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Self-Oscillated Growth Formation of Standing Ultrathin Nanosheets out of Uniform Ge/Si Superlattice Nanowires
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作者 甘鑫 安钧洋 +5 位作者 王军转 刘宗光 徐骏 施毅 陈坤基 余林蔚 《Chinese Physics Letters》 SCIE EI CAS CSCD 2023年第6期27-32,共6页
Self-oscillation is an intriguing and omnipresent phenomenon that governs a broad range of growth dynamics and formation of nanoscale periodic and delicate heterostructures.A self-oscillating growth phenomenon of cata... Self-oscillation is an intriguing and omnipresent phenomenon that governs a broad range of growth dynamics and formation of nanoscale periodic and delicate heterostructures.A self-oscillating growth phenomenon of catalyst droplets,consuming surface-coating a-Si/a-Ge bilayer,is exploited to accomplish a high-frequency alternating growth of ultrathin crystalline Si and Ge(c-Si/c-Ge)nano-slates,with Ge-rich layer thickness of 14–19 nm,embedded within a superlattice nanowire structure,with pre-known position and uniform channel diameter.A subsequent selective etching of the Ge-rich segments leaves a chain of ultrafine standing c-Si nanosheets down to~6 nm thick,without the use of any expensive high-resolution lithography and growth modulation control.A ternary-phase-competition model has been established to explain the underlying formation mechanism of this nanoscale self-oscillating growth dynamics.It is also suggested that these ultrathin nanosheets could help to produce ultrathin fin-channels for advanced electronics,or provide size-specified trapping sites to capture and position hetero nanoparticle for high-precision labelling or light emission. 展开更多
关键词 OSCILLATING consuming sheets
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超薄三维径向结叠层高开启电位(1.15V)光阴极用于太阳能制氢
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作者 张少波 黄辉庭 +8 位作者 张之杰 冯建勇 刘宗光 王军转 徐骏 李朝升 余林蔚 陈坤基 邹志刚 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第7期1842-1850,共9页
a-Si:H薄膜中存在的无序结构和缺陷会大幅减小载流子扩散长度.因此,传统的二维平面叠层光伏器件需要在有效的载流子收集(较短的载流子分离距离)和足够的光吸收(较厚的光吸收层厚度)之间平衡.三维a-Si:H径向结薄膜光伏器件可以很好地解... a-Si:H薄膜中存在的无序结构和缺陷会大幅减小载流子扩散长度.因此,传统的二维平面叠层光伏器件需要在有效的载流子收集(较短的载流子分离距离)和足够的光吸收(较厚的光吸收层厚度)之间平衡.三维a-Si:H径向结薄膜光伏器件可以很好地解决传统平面结中这一难题,它是直接在气-液-固法生长的竖直站立的硅纳米线框架上构建.三维硅米线框架具有很强的光捕获能力,允许使用十分薄的光吸收层(<100 nm),有助于解除光学吸收长度与电学载流子收集路径之间的耦合.薄的吸收层有助于改善光致衰减,提升对材料质量的容忍程度,降低对高品质、成本贵的材料的需求.本文提出了将先进的叠层设计与独特的三维硅纳米线框架相结合的新策略,设计了具有高开启电位的光电阴极,以推动太阳能制氢的应用进程.提出了径向结叠层薄膜光电阴极,其直接在气-液-固法生长的硅纳米线上构筑,由两个径向堆叠的p-i-n结组成.外层p-i-n结的吸收层为非晶硅,用于吸收短波长的光;内层p-i-n结的吸收层则为非晶硅锗合金,用于吸收长波长的光.随机分布的硅纳米线框架具有优异的陷光效应,可允许使用非常薄的非晶硅(~50 nm)和非晶硅锗(~40 nm)吸收层.在100 mW/cm^(2)的太阳光照射下,该径向结叠层光阴极在覆盖2.5 nm厚的Pt催化剂后,在0.1 mol/L磷酸钾水溶液(KPi,pH=7)电解液中具有1.15 V vs.RHE的高开启电位,零偏压下的光电流为2.98 mA/cm^(2),外加偏压下的光电转换效率为1.72%.综上,本文展现了三维径向结叠层技术的独特潜力,有利于发展下一代高开启电位、高效、低成本、耐用、可大规模制备的光阴极. 展开更多
关键词 太阳能制氢 三维径向串联结 非晶硅基光电阴极 超薄吸收层 高起始电位
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Boundedness of some integral operators and commutators on homogeneous Herz spaces with three variable exponents
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作者 Xia YU zongguang liu 《Frontiers of Mathematics in China》 SCIE CSCD 2021年第1期211-237,共27页
We obtain the boundedness of some integral operators and commutators on homogeneous Herz spaces with three variable exponents K^(˙α(⋅))_(p(⋅),q(⋅)),such as some sublinear operators,the fractional integral and its co... We obtain the boundedness of some integral operators and commutators on homogeneous Herz spaces with three variable exponents K^(˙α(⋅))_(p(⋅),q(⋅)),such as some sublinear operators,the fractional integral and its commutator. 展开更多
关键词 Sublinear operator fractional integral COMMUTATOR homogeneous Herz space variable exponent
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