为量化评价新能源汽车动力电池回收利用过程的环境效益,为报废动力电池管理体系和回收再利用相关标准的完善提供支撑,助力国家“双碳”目标的实现,以三元锂电池为研究对象,选取典型的动力电池回收利用场景,将三元锂电池的生命周期划分为...为量化评价新能源汽车动力电池回收利用过程的环境效益,为报废动力电池管理体系和回收再利用相关标准的完善提供支撑,助力国家“双碳”目标的实现,以三元锂电池为研究对象,选取典型的动力电池回收利用场景,将三元锂电池的生命周期划分为4个阶段:原材料获取、制造装配、使用和报废回收,并建立相应的GaBi模型,基于湿法回收A、湿法回收B、火法-湿法联合回收3种不同回收利用方式进行三元锂电池生命周期评价模型搭建与回收再利用过程减碳成效测算。研究结果表明,三元锂电池回收再利用过程有较好的减碳成效,基于3种不同回收工艺的三元锂电池回收再利用可以减少CO_(2)排放量分别为:湿法回收A为60.71kgCO_(2)/kWh;湿法回收B为150.00kgCO_(2)/kWh;火法-湿法联合回收为153.57 kg CO_(2)/kWh。基于这3种不同回收工艺的CO_(2)减排效果从优至劣依次为:湿法-火法联合回收、湿法回收B和湿法回收A。合理的动力电池回收利用方式可以显著减少其回收利用过程中的碳排放量,从而产生更好的环境效益。展开更多
Photosynthesis is the most important biochemical reaction on Earth. It has co-evolved and developed with the Earth, driving the biogeochemical cycle of all elements on the planet and serving as the only chemical proce...Photosynthesis is the most important biochemical reaction on Earth. It has co-evolved and developed with the Earth, driving the biogeochemical cycle of all elements on the planet and serving as the only chemical process in nature that can convert light energy into chemical energy. Some heavy oxygen isotopic(^(18)O) labeling experiments have"conclusively" demonstrated that the oxygen released by photosynthesis comes only from water and are written into textbooks. However, it is not difficult to find that bicarbonate has never been excluded from the direct substrate of photosynthesis from beginning to end during the history of photosynthesis research. No convincing mechanism can be used to explain photosynthetic oxygen evolution solely from water photolysis. The bicarbonate effect, the Dole effect, the thermodynamic convenience of bicarbonate photolysis, the crystal structure characteristics of photosystem Ⅱ, and the reinterpretation of heavy oxygen isotopic labeling(^(18)O)experiments all indicate that the photosynthetic oxygen evolution does not exclude the important role and contribution of bicarbonate photolysis. The recently proposed view that bicarbonate photolysis is the premise of water photolysis, bicarbonate photolysis and water photolysis work together with a 1:1(mol/mol) stoichiometric relationship, and the stoichiometric relationship between oxygen and carbon dioxide released during photosynthetic oxygen evolution is also 1:1, has excellent applicability and objectivity, which can logically and reasonably explain the precise coordination between light and dark reactions during photosynthesis, the bicarbonate effect, the Dole effect, the Kok cycle and the neutrality of water and carbon in nature.This is of great significance for constructing the bionic artificial photosynthetic reactors and scientifically answering the question of the source of elemental stoichiometric relationships in nature.展开更多
文摘为量化评价新能源汽车动力电池回收利用过程的环境效益,为报废动力电池管理体系和回收再利用相关标准的完善提供支撑,助力国家“双碳”目标的实现,以三元锂电池为研究对象,选取典型的动力电池回收利用场景,将三元锂电池的生命周期划分为4个阶段:原材料获取、制造装配、使用和报废回收,并建立相应的GaBi模型,基于湿法回收A、湿法回收B、火法-湿法联合回收3种不同回收利用方式进行三元锂电池生命周期评价模型搭建与回收再利用过程减碳成效测算。研究结果表明,三元锂电池回收再利用过程有较好的减碳成效,基于3种不同回收工艺的三元锂电池回收再利用可以减少CO_(2)排放量分别为:湿法回收A为60.71kgCO_(2)/kWh;湿法回收B为150.00kgCO_(2)/kWh;火法-湿法联合回收为153.57 kg CO_(2)/kWh。基于这3种不同回收工艺的CO_(2)减排效果从优至劣依次为:湿法-火法联合回收、湿法回收B和湿法回收A。合理的动力电池回收利用方式可以显著减少其回收利用过程中的碳排放量,从而产生更好的环境效益。
基金the Support Plan Projects of Science and Technology Department of Guizhou Province [No.(2021)YB453]。
文摘Photosynthesis is the most important biochemical reaction on Earth. It has co-evolved and developed with the Earth, driving the biogeochemical cycle of all elements on the planet and serving as the only chemical process in nature that can convert light energy into chemical energy. Some heavy oxygen isotopic(^(18)O) labeling experiments have"conclusively" demonstrated that the oxygen released by photosynthesis comes only from water and are written into textbooks. However, it is not difficult to find that bicarbonate has never been excluded from the direct substrate of photosynthesis from beginning to end during the history of photosynthesis research. No convincing mechanism can be used to explain photosynthetic oxygen evolution solely from water photolysis. The bicarbonate effect, the Dole effect, the thermodynamic convenience of bicarbonate photolysis, the crystal structure characteristics of photosystem Ⅱ, and the reinterpretation of heavy oxygen isotopic labeling(^(18)O)experiments all indicate that the photosynthetic oxygen evolution does not exclude the important role and contribution of bicarbonate photolysis. The recently proposed view that bicarbonate photolysis is the premise of water photolysis, bicarbonate photolysis and water photolysis work together with a 1:1(mol/mol) stoichiometric relationship, and the stoichiometric relationship between oxygen and carbon dioxide released during photosynthetic oxygen evolution is also 1:1, has excellent applicability and objectivity, which can logically and reasonably explain the precise coordination between light and dark reactions during photosynthesis, the bicarbonate effect, the Dole effect, the Kok cycle and the neutrality of water and carbon in nature.This is of great significance for constructing the bionic artificial photosynthetic reactors and scientifically answering the question of the source of elemental stoichiometric relationships in nature.
