Research on consistency of identifying solitary pulmonary masses with CT

Objective：To research on consistency of identifying solitary pulmonary masses with CT. Methods：Three observers with different working backgrounds in imaging diagnosis individually interpreted the same group images of solitary pulmonary mass, by 12 indexes of objective signs. The differences in interpretation resulted in ante- and post-interpretations were assessed by the x^2 test. The agreement of two interpretations from the same observer was confirmed with the kappa test. A double-blind method was adopted for analysis. Results：The agreement rates of ante- and post-interpreting from the three observers were respectively 82.65%（486/588） 80.27%（472/ 588） and 84.86% （499/588） while their interpreting results were generally accordant without significant difference（x^2 = 4.975, df= 2, P= 0.083） however there was difference between the observer 2 and observer 3（x^2 = 4.875, df= 1, P = 0.027）. There were five indexes with k 〉 0.40 of ante- and post-interpreting results of the three observers, including clarity of nodule borderline, presence of sentus, uniformity of density, existence of cavity and calcification in pathological region, among them, the agreement rate of interpreting borderline and cavity was higher（k 〉 0.07）; the blood vessel convergence poorer（0 〈 k ≤ 0.40）; the other six CT signs of interpretation were slightly different. Conclusion：The ability to identify solitary pulmonary mass was inconsistent, and needs to be improved further.

Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide

In recent years,ionic liquids(ILs)have been widely used in extraction,synthesis,electrochemistry and other fields.Meanwhile,the environmental impact of ILs has been attracting a lot of attention,and eco-friendly treatment for ILs is becoming a necessary subject.In this study,photocatalytic degradations of benzothiazole ILs catalyzed by titanium dioxide(TiO2)and silver-loaded titanium dioxide(Ag/TiO2)were studied for the first time.The degradation of benzothiazole hexafluorophosphate([C4 Bth]PF6)could reach more than 99%within 240 min with the catalysis of TiO2.To improve catalytic efficiency,Ag/TiO2 was synthesized and characterized by UV–Vis diffuse reflectance absorption spectra(DRS)and X-ray photoelectron spectroscopy(XPS).The degradation of[C4 Bth]PF6 could reach more than 99%within 120 min in the degradation catalyzed by Ag/TiO2.The photodegradation products of benzothiazole ILs are composed of inorganic substances or organic substances with simpler structures,which are easier to decompose and less toxic.The degradation system proposed by this study could provide a simple,green,safe,and economical method for the efficient treatment of benzothiazole ILs.

A Biproportional Construction Algorithm for Correctly Calculating Fourier Series of Aperiodic Non-Sinusoidal Signal

The Fourier series (FS) applies to a periodic non-sinusoidal function satisfying the Dirichlet conditions, whereas the being-processed function in practical applications is usually an aperiodic non-sinusoidal signal. When is aperiodic, its calculated FS is not correct, which is still a challenging problem. To overcome the problem, we derive a direct calculation algorithm, a constant iteration algorithm, and an optimal iteration algorithm. The direct calculation algorithm correctly calculates its Fourier coefficients (FCs) when is periodic and satisfies the Dirichlet conditions. Both the constant iteration algorithm and the optimal iteration algorithm provide an idea of determining the states of . From the idea, we obtain an algorithm for determining the states of based on the optimal iteration algorithm. In the algorithm, the variable iteration step is introduced; thus, we present an algorithm for determining the states of based on the variable iteration step. The presented algorithm accurately determines the states of . On the basis of these algorithms, we build a biproportional construction theory. The theory consists of a first and a second proportional construction theory. The former correctly calculates the FCs of at the present sampling time

cPCN-Regulated SnO_(2) Composites Enables Perovskite Solar Cell with Efficiency Beyond 23%

Efficient electron transport layers(ETLs)not only play a crucial role in promoting carrier separation and electron extraction in perovskite solar cells(PSCs)but also significantly affect the process of nucleation and growth of the perovskite layer.Herein,crystalline polymeric carbon nitrides(cPCN)are introduced to regulate the electronic properties of SnO_(2) nanocrystals,resulting in cPCN-composited SnO_(2)(SnO_(2)-cPCN)ETLs with enhanced charge transport and perovs-kite layers with decreased grain boundaries.Firstly,SnO_(2)-cPCN ETLs show three times higher electron mobility than pristine SnO_(2) while offering better energy level alignment with the perovskite layer.The SnO_(2)-cPCN ETLs with decreased wettability endow the perovskite films with higher crystallinity by retarding the crystallization rate.In the end,the power conversion efficiency(PCE)of planar PSCs can be boosted to 23.17%with negligible hysteresis and a steady-state efficiency output of 21.98%,which is one of the highest PCEs for PSCs with modified SnO_(2) ETLs.SnO_(2)-cPCN based devices also showed higher stability than pristine SnO_(2),maintaining 88%of the initial PCE after 2000 h of storage in the ambient environment(with controlled RH of 30%±5%)without encapsulation.