A new type of AlTiN coating containing about 29.13 at.% Al,16.02 at.% Ti and 54.85 at.% N was prepared by arc ion plating technology. The coating is composed of singular fcc-(Al, Ti)N phase and has no hcp-AlN phase ...A new type of AlTiN coating containing about 29.13 at.% Al,16.02 at.% Ti and 54.85 at.% N was prepared by arc ion plating technology. The coating is composed of singular fcc-(Al, Ti)N phase and has no hcp-AlN phase to be formed. Due to the high content of beneficial element Al, the hardness and effective elastic modulus of the coating are up to 33.9 and 486.1 GPa, respectively. The adhesion strength between the coating and substrate is about 39.7 N. Electro- chemical test shows that the corrosion current density of the AlTiN coating is nearly one-sixth of the substrate, and the charge transfer resistance Rct of the AlTiN coating is much larger than that of the substrate, which means that the coating could act as a protective barrier between the substrate and corrosive electrolyte, enhancing the corrosion resistance.展开更多
基金supported by the National Nature Science Foundation of China (Grant Nos. 51501130 and 51301181)the Tianjin Key Research Program of Application Foundation and Advanced Technology (Grant No. 15JCZDJC39700)+2 种基金the Innovation Team Training Plan of Tianjin Universities and colleges (Grant No. TD12-5043)the Tianjin Science and Technology correspondent project (16JCTPJC49500)Research Development Foundation of Tianjin University of Technology and Education (Grant No. KJ1422)
文摘A new type of AlTiN coating containing about 29.13 at.% Al,16.02 at.% Ti and 54.85 at.% N was prepared by arc ion plating technology. The coating is composed of singular fcc-(Al, Ti)N phase and has no hcp-AlN phase to be formed. Due to the high content of beneficial element Al, the hardness and effective elastic modulus of the coating are up to 33.9 and 486.1 GPa, respectively. The adhesion strength between the coating and substrate is about 39.7 N. Electro- chemical test shows that the corrosion current density of the AlTiN coating is nearly one-sixth of the substrate, and the charge transfer resistance Rct of the AlTiN coating is much larger than that of the substrate, which means that the coating could act as a protective barrier between the substrate and corrosive electrolyte, enhancing the corrosion resistance.