High-temperature oxidation behavior of ferrovanadium(FeV_(2)O_(4))and ferrochrome(FeCr_(2)O_(4))spinels is crucial for the application of spinel as an energy material,as well as for the clean usage of high-chromium va...High-temperature oxidation behavior of ferrovanadium(FeV_(2)O_(4))and ferrochrome(FeCr_(2)O_(4))spinels is crucial for the application of spinel as an energy material,as well as for the clean usage of high-chromium vanadium slag.Herein,the nonisothermal oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)prepared by high-temperature solid-state reaction was examined by thermogravimetry and X-ray diffraction(XRD)at heating rates of 5,10,and 15 K/min.The apparent activation energy was determined by the Kissinger-Akahira-Sunose(KAS)method,whereas the mechanism function was elucidated by the Malek method.Moreover,in-situ XRD was conducted to deduce the phase transformation of the oxidation mechanism for FeV_(2)O_(4)and FeCr_(2)O_(4).The results reveal a gradual increase in the overall apparent activation energies for FeV_(2)O_(4)and FeCr_(2)O_(4)during oxidation.Four stages of the oxidation process are observed based on the oxidation conversion rate of each compound.The oxidation mechanisms of FeV_(2)O_(4)and FeCr_(2)O_(4)are complex and have distinct mechanisms.In particular,the chemical reaction controls the entire oxidation process for FeV_(2)O_(4),whereas that for FeCr_(2)O_(4)transitions from a three-dimensional diffusion model to a chemical reaction model.According to the in-situ XRD results,numerous intermediate products are observed during the oxidation process of both compounds,eventually resulting in the final products FeVO_(4)and V2O_(5)for FeV_(2)O_(4)and Fe_(2)O_(3)and Cr_(2)O_(3)for FeCr_(2)O_(4),respectively.展开更多
The unique in-plane and out-of-plane anisotropy of α-MoO_(3) has attracted considerable interest with regard to potential optoelectronic applications. However, most research has focused on the mid-infrared spectrum, ...The unique in-plane and out-of-plane anisotropy of α-MoO_(3) has attracted considerable interest with regard to potential optoelectronic applications. However, most research has focused on the mid-infrared spectrum, leaving its properties and applications in the visible and near-infrared light spectrum less explored. This study advances the understanding of waveguiding properties of α-MoO_(3) by near-field imaging of the waveguide modes along the [100] and [001] directions of α-MoO_(3) flakes at 633 nm and 785 nm. We investigate the effects of flake thickness and documented the modes' dispersion relationships, which is crucial for tailoring the optical responses of α-MoO_(3) in device applications. Our findings enhance the field of research into α-MoO_(3), highlighting its utility in fabricating next-generation optoelectronic devices due to its unique optically anisotropic waveguide.展开更多
基金This work was supported by the National Natural Science Foundation of China(No.52004044)the Natural Science Foundation of Chongqing,China(Nos.cstb2022nscqmsx0801 and cstc2021jcyj-msxmx0882)+2 种基金the Foundation of Chongqing University of Science and Technology(No.ckrc2022030)the Graduate Research Innovation Project of Chongqing University of Science and Technology(No.YKJCX2220216)the National Undergraduate Training Program for Innovation and Entrepreneurship(No.202311551007).
文摘High-temperature oxidation behavior of ferrovanadium(FeV_(2)O_(4))and ferrochrome(FeCr_(2)O_(4))spinels is crucial for the application of spinel as an energy material,as well as for the clean usage of high-chromium vanadium slag.Herein,the nonisothermal oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)prepared by high-temperature solid-state reaction was examined by thermogravimetry and X-ray diffraction(XRD)at heating rates of 5,10,and 15 K/min.The apparent activation energy was determined by the Kissinger-Akahira-Sunose(KAS)method,whereas the mechanism function was elucidated by the Malek method.Moreover,in-situ XRD was conducted to deduce the phase transformation of the oxidation mechanism for FeV_(2)O_(4)and FeCr_(2)O_(4).The results reveal a gradual increase in the overall apparent activation energies for FeV_(2)O_(4)and FeCr_(2)O_(4)during oxidation.Four stages of the oxidation process are observed based on the oxidation conversion rate of each compound.The oxidation mechanisms of FeV_(2)O_(4)and FeCr_(2)O_(4)are complex and have distinct mechanisms.In particular,the chemical reaction controls the entire oxidation process for FeV_(2)O_(4),whereas that for FeCr_(2)O_(4)transitions from a three-dimensional diffusion model to a chemical reaction model.According to the in-situ XRD results,numerous intermediate products are observed during the oxidation process of both compounds,eventually resulting in the final products FeVO_(4)and V2O_(5)for FeV_(2)O_(4)and Fe_(2)O_(3)and Cr_(2)O_(3)for FeCr_(2)O_(4),respectively.
基金Project supported by the National Key Research and Development Program of China(Grant No.2022YFA1203500)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB30000000)the CAS Youth Interdisciplinary Team。
文摘The unique in-plane and out-of-plane anisotropy of α-MoO_(3) has attracted considerable interest with regard to potential optoelectronic applications. However, most research has focused on the mid-infrared spectrum, leaving its properties and applications in the visible and near-infrared light spectrum less explored. This study advances the understanding of waveguiding properties of α-MoO_(3) by near-field imaging of the waveguide modes along the [100] and [001] directions of α-MoO_(3) flakes at 633 nm and 785 nm. We investigate the effects of flake thickness and documented the modes' dispersion relationships, which is crucial for tailoring the optical responses of α-MoO_(3) in device applications. Our findings enhance the field of research into α-MoO_(3), highlighting its utility in fabricating next-generation optoelectronic devices due to its unique optically anisotropic waveguide.
