Considering the features of martensitic transformation in Fe-Mn-Si based alloys, the Landau theory is established by introducing the density of stacking faults as a new order parameter η and the corresponding free en...Considering the features of martensitic transformation in Fe-Mn-Si based alloys, the Landau theory is established by introducing the density of stacking faults as a new order parameter η and the corresponding free energy function. By using such an order parameter, the stacking fault mechanism of the nucleation and growth for the γ(fcc) →ε(hcp) martensitic transformation can be reasonably explained, and a further detailed mechanism is proposed. The stacking faults are generated and overlapped in an irregular form at the beginning and then becoming regular to create some transition structures till a stable phase forms at a certain temperature. The importance of the interface soliton is to complete the transformations into various structures of martensite but not the twinned one. The thermodynamics of fcc→hcp transformation and those between different transition structures are described by the free energy function established in the present note.展开更多
基金This work was financially supported by the National Natural Science Foundation of China (Grant No. 59671023)the Emerson Electric Corporation of U.S.A.
文摘Considering the features of martensitic transformation in Fe-Mn-Si based alloys, the Landau theory is established by introducing the density of stacking faults as a new order parameter η and the corresponding free energy function. By using such an order parameter, the stacking fault mechanism of the nucleation and growth for the γ(fcc) →ε(hcp) martensitic transformation can be reasonably explained, and a further detailed mechanism is proposed. The stacking faults are generated and overlapped in an irregular form at the beginning and then becoming regular to create some transition structures till a stable phase forms at a certain temperature. The importance of the interface soliton is to complete the transformations into various structures of martensite but not the twinned one. The thermodynamics of fcc→hcp transformation and those between different transition structures are described by the free energy function established in the present note.