This paper reports the experimental data of metastable phase equilibrium of Li+,K+/Cl-,CO32-—H2O quaternary system at 298K for Zhabuye salt lake in Tibet,from which the metastable phase diagrams were plotted This qua...This paper reports the experimental data of metastable phase equilibrium of Li+,K+/Cl-,CO32-—H2O quaternary system at 298K for Zhabuye salt lake in Tibet,from which the metastable phase diagrams were plotted This quaternary system is a simple evtonic type,and no double salt or solid solution is formed.The isotherm diagram consists of two invariant point,five univariant curves and four crystallization fields corresponding to K2CO3·3/2H2O,KCl,Li2CO3 and LiCl·H2O salt.It is found in the metastable equilibrium phase diagram that: ① the crystallization speciations of K2CO3·3/2H2O,LiCl·H2O,Li2CO3,and KCl are the same as those in the stable equilibrium one;② potassium chloride field is also enlarged.展开更多
文摘This paper reports the experimental data of metastable phase equilibrium of Li+,K+/Cl-,CO32-—H2O quaternary system at 298K for Zhabuye salt lake in Tibet,from which the metastable phase diagrams were plotted This quaternary system is a simple evtonic type,and no double salt or solid solution is formed.The isotherm diagram consists of two invariant point,five univariant curves and four crystallization fields corresponding to K2CO3·3/2H2O,KCl,Li2CO3 and LiCl·H2O salt.It is found in the metastable equilibrium phase diagram that: ① the crystallization speciations of K2CO3·3/2H2O,LiCl·H2O,Li2CO3,and KCl are the same as those in the stable equilibrium one;② potassium chloride field is also enlarged.
