By using muon spin relaxation(μSR)measurements,we perform a comparative study of the microscopic magnetism in the parent compounds of infinite-layer nickelate superconductors RNiO_(2)(R=La,Nd).In either compound,the ...By using muon spin relaxation(μSR)measurements,we perform a comparative study of the microscopic magnetism in the parent compounds of infinite-layer nickelate superconductors RNiO_(2)(R=La,Nd).In either compound,the zero-fieldμSR spectra down to the lowest measured temperature reveal no long-range magnetic order.In LaNiO_(2),short-range spin correlations appear below T=150 K,and spins fully freeze below T∼10 K.NdNiO_(2)exhibits a more complex spin dynamics driven by the Nd 4f and Ni3d electron spin fluctuations.Further,it shows features suggesting the proximity to a spin-glass state occurring below T=5 K.In both compounds,the spin behavior with temperature is further confirmed by longitudinal-field μSR measurements.These results provide new insight into the magnetism of the parent compounds of the superconducting nickelates,crucial to understanding the microscopic origin of their superconductivity.展开更多
Implantable biomaterials and biosensors are integral components of modern medical systems but often encounter hindrances due to the foreign body response(FBR).Herein,we report an albumin coating strategy aimed at addr...Implantable biomaterials and biosensors are integral components of modern medical systems but often encounter hindrances due to the foreign body response(FBR).Herein,we report an albumin coating strategy aimed at addressing this challenge.Using a facile and scalable silane coupling strategy,human serum albumin(HSA)is covalently grafted to the surface of polydimethylsiloxane(PDMS)implants.This covalently grafted albumin coating remains stable and resistant to displacement by other proteins.Notably,the PDMS with covalently grafted HSA strongly resists the fibrotic capsule formation following a 180-day subcutaneous implantation in C57BL/6 mice.Furthermore,the albumin coating led to reduced recruitment of macrophages and triggered a mild immune activation pattern.Exploration of albumin coatings sourced from various mammalian species has shown that only HSA exhibited a promising anti-FBR effect.The albumin coating method reported here holds the potential to improve and extend the function of silicone-based implants by mitigating the host responses to subcutaneously implanted biomaterials.展开更多
With the popularity of online learning in recent decades,MOOCs(Massive Open Online Courses)are increasingly pervasive and widely used in many areas.Visualizing online learning is particularly important because it help...With the popularity of online learning in recent decades,MOOCs(Massive Open Online Courses)are increasingly pervasive and widely used in many areas.Visualizing online learning is particularly important because it helps to analyze learner performance,evaluate the effectiveness of online learning platforms,and predict dropout risks.Due to the large-scale,high-dimensional,and heterogeneous characteristics of the data obtained from online learning,it is difficult to find hidden information.In this paper,we review and classify the existing literature for online learning to better understand the role of visualization in online learning.Our taxonomy is based on four categorizations of online learning tasks:behavior analysis,behavior prediction,learning pattern exploration and assisted learning.Based on our review of relevant literature over the past decade,we also identify several remaining research challenges and future research work.展开更多
The efficient utilization of natural lignin,which is the main by-product of the cellulose industry,is crucial for enhancing its economic value,alleviating the environmental burden,and improving ecological security.By ...The efficient utilization of natural lignin,which is the main by-product of the cellulose industry,is crucial for enhancing its economic value,alleviating the environmental burden,and improving ecological security.By taking advantage of the large sp2 hybrid domain of lignin and introducing amino functional groups,new lignin-derived carbon dots(SPN-CDs)with red fluorescence were successfully synthesized.Compared with green and blue fluorescent materials,red SPN-CDs have desirable anti-interference properties of short-wave background and exhibit superior luminescence stability.The SPN-CDs obtained exhibited sensitive and distinctive visible color with fluorescence-dual responses toward hypochlorite.Considering this feature,a portable,low-cost,and sensitive fluorescence sensing paper with a low limit of detection of 0.249μmol∙L^(–1) was fabricated using the SPN-CDs for hypochlorite detection.Furthermore,a new type of visible-light and fluorescence dual-channel information encryption platform was constructed.Low-concentration hypochlorite can be employed as an accessible and efficient information encryption/decryption stimulus,as well as an information“eraser”,facilitating a safe and diversified transmission and convenient decryption of information.This work opens new avenues for high-value-added applications of lignin-based fluorescent materials.展开更多
LaIrIn5 is a reference compound of the heavy-fermion superconductor LaIrIn5.The lack of f electrons in LaIrIn5 indicates that there should not be any f electron participating in the construction of its Fermi surface.T...LaIrIn5 is a reference compound of the heavy-fermion superconductor LaIrIn5.The lack of f electrons in LaIrIn5 indicates that there should not be any f electron participating in the construction of its Fermi surface.Thus the electronic structure comparison between LaIrIn5 and LaIrIn5 provides a good platform to study the properties of f electrons.Here angle-resolved photoemission spectroscopy(ARPES)measurements and density functional theory(DFT)calculations are performed to study the electronic structures of LaIrIn5 and LaIrIn5.We find the valence band structures of the two materials are similar to each other,except for the absence of f bands in LaIrIn5.By analyzing the Fermi crossings of the three conduction bands of the two materials quantitatively,we find the volumes of the electron pocketsαandβaround the M′point become larger from LaIrIn5 to LaIrIn5,while the hole pocketγaround theΓ′point becomes smaller.Together with the calculation results,we confirm that this is mainly originated from the f-electron contribution,while the lattice-constant difference between LaIrIn5 and LaIrIn5 only has a finite influence.We also give a summary of the f-electron character in its related Ce-115 heavy fermion compounds.Our results may be essential for the complete microscopic understanding of the 115 compounds and the related heavy-fermion systems.展开更多
With the development of production technology and social needs,sectors of manufacturing are constantly improving.The use of sensors and computers has made it increasingly convenient to collect multimedia data in manuf...With the development of production technology and social needs,sectors of manufacturing are constantly improving.The use of sensors and computers has made it increasingly convenient to collect multimedia data in manufacturing.Targeted,rapid,and detailed analysis based on the type of multimedia data can make timely decisions at different stages of the entire manufacturing process.Visualization and visual analytics are frequently adopted in multimedia data analysis of manufacturing because of their powerful ability to understand,present,and analyze data intuitively and interactively.In this paper,we present a literature review of visualization and visual analytics specifically for manufacturing multimedia data.We classify existing research according to visualization techniques,interaction analysis methods,and application areas.We discuss the differences when visualization and visual analytics are applied to different types of multimedia data in the context of particular examples of manufacturing research projects.Finally,we summarize the existing challenges and prospective research directions.展开更多
The search of quantum spin liquid(QSL),an exotic magnetic state with strongly fluctuating and highly entangled spins down to zero temperature,is a main theme in current condensed matter physics.However,there is no smo...The search of quantum spin liquid(QSL),an exotic magnetic state with strongly fluctuating and highly entangled spins down to zero temperature,is a main theme in current condensed matter physics.However,there is no smoking gun evidence for deconfined spinons in any QSL candidate so far.The disorders and competing exchange interactions may prevent the formation of an ideal QSL state on frustrated spin lattices.Here we report comprehensive and systematic measurements of the magnetic susceptibility,ultralow-temperature specific heat,muon spin relaxation(μSR),nuclear magnetic resonance(NMR),and thermal conductivity for NaYbSe2 single crystals,in which Yb3+ions with effective spin-1/2 form a perfect triangular lattice.All these complementary techniques find no evidence of long-range magnetic order down to their respective base temperatures.Instead,specific heat,μSR,and NMR measurements suggest the coexistence of quasi-static and dynamic spins in NaYbSe2.The scattering from these quasi-static spins may cause the absence of magnetic thermal conductivity.Thus,we propose a scenario of fluctuating ferrimagnetic droplets immersed in a sea of QSL.This may be quite common on the way pursuing an ideal QSL,and provides a brand new platform to study how a QSL state survives impurities and coexists with other magnetically ordered states.展开更多
This article overviews the design considerations and state-of-the-art of the ring voltage-controlled oscillator(VCO)-based phase-locked loops(PLLs)for clock generation in different applications.Partic-ularly,the objec...This article overviews the design considerations and state-of-the-art of the ring voltage-controlled oscillator(VCO)-based phase-locked loops(PLLs)for clock generation in different applications.Partic-ularly,the objective of the current work is to evaluate the required PLL performance among the fundamental metrics of power,jitter and area.An in-depth treatment of the mainstream PLL architectures and the associated design techniques enables them to be compared analyt-ically and benchmarked with respect to their figure-of-merit(FoM).The paper also summarizes the key concerns on the selection of dif-ferent circuit techniques to optimize the clock performance under dif-ferent scenarios.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2022YFA1402203)the National Natural Science Foundation of China(Grant No.12174065)supported by the Shenzhen Fundamental Research Program(Grant Nos.JCYJ20220818100405013 and JCYJ20230807093204010)。
文摘By using muon spin relaxation(μSR)measurements,we perform a comparative study of the microscopic magnetism in the parent compounds of infinite-layer nickelate superconductors RNiO_(2)(R=La,Nd).In either compound,the zero-fieldμSR spectra down to the lowest measured temperature reveal no long-range magnetic order.In LaNiO_(2),short-range spin correlations appear below T=150 K,and spins fully freeze below T∼10 K.NdNiO_(2)exhibits a more complex spin dynamics driven by the Nd 4f and Ni3d electron spin fluctuations.Further,it shows features suggesting the proximity to a spin-glass state occurring below T=5 K.In both compounds,the spin behavior with temperature is further confirmed by longitudinal-field μSR measurements.These results provide new insight into the magnetism of the parent compounds of the superconducting nickelates,crucial to understanding the microscopic origin of their superconductivity.
基金supported by the National Key R&D Program of China(2022YFB3807300)the National Natural Science Foundation of China(52103188,22175152)+2 种基金the Joint Funds of the Zhejiang Provincial Natural Science Foundation of China and Huadong Medicine(LHDMZ22H300011)the Fundamental Research Funds for the Central Universities(226-2022-00146)the startup package of Zhejiang University.
文摘Implantable biomaterials and biosensors are integral components of modern medical systems but often encounter hindrances due to the foreign body response(FBR).Herein,we report an albumin coating strategy aimed at addressing this challenge.Using a facile and scalable silane coupling strategy,human serum albumin(HSA)is covalently grafted to the surface of polydimethylsiloxane(PDMS)implants.This covalently grafted albumin coating remains stable and resistant to displacement by other proteins.Notably,the PDMS with covalently grafted HSA strongly resists the fibrotic capsule formation following a 180-day subcutaneous implantation in C57BL/6 mice.Furthermore,the albumin coating led to reduced recruitment of macrophages and triggered a mild immune activation pattern.Exploration of albumin coatings sourced from various mammalian species has shown that only HSA exhibited a promising anti-FBR effect.The albumin coating method reported here holds the potential to improve and extend the function of silicone-based implants by mitigating the host responses to subcutaneously implanted biomaterials.
基金supported by the National Natural Science Foundation of China(61972356,62036009).
文摘With the popularity of online learning in recent decades,MOOCs(Massive Open Online Courses)are increasingly pervasive and widely used in many areas.Visualizing online learning is particularly important because it helps to analyze learner performance,evaluate the effectiveness of online learning platforms,and predict dropout risks.Due to the large-scale,high-dimensional,and heterogeneous characteristics of the data obtained from online learning,it is difficult to find hidden information.In this paper,we review and classify the existing literature for online learning to better understand the role of visualization in online learning.Our taxonomy is based on four categorizations of online learning tasks:behavior analysis,behavior prediction,learning pattern exploration and assisted learning.Based on our review of relevant literature over the past decade,we also identify several remaining research challenges and future research work.
基金Yixuan Chang and Fanwei Kong contributed equally to the work.We are grateful for the financial support by the Undergraduate Training Programs for Innovations by NEFU(Grant No.202110225105)the National Natural Science Foundation of China(Grant No.51903031)+5 种基金Fundamental Research Funds for the Central Universities(Grant No.2572021CG05)Young Elite Scientists Sponsorship Program by CAST(Grant No.2019QNRC001)China Postdoctoral Science Foundation Funded Project(Grant Nos.2022T150102,2021M700735,2019T120249,2018M630331)Heilongjiang Postdoctoral Fund(Grant Nos.LBH-Z18010,LBH-TZ1001)the Key Program of the Natural Science Foundation of Heilongjiang Province(Grant No.ZD2021C001)the 111 Project(Grant No.B20088).
文摘The efficient utilization of natural lignin,which is the main by-product of the cellulose industry,is crucial for enhancing its economic value,alleviating the environmental burden,and improving ecological security.By taking advantage of the large sp2 hybrid domain of lignin and introducing amino functional groups,new lignin-derived carbon dots(SPN-CDs)with red fluorescence were successfully synthesized.Compared with green and blue fluorescent materials,red SPN-CDs have desirable anti-interference properties of short-wave background and exhibit superior luminescence stability.The SPN-CDs obtained exhibited sensitive and distinctive visible color with fluorescence-dual responses toward hypochlorite.Considering this feature,a portable,low-cost,and sensitive fluorescence sensing paper with a low limit of detection of 0.249μmol∙L^(–1) was fabricated using the SPN-CDs for hypochlorite detection.Furthermore,a new type of visible-light and fluorescence dual-channel information encryption platform was constructed.Low-concentration hypochlorite can be employed as an accessible and efficient information encryption/decryption stimulus,as well as an information“eraser”,facilitating a safe and diversified transmission and convenient decryption of information.This work opens new avenues for high-value-added applications of lignin-based fluorescent materials.
基金supported by the National Natural Science Foundation of China(Grant Nos.11874330,11774320,U1630248,and 11904334)the National Key Research and Development Program of China(Grant No.2017YFA0303104)+5 种基金the National Key R&D Program of the MOST of China(Grant No.2016YFA0300204)the special fund from Institute of Materials,CAEP(Grant No.TP02201904)the Equipment development fund(Grant No.JZX7Y201901SY00900107)the Science Challenge Project(Grant No.TZ2016004)Part of this research used Beamline 03U of the Shanghai Synchron Radiation Facility,which is supported by ME2 project under contract No.11227902 from National Natural Science Foundation of Chinasupported by“Award for Outstanding Member in Youth Innovation Promotion Association CAS”。
文摘LaIrIn5 is a reference compound of the heavy-fermion superconductor LaIrIn5.The lack of f electrons in LaIrIn5 indicates that there should not be any f electron participating in the construction of its Fermi surface.Thus the electronic structure comparison between LaIrIn5 and LaIrIn5 provides a good platform to study the properties of f electrons.Here angle-resolved photoemission spectroscopy(ARPES)measurements and density functional theory(DFT)calculations are performed to study the electronic structures of LaIrIn5 and LaIrIn5.We find the valence band structures of the two materials are similar to each other,except for the absence of f bands in LaIrIn5.By analyzing the Fermi crossings of the three conduction bands of the two materials quantitatively,we find the volumes of the electron pocketsαandβaround the M′point become larger from LaIrIn5 to LaIrIn5,while the hole pocketγaround theΓ′point becomes smaller.Together with the calculation results,we confirm that this is mainly originated from the f-electron contribution,while the lattice-constant difference between LaIrIn5 and LaIrIn5 only has a finite influence.We also give a summary of the f-electron character in its related Ce-115 heavy fermion compounds.Our results may be essential for the complete microscopic understanding of the 115 compounds and the related heavy-fermion systems.
基金supported by the National Key Research and Development Program of China(2020YFB1707700)National Natural Science Foundation of China(61972356,62036009).
文摘With the development of production technology and social needs,sectors of manufacturing are constantly improving.The use of sensors and computers has made it increasingly convenient to collect multimedia data in manufacturing.Targeted,rapid,and detailed analysis based on the type of multimedia data can make timely decisions at different stages of the entire manufacturing process.Visualization and visual analytics are frequently adopted in multimedia data analysis of manufacturing because of their powerful ability to understand,present,and analyze data intuitively and interactively.In this paper,we present a literature review of visualization and visual analytics specifically for manufacturing multimedia data.We classify existing research according to visualization techniques,interaction analysis methods,and application areas.We discuss the differences when visualization and visual analytics are applied to different types of multimedia data in the context of particular examples of manufacturing research projects.Finally,we summarize the existing challenges and prospective research directions.
基金National Key R&D Program of China(Grant No.2022YFA1402203)National Natural Science Foundation of China of China(Grant No.12034004,No.11774061,and No.11774306)+2 种基金Shanghai Municipal Science and Technology(Major Project Grant No.2019SHZDZX01,No.20ZR1405300,and No.23ZR1404500)Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB28000000)Innovation program for Quantum Science and Technology(Grant No.2021ZD0302500).
文摘The search of quantum spin liquid(QSL),an exotic magnetic state with strongly fluctuating and highly entangled spins down to zero temperature,is a main theme in current condensed matter physics.However,there is no smoking gun evidence for deconfined spinons in any QSL candidate so far.The disorders and competing exchange interactions may prevent the formation of an ideal QSL state on frustrated spin lattices.Here we report comprehensive and systematic measurements of the magnetic susceptibility,ultralow-temperature specific heat,muon spin relaxation(μSR),nuclear magnetic resonance(NMR),and thermal conductivity for NaYbSe2 single crystals,in which Yb3+ions with effective spin-1/2 form a perfect triangular lattice.All these complementary techniques find no evidence of long-range magnetic order down to their respective base temperatures.Instead,specific heat,μSR,and NMR measurements suggest the coexistence of quasi-static and dynamic spins in NaYbSe2.The scattering from these quasi-static spins may cause the absence of magnetic thermal conductivity.Thus,we propose a scenario of fluctuating ferrimagnetic droplets immersed in a sea of QSL.This may be quite common on the way pursuing an ideal QSL,and provides a brand new platform to study how a QSL state survives impurities and coexists with other magnetically ordered states.
基金supported by the National Natural Science Foundation of China under Grant 62004028,62090041the Science Foundation of Sichuan under Grant 2022NSFSC0927.
文摘This article overviews the design considerations and state-of-the-art of the ring voltage-controlled oscillator(VCO)-based phase-locked loops(PLLs)for clock generation in different applications.Partic-ularly,the objective of the current work is to evaluate the required PLL performance among the fundamental metrics of power,jitter and area.An in-depth treatment of the mainstream PLL architectures and the associated design techniques enables them to be compared analyt-ically and benchmarked with respect to their figure-of-merit(FoM).The paper also summarizes the key concerns on the selection of dif-ferent circuit techniques to optimize the clock performance under dif-ferent scenarios.