Stress separation is usually achieved by solving differential equations of equilibrium after parameter determination from isochromatics and isoclinics.The numerical error resulting from the stress determination is a m...Stress separation is usually achieved by solving differential equations of equilibrium after parameter determination from isochromatics and isoclinics.The numerical error resulting from the stress determination is a main concern as it is always a function of parameters in discretization.To improve the accuracy of stress calculation,a novel meshless barycentric rational interpolation collocation method(BRICM)is proposed.The derivatives of the shear stress on the calculation path are determined by using the differential matrix which converts the differential form of the equations of equilibrium into a series of algebraic equations.The advantage of the proposed method is that the auxiliary lines,grids,and error accumulation which are commonly used in traditional shear difference methods(SDMs)are not required.Simulation and experimental results indicate that the proposed meshless method is able to provide high computational accuracy in the full-field stress determination.展开更多
Manganese dioxide(MnO_(2)),as a cathode material for multivalent ion(such as Mg^(2+)and Al^(3+))storage,is investigated due to its high initial capacity.However,during multivalent ion insertion/extraction,the crystal ...Manganese dioxide(MnO_(2)),as a cathode material for multivalent ion(such as Mg^(2+)and Al^(3+))storage,is investigated due to its high initial capacity.However,during multivalent ion insertion/extraction,the crystal structure of MnO_(2)partially collapses,leading to fast capacity decay in few charge/discharge cycles.Here,through pre-intercalating potassium-ion(K+)intoδ-MnO_(2),we synthesize a potassium ion pre-intercalated MnO_(2),K_(0.21)MnO_(2)·0.31H_(2)O(KMO),as a reliable cathode material for multivalent ion batteries.The as-prepared KMO exhibits a high reversible capacity of 185 mAh/g at 1 A/g,with considerable rate performance and improved cycling stability in 1 mol/L MgSO_(4)electrolyte.In addition,we observe that aluminum-ion(Al^(3+))can also insert into a KMO cathode.This work provides a valid method for modifcation of manganesebased oxides for aqueous multivalent ion batteries.展开更多
基金Project supported by the National Key R&D Program of China(No.2018YFF01014200)the National Natural Science Foundation of China(Nos.11727804,11872240,12072184,12002197,and 51732008)the China Postdoctoral Science Foundation(Nos.2020M671070 and 2021M692025)。
文摘Stress separation is usually achieved by solving differential equations of equilibrium after parameter determination from isochromatics and isoclinics.The numerical error resulting from the stress determination is a main concern as it is always a function of parameters in discretization.To improve the accuracy of stress calculation,a novel meshless barycentric rational interpolation collocation method(BRICM)is proposed.The derivatives of the shear stress on the calculation path are determined by using the differential matrix which converts the differential form of the equations of equilibrium into a series of algebraic equations.The advantage of the proposed method is that the auxiliary lines,grids,and error accumulation which are commonly used in traditional shear difference methods(SDMs)are not required.Simulation and experimental results indicate that the proposed meshless method is able to provide high computational accuracy in the full-field stress determination.
基金supported by the National Natural Science Foundation of China(Grant No.52102264)the Leading Edge Technology of Jiangsu Province(BK20220009)the Open Project Program of Wuhan National Laboratory for Optoelectronics(No.2020WNLOKF011).
文摘Manganese dioxide(MnO_(2)),as a cathode material for multivalent ion(such as Mg^(2+)and Al^(3+))storage,is investigated due to its high initial capacity.However,during multivalent ion insertion/extraction,the crystal structure of MnO_(2)partially collapses,leading to fast capacity decay in few charge/discharge cycles.Here,through pre-intercalating potassium-ion(K+)intoδ-MnO_(2),we synthesize a potassium ion pre-intercalated MnO_(2),K_(0.21)MnO_(2)·0.31H_(2)O(KMO),as a reliable cathode material for multivalent ion batteries.The as-prepared KMO exhibits a high reversible capacity of 185 mAh/g at 1 A/g,with considerable rate performance and improved cycling stability in 1 mol/L MgSO_(4)electrolyte.In addition,we observe that aluminum-ion(Al^(3+))can also insert into a KMO cathode.This work provides a valid method for modifcation of manganesebased oxides for aqueous multivalent ion batteries.
