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Crystal Structure and Spectra of the Complex Eu(p-ClC_6H_4COO)_3C_(12)H_8N_2 被引量:1
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作者 金林培 王瑞芬 +1 位作者 李林书 吕少哲 《Journal of Rare Earths》 SCIE EI CAS CSCD 1996年第3期161-166,共6页
The europium p-chlorobenzoate complex with 1, 10-phenanthroline was synthesizd in the ethanol solution. The crystal structure of the complex, Eu (p-ClBA)3·phen (p-ClBA: p-chlorobenzoate, phen:1,10-phenanthroline)... The europium p-chlorobenzoate complex with 1, 10-phenanthroline was synthesizd in the ethanol solution. The crystal structure of the complex, Eu (p-ClBA)3·phen (p-ClBA: p-chlorobenzoate, phen:1,10-phenanthroline), was determined by the X-ray diffraction. The complex crystalizes in triclinic,space group Pl with a=1. 0054 (2), b=1.1858(3), c=1.4349 (7) nm,α=110. 52(3), β=96. 52(3), γ= 101. 95(2)°, V=1. 5348(8) nm3, z=1, Dx=1. 729 g/cm3,Mr=1597. 72, T= 299±1 K. The coordination number of the europium ion is eight. The coordination geometry of the Eu3+ ion is a distorted square antiprism. In the 7F→5Do excitation spectrum of the complex, there is one sharp peak at 580. 04 nm. This shows that the complex has one Eu3+ site only. 5Do→7Fj(j=1 ̄4) luminescence spectra have been obtained by the selectively excited 5Do level of the complex, which indicates that Eu3+ ions in the complex have equally chemical environments. Raman spectrum shows more than one coordination modes for the carboxylate groups in the complex. This is in agreement with the results of the structure determination. 展开更多
关键词 Europium complex Crystal structure SPECTRA
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