Microporous organic polymers(MOPs) have attracted considerable research interest because of their well-defined porosity,high surface area, lightweight nature, and tunable surface chemistry. The morphology of MOPs are ...Microporous organic polymers(MOPs) have attracted considerable research interest because of their well-defined porosity,high surface area, lightweight nature, and tunable surface chemistry. The morphology of MOPs are demonstrated to play a significant role in various applications although limited examples manifesting the importance of the MOP morphology in numerous applications have been reported. This review summarizes the recent progress in the design of MOPs using different techniques, including hard and soft template and direct synthesis methods. In addition, their applications, which possibly attribute to their shape, are discussed. Furthermore, the advantages and disadvantages of different methods are discussed, as well as their development and future challenges.展开更多
Covalent organic frameworks(COFs) have been attracting growing concerns since the first report in2005. With the well-defined and ordered structures, COFs express big potential in mass transport, storage/separation and...Covalent organic frameworks(COFs) have been attracting growing concerns since the first report in2005. With the well-defined and ordered structures, COFs express big potential in mass transport, storage/separation and energy conversion applications. From the perspective of both theory and application,the construction of crystalline COFs with high quality and variety is highly worth to be devoted to. To give insight into the crystalline process of COFs and deeply understand the factors of COFs crystallization,this review was concentrated on the recent progress in construction of crystalline COFs. Accordingly, the types and crystallization process of COFs were summarized firstly. And then the factors on crystallinity and the measures for improving the crystallinity of COFs were classified and discussed in detail. Finally,the perspectives for the development of COFs in further was given at the end of this review.展开更多
基金supported by the National Natural Science Foundation of China(51902121,52073110,22071072,51872107,21975090,and 21801086)the Fundamental Research Funds for the Central Universities of China(2662018QD011,2662018PY052,and 2662019PY023)the Natural Science Foundation of Hubei Province(2019CFB322)。
基金supported by the National Natural Science Foundation of China(21474033)the International Science and Technology Cooperation Program of China(2016YFE0124400)the Program for Huazhong University of Science and Technology Interdisciplinary Innovation Team(2016JCTD104)
文摘Microporous organic polymers(MOPs) have attracted considerable research interest because of their well-defined porosity,high surface area, lightweight nature, and tunable surface chemistry. The morphology of MOPs are demonstrated to play a significant role in various applications although limited examples manifesting the importance of the MOP morphology in numerous applications have been reported. This review summarizes the recent progress in the design of MOPs using different techniques, including hard and soft template and direct synthesis methods. In addition, their applications, which possibly attribute to their shape, are discussed. Furthermore, the advantages and disadvantages of different methods are discussed, as well as their development and future challenges.
基金Natural Science Foundation of Shandong Province, China (No. ZR2021QB070)。
文摘Covalent organic frameworks(COFs) have been attracting growing concerns since the first report in2005. With the well-defined and ordered structures, COFs express big potential in mass transport, storage/separation and energy conversion applications. From the perspective of both theory and application,the construction of crystalline COFs with high quality and variety is highly worth to be devoted to. To give insight into the crystalline process of COFs and deeply understand the factors of COFs crystallization,this review was concentrated on the recent progress in construction of crystalline COFs. Accordingly, the types and crystallization process of COFs were summarized firstly. And then the factors on crystallinity and the measures for improving the crystallinity of COFs were classified and discussed in detail. Finally,the perspectives for the development of COFs in further was given at the end of this review.
