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具有轴手性化合物的对映选择性合成研究进展
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作者 赵熙林 涂星宇 +3 位作者 李宗宣 董锐 蒋博 苗志伟 《大学化学》 CAS 2024年第11期158-173,共16页
轴手性化合物具有独特的手性结构,在不对称催化、医药、光电材料和天然产物等诸多领域具有重要应用。近年来轴手性化合物对映选择性合成取得了较大的研究进展,在手性轴的类型上除了传统的C―C轴和C―N轴以外,N―N轴、C―S轴、C―O轴和C... 轴手性化合物具有独特的手性结构,在不对称催化、医药、光电材料和天然产物等诸多领域具有重要应用。近年来轴手性化合物对映选择性合成取得了较大的研究进展,在手性轴的类型上除了传统的C―C轴和C―N轴以外,N―N轴、C―S轴、C―O轴和C―B轴手性化合物的不对称合成也取得了新的突破。本文综述了近年来各类轴手性化合物不对称合成的研究进展,并对该领域未来的发展方向进行了展望。 展开更多
关键词 轴手性化合物 对映选择性合成 研究进展
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An Improved YOLOv8-Based Method for Real-Time Detection of Harmful Tea Leaves in Complex Backgrounds
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作者 Xin Leng Jiakai Chen +2 位作者 Jianping Huang Lei Zhang zongxuan li 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第11期2963-2981,共19页
Tea,a globally cultivated crop renowned for its uniqueflavor profile and health-promoting properties,ranks among the most favored functional beverages worldwide.However,diseases severely jeopardize the production and qu... Tea,a globally cultivated crop renowned for its uniqueflavor profile and health-promoting properties,ranks among the most favored functional beverages worldwide.However,diseases severely jeopardize the production and quality of tea leaves,leading to significant economic losses.While early and accurate identification coupled with the removal of infected leaves can mitigate widespread infection,manual leaves removal remains time-con-suming and expensive.Utilizing robots for pruning can significantly enhance efficiency and reduce costs.How-ever,the accuracy of object detection directly impacts the overall efficiency of pruning robots.In complex tea plantation environments,complex image backgrounds,the overlapping and occlusion of leaves,as well as small and densely harmful leaves can all introduce interference factors.Existing algorithms perform poorly in detecting small and densely packed targets.To address these challenges,this paper collected a dataset of 1108 images of harmful tea leaves and proposed the YOLO-DBD model.The model excels in efficiently identifying harmful tea leaves with various poses in complex backgrounds,providing crucial guidance for the posture and obstacle avoidance of a robotic arm during the pruning process.The improvements proposed in this study encompass the Cross Stage Partial with Deformable Convolutional Networks v2(C2f-DCN)module,Bi-Level Routing Atten-tion(BRA),Dynamic Head(DyHead),and Focal Complete Intersection over Union(Focal-CIoU)Loss function,enhancing the model’s feature extraction,computation allocation,and perception capabilities.Compared to the baseline model YOLOv8s,mean Average Precision at IoU 0.5(mAP0.5)increased by 6%,and Floating Point Operations Per second(FLOPs)decreased by 3.3 G. 展开更多
关键词 Harmful tea leaves YOLO-DBD Focal-CIoU Loss dynamic head Bi-Level Routing Attention
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Effects of Rubber Shock Absorber on the Flywheel Micro Vibration in the Satellite Imaging System 被引量:5
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作者 Changcheng DENG Deqiang MU +1 位作者 Xuezhi JIA zongxuan li 《Photonic Sensors》 SCIE EI CAS CSCD 2016年第4期372-384,共13页
When a satellite is in orbit, its flywheel will generate micro vibration and affect the imaging quality of the camera. In order to reduce this effect, a rubber shock absorber is used, and a numerical model and an expe... When a satellite is in orbit, its flywheel will generate micro vibration and affect the imaging quality of the camera. In order to reduce this effect, a rubber shock absorber is used, and a numerical model and an experimental setup are developed to investigate its effect on the micro vibration in the study. An integrated model is developed for the system, and a ray tracing method is used in the modeling. The spot coordinates and displacements of the image plane are obtained, and the modulate transfer function (MTF) of the system is calculated. A satellite including a rubber shock absorber is designed, and the experiments are carried out. Both simulation and experiments results show that the MTF increases almost 10 %, suggesting the rubber shock absorber is useful to decrease the flywheel vibration. 展开更多
关键词 Micro vibration FLYWHEEL rubber shock absorber integrated modeling MTF isolation experiment
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