radical and the concentrations of MACR and MVK, it was found that methylglyoxal and formaldehyde were the main oxidation products of MACR and MVK at the HS site. Overall, this study evaluated the roles of primary emissions on ambient levels of MACR and MVK and advanced the understanding of photochemical oxidation of MACR and MVK in the PRD.展开更多
基金We thank the support by the Ministry of Science and Technology of China(2018YFA0307000)the National Natural Science Foundation of China(11874022)G.X.is supported by the National Thousand-Young-Talents Program.
文摘Magnetic topological semimetals(TSMs)are topological quantum materials with broken time-reversal symmetry(TRS)and isolated nodal points or lines near the Fermi level.Their topological properties would typically reveal from the bulk-edge correspondence principle as nontrivial surface states such as Fermi arcs or drumhead states,etc.Depending on the degeneracies and distribution of the nodes in the crystal momentum space,TSMs are usually classified into Weyl semimetals(WSMs),Dirac semimetals(DSMs),nodal-line semimetals(NLSMs),triple-point semimetals(TPSMs),etc.In this review article,we present the recent advances of magnetic TSMs from a computational perspective.We first review the early predicted magnetic WSMs such as pyrochlore iridates and HgCr_(2)Se_(4),as well as the recently proposed Heusler,Kagome layers,and honeycomb lattice WSMs.Then we discuss the recent developments of magnetic DSMs,especially CuMnAs in Type-III and EuCd_(2)As_(2) in Type-IV magnetic space groups(MSGs).Then we introduce some magnetic NLSMs that are robust against spin–orbit coupling(SOC),namely Fe_(3)GeTe_(2) and LaCl(LaBr).Finally,we discuss the prospects of magnetic TSMs and the interesting directions for future research.
基金supported by the National Key Research and Development Program of China(No.2016YFC0202206)the State Key Program of National Natural Science Foundation of China(No.91644215)+3 种基金the National Natural Science Foundation of China(Nos.41405112 and 41505103)the Pearl River Science&Technology Nova Program of Guangzhou(No.201806010146)the National Nature Science Fund for Distinguished Young Scholars(No.41425020)the Hong Kong Research Grands Council(No.25221215)
文摘Methacrolein(MACR) and methyl vinyl ketone(MVK) are two major intermediate products from the photochemical oxidation of isoprene, the most important biogenic volatile organic compound. In addition, MACR and MVK have primary emissions. Investigating the sources and evolution of MACR and MVK could provide helpful information for the oxidative capacity of the atmosphere. In this study, hourly measurements of isoprene, MACR, and MVK were conducted at a receptor site in the Pearl River Delta region(PRD), i.e., the Heshan site(HS), from 22 October to 20 November, 2014. The average mixing ratios of isoprene,MACR and MVK were 151 ± 17, 91 ± 6 and 79 ± 6 pptv, respectively. The daily variations and the ratios of MVK/MACR during daytime and nighttime suggested that other sources besides isoprene photooxidation influenced the MACR and MVK abundances at the HS.Positive matrix factorization was utilized to resolve the sources of MACR and MVK. Five sources were identified and quantified, including biogenic emissions, biomass burning,secondary formation, diesel, and gasoline vehicular emissions. Among them, secondary formation made the greatest contribution to observed MACR and MVK with average contributions of ~ 45% and ~ 70%, respectively. Through the yields of secondary products from the oxidation of MACR and MVK by the OH radical and the concentrations of MACR and MVK, it was found that methylglyoxal and formaldehyde were the main oxidation products of MACR and MVK at the HS site. Overall, this study evaluated the roles of primary emissions on ambient levels of MACR and MVK and advanced the understanding of photochemical oxidation of MACR and MVK in the PRD.