A superior carbocatalyst ultrahigh N-doped graphene(NG) was prepared by a novel self-sacrificial templating method of one-step annealing vitamin B_(9).The NG catalyst with pyrolysis temperature of 800℃(abbreviated VB...A superior carbocatalyst ultrahigh N-doped graphene(NG) was prepared by a novel self-sacrificial templating method of one-step annealing vitamin B_(9).The NG catalyst with pyrolysis temperature of 800℃(abbreviated VB_(9)-NG-800) has an ultrahigh nitrogen content of 13.5 wt% and demonstrated the highest activity for the oxidation of bio-based alcohols and terpenes with molecular oxygen without any additives.Systematic characterizations and quantum-chemical calculations further manifested that high contents of graphitic N and pyridinic N species in VB_(9)-NG-800 promoted the generation of·O_(2)^(-)active species from molecular oxygen effortlessly,resulting in excellent catalytic performance for aerobic oxidation.展开更多
基金financial support from the National Natural Science Foundations of China (22068013,31570560)21922513 the Natural Science Foundations of Jiangxi Province (20192ACBL20025)the Science and Technology Programs of Jiangxi Province Department of Education (GJJ160272)。
文摘A superior carbocatalyst ultrahigh N-doped graphene(NG) was prepared by a novel self-sacrificial templating method of one-step annealing vitamin B_(9).The NG catalyst with pyrolysis temperature of 800℃(abbreviated VB_(9)-NG-800) has an ultrahigh nitrogen content of 13.5 wt% and demonstrated the highest activity for the oxidation of bio-based alcohols and terpenes with molecular oxygen without any additives.Systematic characterizations and quantum-chemical calculations further manifested that high contents of graphitic N and pyridinic N species in VB_(9)-NG-800 promoted the generation of·O_(2)^(-)active species from molecular oxygen effortlessly,resulting in excellent catalytic performance for aerobic oxidation.
