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通过聚阳离子取代策略实现压缩黄铜矿型硒化物[Rb3BaCl][In_(8)Se_(14)]以获得优异的非线性光学性能
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作者 吴帆 陈文发 +3 位作者 吴子璇 姜小明 刘彬文 郭国聪 《Science China Materials》 SCIE EI CAS CSCD 2024年第6期2000-2007,共8页
单价Ag+或Li+引入到类金刚石结构的MQ22-(M=Ga,In;Q=S,Se)阴离子基团中能合成出良好的二阶非线性光学(NLO)晶体材料.然而,这些晶体分别面临着较低的抗激光损伤阈值(LIDT)或二氧化硅易被腐蚀等缺点,严重限制了其在高功率激光应用中的实用... 单价Ag+或Li+引入到类金刚石结构的MQ22-(M=Ga,In;Q=S,Se)阴离子基团中能合成出良好的二阶非线性光学(NLO)晶体材料.然而,这些晶体分别面临着较低的抗激光损伤阈值(LIDT)或二氧化硅易被腐蚀等缺点,严重限制了其在高功率激光应用中的实用性.在本研究中,基于类金刚石结构的ZnSe,我们采用[Se_(4)Zn_(13)]Se_(2)4→[ClRb_(3)Ba]Se_(24)非常规的聚阳离子取代策略,设计并合成了一种新型的盐包硫属化合物[Rb_(3)BaCl][In_(8)Se_(14)](1).化合物1属于压缩黄铜矿型硒化物并保持了与AgInSe_(2)相同的晶体对称性(I-42d空间群).值得注意的是,由于InSe_(4)四面体结构单元的平行排列,化合物1具有相位匹配的强二次谐波(SHG)响应(2.0倍于AgGaS_(2)@2.90μm).此外,聚阳离子[Rb_(3)BaCl]^(4+)的引入促进了光学带隙(2.02 eV)的增强,有效地避免了对2.09μm激光的双光子吸收;同时结合较低的热膨胀系数,使得化合物1表现出高的LIDT(3.2倍于AgGaS2@2.09μm).本研究验证了在类金刚石结构中进行聚阳离子取代的可行性,并成功获得了性能优异的中远红外NLO材料. 展开更多
关键词 CHALCOGENIDE nonlinear optical material substitution strategy diamond-like structure structure-property relationship
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Mechanism of Ta on the microstructure and properties of Fe-Mn damping alloys
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作者 Gui-Xiang Liu Kun Zhang +6 位作者 Chao Han Xiao-Lin Shao Jun Lu Lin Zhang Xiao-Song Jiang zi-xuan wu Liu Yang 《Tungsten》 EI CSCD 2024年第4期767-777,共11页
Fe-Mn-Co-xTa alloys(x=0,1,2,3 wt.%)were fabricated using spark plasma sintering to explore the influence of Ta content on the microstructure,mechanical properties,and damping characteristics of Fe-17Mn-3Co damping all... Fe-Mn-Co-xTa alloys(x=0,1,2,3 wt.%)were fabricated using spark plasma sintering to explore the influence of Ta content on the microstructure,mechanical properties,and damping characteristics of Fe-17Mn-3Co damping alloys.The micro structural analysis reveals the dominant presence ofγ-austenite,ε-martensite,α'-martensite,and Co_(3)Ta precipitates within the alloy.Incremental increments in Ta content exhibit proportional enhancements in hardness,tensile strength,and fracture elongation of the alloy.Notably,these improvements in mechanical attributes are closely correlated with the generated second-phase Co_(3)Ta.As the Ta content increases,there is a gradual augmentation in the formation of Co_(3)Ta within the alloy.Consequently,the damping property initially experiences an ascent followed by a subsequent decline with rising Ta content.This damping behavior finds its origins in multiple mechanisms,including grain boundary damping stemming from reduced grain size,interfacial damping induced by the generated Co_(3)Ta,and dislocation damping.It is noteworthy that the emergence of the secondary phase wields a dual impact on damping property.On the one hand,the proliferation of the second phase fosters increased interfaces for energy dissipation.On the other hand,these interfaces give rise to compressive stresses,constraining interface movement and thus impeding damping property enhancement. 展开更多
关键词 Fe-Mn-Co TA Spark plasma sintering Mechanical properties DAMPING
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Enhanced mechanical and electrical properties of multi-walled carbon nanotubes reinforced Cu/Ti_(3)SiC_(2)/C nanocomposites via high-pressure torsion
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作者 zi-xuan wu Pei-fan ZHANG +4 位作者 Xiao-song JIANG Hong-liang SUN Yan-jun LI Pål CHRISTIAN Liu YANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS 2024年第12期4005-4019,共15页
In order to achieve combined mechanical and electrical properties,multi-walled carbon nanotubes(MWCNTs)reinforced Cu/Ti_(3)SiC_(2)/C nanocomposites were further processed by high-pressure torsion(HPT).The maximum micr... In order to achieve combined mechanical and electrical properties,multi-walled carbon nanotubes(MWCNTs)reinforced Cu/Ti_(3)SiC_(2)/C nanocomposites were further processed by high-pressure torsion(HPT).The maximum microhardness values of central and edge from the composites with 1 wt.%MWCNTs reached HV 130.0 and HV 363.5,which were 43.9%and 39.5%higher than those of the original samples,respectively.With the same content of MWCNTs,its electrical conductivity achieved 3.42×10^(7) S/m,which was increased by 78.1%compared with that of original samples.The synergistic improvement of mechanical and electrical properties is attributed to the obtained microstructure with increased homogenization and refinement,as well as improved interfacial bonding and reduced porosity.The strengthening mechanisms include dispersion and refinement strengthening for mechanical properties,as well as reduced electron scattering for electrical properties. 展开更多
关键词 Cu/Ti_(3)SiC_(2)/C nanocomposites multi-walled carbon nanotubes high-pressure torsion microstructure microhardness electrical conductivity
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Effect of air frying and baking on physicochemical properties and digestive properties of scallop (Patinopecten yessoensis) adductor muscle
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作者 Zi-Ye Wang zi-xuan wu +5 位作者 Guan-Hua Zhao De-Yang Li Yu-Xin Liu Lei Qin Peng-Fei Jiang Da-Yong Zhou 《Food Bioscience》 SCIE 2023年第2期901-911,共11页
In this study,the effects of dry heat treatments including air frying and baking on the physicochemical and digestive properties of proteins in scallop adductor muscle(SAM)were evaluated.After heat treatments,the prot... In this study,the effects of dry heat treatments including air frying and baking on the physicochemical and digestive properties of proteins in scallop adductor muscle(SAM)were evaluated.After heat treatments,the proteins in SAM exhibited different degrees of oxidation,aggregation and degradation.For both heat treatments,the increase of carbonyl and dityrosine contents and the decrease of free sulfhydryl groups and surface hydrophobicity of proteins in SAM were observed along with increasing heat temperature.Meanwhile,with increasing heat temperature,there was a progressive transition fromα-helix toβ-sheet in protein secondary structure.However,the protein solubility first increased and then decreased with increasing temperature.Among which,the solubility of 160℃-treated samples was the highest,which were 21.02%and 20.32%for air frying and baking.The protein digestive properties which reflected by the degree of hydrolysis(DH),soluble amino groups and soluble peptides showed a trend of increasing first and then decreasing with increasing temperature.After gastrointestinal digestion,the DH,soluble amino groups and soluble peptides of 160℃-treated SAMs cooking by air frying were 69.96%,61.14%and 39.33%,respectively,which were significantly higher than all other samples including the fresh ones.Correlation analysis showed that the protein digestive indexes were positively correlated with solubility,free sulfhydryl content and surface hydrophobicity,and negatively correlated with protein carbonyl content,dityrosine content and protein aggregation degree.These results provide evidence for knowing more about the effects of dry heat treatments on physicochemical and digestive properties of aquatic muscle food. 展开更多
关键词 Heat treatment SOLUBILITY Protein oxidation AGGREGATION Degradation In vitro digestion
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