The phase transformation and microstructure in Ti-22Al-25Nb alloy are extremely complex.In this work,the morphology evolution of the O phase during the heating and cooling process was investigated by electron backscat...The phase transformation and microstructure in Ti-22Al-25Nb alloy are extremely complex.In this work,the morphology evolution of the O phase during the heating and cooling process was investigated by electron backscatter diffraction(EBSD)and first-principles calculations.The results show that the O→α_(2)phase transformation process during the heating process is as follows:spheroidization of the O phase occurs first,then theα_(2)phase nucleates in the spheroidized O phase,grows and replaces the O phase,completing the O→α_(2)phase transformation.In the meanwhile,the diffusion of Nb from Nb-poor O to Nb-rich B2 phases is a back-diffusion process.According to first-principles calculations,the driving force of the O→α_(2)phase transformation is the difference in the free energies of formation for the two phases(0.09 eV/atom).When the Nb content is greater than 15.625%,the lattice distortion of theα_(2)phase sharply increases,and the distortion energy drives the back-diffusion of Nb.During the cooling process,theα_(2)→O phase transformation is difficult and slow due to the difficult diffusion of Nb from the B2 toα_(2)phases.When holding for 60 min at 960℃,the coarseα_(2)phase gradually transforms to the O phase from the margin to the inside,forming a dispersed mixed structure of the O andα_(2)phases.During the B2→O transformation,the nucleation of the O phase induces a high stress region,in the range of approximately 200 nm.展开更多
基金the financial support from the National Natural Science Foundation of China under Grant No.52005129。
文摘The phase transformation and microstructure in Ti-22Al-25Nb alloy are extremely complex.In this work,the morphology evolution of the O phase during the heating and cooling process was investigated by electron backscatter diffraction(EBSD)and first-principles calculations.The results show that the O→α_(2)phase transformation process during the heating process is as follows:spheroidization of the O phase occurs first,then theα_(2)phase nucleates in the spheroidized O phase,grows and replaces the O phase,completing the O→α_(2)phase transformation.In the meanwhile,the diffusion of Nb from Nb-poor O to Nb-rich B2 phases is a back-diffusion process.According to first-principles calculations,the driving force of the O→α_(2)phase transformation is the difference in the free energies of formation for the two phases(0.09 eV/atom).When the Nb content is greater than 15.625%,the lattice distortion of theα_(2)phase sharply increases,and the distortion energy drives the back-diffusion of Nb.During the cooling process,theα_(2)→O phase transformation is difficult and slow due to the difficult diffusion of Nb from the B2 toα_(2)phases.When holding for 60 min at 960℃,the coarseα_(2)phase gradually transforms to the O phase from the margin to the inside,forming a dispersed mixed structure of the O andα_(2)phases.During the B2→O transformation,the nucleation of the O phase induces a high stress region,in the range of approximately 200 nm.
