CONSPECTUS:Nanoporous crystals,such as silica mesoporous crystals(SMCs),zeolites,metal−organic frameworks(MOFs)and covalent organic frameworks(COFs),usually have unique geometrical features of periodically arranged po...CONSPECTUS:Nanoporous crystals,such as silica mesoporous crystals(SMCs),zeolites,metal−organic frameworks(MOFs)and covalent organic frameworks(COFs),usually have unique geometrical features of periodically arranged pores from micro-,meso-to macro-scale.They have great potential to be structurally designed toward novel materials for various applications,such as storage,separation,and catalysis.展开更多
Vacancies are prevalent and versatile in solid-state physics and materials science.The role of vacancies in strongly correlated materials,however,remains uncultivated until now.Here,we report the discovery of an unpre...Vacancies are prevalent and versatile in solid-state physics and materials science.The role of vacancies in strongly correlated materials,however,remains uncultivated until now.Here,we report the discovery of an unprecedented vacancy state forming an extended buckled-honeycomb-vacancy(BHV)ordering in Ir16Sb18.Superconductivity emerges by suppressing the BHV ordering through squeezing of extra Ir atoms into the vacancies or isovalent Rh substitution.The phase diagram on vacancy ordering reveals the superconductivity competes with the BHV ordering.Further theoretical calculations suggest that this ordering originates from a synergistic effect of the vacancy formation energy and Fermi surface nesting with a wave vector of(1/3,1/3,0).The buckled structure breaks the crystal inversion symmetry and can mostly suppress the density of states near the Fermi level.The peculiarities of BHV ordering highlight the importance of"correlated vacancies"and may serve as a paradigm for exploring other non-trivial excitations and quantum criticality.展开更多
基金The authors acknowledge Prof.Kenneth D.M.Harris for scientific discussions.Support from ShanghaiTech University and the Centre for High-resolution Electron Microscopy(ChEM)through EM-19430216the National Natural Science Foundation of China(No.21835002,21875140,92045303,12027804)are acknowledged.
文摘CONSPECTUS:Nanoporous crystals,such as silica mesoporous crystals(SMCs),zeolites,metal−organic frameworks(MOFs)and covalent organic frameworks(COFs),usually have unique geometrical features of periodically arranged pores from micro-,meso-to macro-scale.They have great potential to be structurally designed toward novel materials for various applications,such as storage,separation,and catalysis.
基金support by the National Key Research and Development Program of China(2018YFA0704300)the National Natural Science Foundation of China(U1932217 and 11974246)+4 种基金the Natural Science Foundation of Shanghai(19ZR1477300)supported by MEXT Element Strategy Initiative to form Core Research Centerpartially supported by ChEM,SPST of ShanghaiTech University(02161943)Analytical Instrumentation Center(SPST-AIC10112914),SPST of ShanghaiTech Universitysupported by the National Natural Science Foundation of China(11888101)。
文摘Vacancies are prevalent and versatile in solid-state physics and materials science.The role of vacancies in strongly correlated materials,however,remains uncultivated until now.Here,we report the discovery of an unprecedented vacancy state forming an extended buckled-honeycomb-vacancy(BHV)ordering in Ir16Sb18.Superconductivity emerges by suppressing the BHV ordering through squeezing of extra Ir atoms into the vacancies or isovalent Rh substitution.The phase diagram on vacancy ordering reveals the superconductivity competes with the BHV ordering.Further theoretical calculations suggest that this ordering originates from a synergistic effect of the vacancy formation energy and Fermi surface nesting with a wave vector of(1/3,1/3,0).The buckled structure breaks the crystal inversion symmetry and can mostly suppress the density of states near the Fermi level.The peculiarities of BHV ordering highlight the importance of"correlated vacancies"and may serve as a paradigm for exploring other non-trivial excitations and quantum criticality.
