Tectonic-thermal history and hydrocarbon potential of the Pearl River Mouth Basin,northern South China Sea:Insights from borehole apatite fission-track thermochronology

The Pearl River Mouth Basin(PRMB)is one of the most petroliferous basins on the northern margin of the South China Sea.Knowledge of the thermal history of the PRMB is significant for understanding its tectonic evolution and for unraveling its poorly studied source-rock maturation history.Our investigations in this study are based on apatite fission-track(AFT)thermochronology analysis of 12 cutting samples from 4 boreholes.Both AFT ages and length data suggested that the PRMB has experienced quite complicated thermal evolution.Thermal history modeling results unraveled four successive events of heating separated by three stages of cooling since the early Middle Eocene.The cooling events occurred approximately in the Late Eocene,early Oligocene,and the Late Miocene,possibly attributed to the Zhuqiong II Event,Nanhai Event,and Dongsha Event,respectively.The erosion amount during the first cooling stage is roughly estimated to be about 455-712 m,with an erosion rate of 0.08-0.12 mm/a.The second erosion-driven cooling is stronger than the first one,with an erosion amount of about 747-814 m and an erosion rate between about 0.13-0.21 mm/a.The erosion amount calculated related to the third cooling event varies from 800 m to 3419 m,which is speculative due to the possible influence of the magmatic activity.

Geochemical characteristics of Sr isotopes in the LS33 drill core from the Qiongdongnan Basin, South China Sea, and their response to the uplift of the Tibetan Plateau

Making full use of modern analytical and testing techniques to explore and establish new indexes or methods for extracting paleoseawater geochemical information from sediments will help to reconstruct the sedimentary paleoenvironment in different research areas.The connection between the subsidence of the South China Sea basin and the uplift of the Tibetan Plateau has been a scientific concern in recent decades.To explore the information on the sedimentary paleoenvironment,provenance changes and uplift of Tibetan Plateau contained in core sediments(debris),we selected core samples from Well LS33 in the Qiongdongnan Basin,South China Sea,and analyzed the contents of typical elements(Al,Th,and rare earth elements)that can indicate changes in provenance and the Sr isotopic compositions,which can reveal the geochemical characteristics of the paleoseawater depending on the type of material(authigenic carbonate and terrigenous detritus).The results show the following:(1)during the late Miocene,the Red River transported a large amount of detrital sediments from the ancient continental block(South China)to the Qiongdongnan Basin.(2)The authigenic carbonates accurately record changes in the 87Sr/86Sr ratios in the South China Sea since the Oligocene.These ratios reflect the semi-closed marginal sea environment of the South China Sea(relative to the ocean)and the sedimentary paleoenvironment evolution process of the deep-water area of the Qiongdongnan Basin from continental to transitional and then to bathyal.(3)Since the Neogene,the variations in the 87Sr/86Sr ratio in the authigenic carbonates have been consistent with the variations in the uplift rate of the Tibetan Plateau and the sediment accumulation rate in the Qiongdongnan Basin.These consistent changes indicate the complex geological process of the change in the rock weathering intensity and terrigenous Sr flux caused by changes in the uplift rate of the Tibetan Plateau,which influence the Sr isotope composition of seawater.

Evidence for water exchange between the South China Sea and the Pacific Ocean through the Luzon Strait

An analysis of historical oxygen data provides evidence on the water exchange between theSouth China Sea (SCS) and the Pacific Ocean (PO). In the vicinity of the Luzon Strait (LS) , the dissolved oxygen concentration of sea water is found to be lower on the Pacific side than on the SCS side at depths between 700 and 1500 m (intermediate layer) , while the situation is reversed above 700 m (upper layer) and below 1 500 m (deep layer). The evidence suggests that water exits the SCS in the intermediate layer but enters it from the Pacific in both the upper and the deep layers, supporting the earlier speculation that the Luzon Strait transport has a sandwiched structure in the vertical. Within the SCS basin, the oxygen distribution indicates widespread vertical movement, including the upwelling in the intermediate layer and the downwelling in the deep layer.

Deep-water Fan Systems and Petroleum Resources on the Northern Slope of the South China Sea

The shallow shelf delta/strand arenaceous-pelitic deposit region in the north of the Pearl River mouth basin, sitting on the northern continental shelf of the South China Sea, has already become an important oil production base in China. Recent researched has revealed that a great deal of deep-water fans of great petroleum potentiality exist on the Baiyun deep-water slope below the big paleo Pearl River and its large delta. Based on a mass of exploration wells and 2-D seismic data of the shallow shelf region, a interpretation of sequence stratigraphy confirmed the existence of deep-water fans. The cyclic falling of sea level, abundant detrital matter from the paleo Pearl River and the persistent geothermal subsidence in the Baiyun sag are the three prerequisites for the formation and development of deep-water fans. There are many in common between the deep-water shelf depositional system of the northern South China Sea and the exploration hotspots region on the two banks of the Atlantic. For example, both are located on passive continent margins, and persistent secular thermal subsidence and large paleo rivers have supplied abundant material sources and organic matter. More recently, the discovery of the big gas pool on the northern slope of the Baiyun sag confirms that the Lower Tertiary lacustrine facies in the Baiyun sag has a great potentiality of source rocks. The fans overlying the Lower Tertiary source rocks should become the main exploration areas for oil and gas resources.

Impact of the Thermal State of the Tropical Western Pacific on Onset Date and Process of the South China Sea Summer Monsoon

Since the early or late onset of the South China Sea summer monsoon （SCSM） has a large impact on summer monsoon rainfall in East Asia, the mechanism and process of early or late onset of the SCSM are an worthy issue to study. In this paper, the results analyzed by using the observed data show that the onset date and process of the SCSM are closely associated with the thermal state of the tropical western Pacific in spring. When the tropical western Pacific is in a warming state in spring, the western Pacific subtropical high shifts eastward, and twin cyclones are early caused over the Bay of Bengal and Sumatra before the SCSM onset. In this case, the cyclonic circulation located over the Bay of Bengal can be early intensified and become into a strong trough. Thus, the westerly flow and convective activity can be intensified over Sumatra, the Indo-China Peninsula and the South China Sea （SCS） in mid-May. This leads to early onset of the SCSM. In contrast, when the tropical western Pacific is in a cooling state, the western Pacific subtropical high anomalously shifts westward, the twin cyclones located over the equatorial eastern Indian Ocean and Sumatra are weakened, and the twin anomaly anticyclones appear over these regions from late April to mid-May. Thus, the westerly flow and convective activity cannot be early intensified over the Indo-China Peninsula and the SCS. Only when the western Pacific subtropical high moves eastward, the weak trough located over the Bay of Bengal can be intensified and become into a strong trough, the strong southwesterly wind and convective activity can be intensified over the Indo-China Peninsula and the SCS in late May. Thus, this leads to late onset of the SCSM. Moreover, in this paper, the influencing mechanism of the thermal state of the tropical western Pacific on the SCSM onset is discussed further from the Walker circulation anomalies in the different thermal states of the tropical western Pacific.

Types,Characteristics and Significances of Migrating Pathways of Gas-bearing Fluids in the Shenhu Area,Northern Continental Slope of the South China Sea

The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways（largescale faults, gas chimneys and mud diapirs） presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways（large-scale faults and mud diapirs） in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways（composed of gas chimneys） in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.

Features of eddy kinetic energy and variations of upper circulation in the South China Sea

The features of eddy kinetic energy (EKE) and the variations of upper circulation in theSouth China Sea (SCS) are discussed in this paper using geostrophic currents estimated from Maps of Sea Level Anomalies of the TOPEX/Poseidon altimetry data. A high EKE center is identified in the southeast of Vietnam coast with the highest energy level 1 400 cm2 ·s^(-2) in both summer and autumn. This high EKE center is caused by the instability of the current axis leaving the coast of Vietnam in summer and the transition of seasonal circulation patterns in autumn. There exists another high EKE region in the northeastern SCS, southwest to Taiwan Island in winter. This high EKE region is generated from the eddy activities caused by the Kuroshio intrusion and accumulates more than one third of the annual EKE, which confirms that the eddies are most active in winter. The transition of upper circulation patterns is also evidenced by the directions of the major axises of velocity variance ellipses between 10?and 14.5°N, which supports the model results reported before.

A numerical study of the South China Sea deep circulation and its relation to the Luzon Strait transport

A fine-resolution MOM code is used to study the South China Sea basin-scale circulationand its relation to the mass transport through the Luzon Strait. The model domain includes the South China Sea, part of the East China Sea, and part of the Philippine Sea so that the currents in the vicinity of the Luzon Strait are free to evolve. In addition, all channels between the South China Sea and the Indonesian seas are closed so that the focus is on the Luzon Strait transport. The model is driven by specified Philippine Sea currents and by surface heat and salt flux conditions. For simplicity, no wind-stress is applied at the surface.The simulated Luzon Strait transport and the South China Sea circulation feature a sandwich vertical structure from the surface to the bottom. The Philippine Sea water is simulated to enter the South China Sea at the surface and in the deep ocean and is carried to the southern basin by western boundary currents. At the intermediate depth, the net Luzon Strait transport is out of the South China Sea and is fed by a western boundary current flowing to the north at the base of the thermocline. Corresponding to the western boundary currents, the basin circulation of the South China Sea is cyclonic gyres at the surface and in the abyss but an anti-cyclonic gyre at the intermediate depth. The vorticity balance of the gyre circulation is between the vortex stretching and the meridional change of the planetary vorticity. Based on these facts, it is hypothesized that the Luzon Strait transports are determined by the diapycnal mixing inside the entire South China Sea. The South China Sea plays the role of a 'mixing mill' that mixes the surface and deep waters to return them to the Luzon Strait at the intermediate depth. The gyre structures are consistent with the Stommel and Arons theory (1960), which suggests that the mixing-induced circulation inside the South China Sea should be cyclonic gyres at the surface and at the bottom but an anti-cyclonic gyre at the intermediate depth. The simulated gyre circulation at the intermediate depth has been confirmed by the dynamic height calculation based on the Levitus hydrography data. The sandwich transports in the Luzon Strait are consistent with recent hydrographical observations.Model results suggest that the Kuroshio tends to form a loop current in the northeastern South China Sea. The simulated Kuroshio Loop Current is generated by the pressure head at the Pacific side of the Luzon Strait and is enhanced by the β-plane effects. The β - plane appears to be of paramount importance to the South China Sea circulation and to the Luzon Strait transports. Without the β-plane, theLuzon Strait transports would be greatly reduced and the South China Sea circulation would be complete-ly different.

Fouling in offshore areas southeast of the Zhujiang(Pearl)River Delta,the northern South China Sea

In order to understand the type and extent of marine fouling in offshore areas southeast ofthe Zhujiang (Pearl) River delta, within the period form May 1986 to June 1987, two biological buoys were deployed at water depths of 95 m and 113 m located in 114 km and 160 km off the coast of Hong Kong, respectively. Moreover, the fouling community of a Marex hydrological buoy located in 115 m depth water 172 km off Hong Kong was also surveyed. The results show that a total of 78 species were collected and identified. The panels exposed for 3 months were mainly dominated by stalked barnacles Conchoderma hunteri and Lepas anatifera and hydroids Orthopyxis sp. As for the buoys, including the subsurface buoy, and their mooring systems exposed for 6 and 12 months, respectively, some hard foulers such as common oysters, pearl oysters, acorn barnacles and bryozoans were also found. The compositions of fouling communities also varied greatly with depth.

Geoacoustic Inversion for Bottom Parameters in the Deep-Water Area of the South China Sea

Bottom acoustic parameters play an important role in sound field prediction. Acoustic parameters in deep water are not well understood. Bottom acoustic parameters are sensitive to the transmission-loss （TL） data in the shadow zone of deep water. We propose a multiple-step fill inversion method to invert sound speed, density and attenuation in deep water. Based on a uniform liquid hMf-space bottom model, sound speed of the bottom is inverted by using the long range TL at low frequency obtained in an acoustic propagation experiment conducted in the South China Sea （SCS） in summer 2014. Meanwhile, bottom density is estimated combining with the Hamilton sediment empirical relationship. Attenuation coefficients at different frequencies are then estimated from the TL data in the shadow zones by using the known sound speed and density as a constraint condition. The nonlinear relationship between attenuation coefficient and frequency is given in the end. Tile inverted bottom parameters can be used to forecast the transmission loss in the deep water area of SCS very we//.

Diagnostic Study of Apparent Heat Sources and Moisture Sinks in the South China Sea and its Adjacent Areas during the Onset of 1998 SCS Monsoon

The apparent heat sources (?Q1 ?) and moisture sinks (?Q2 ?) are calculated based on the reanalyzed data of the South China Sea Monsoon Experiment (SCSMEX) from May 1 to August 31, 1998. It is found that the formation and distribution of the atmospheric heat sources are important for the monsoon onset. The earlier onset of the SCS monsoon is the result of enduring atmospheric heating in the Indo–China Peninsula and South China areas. The atmospheric heating firstly appears in the Indo–China Peninsula area and the sensible heat is the major one. The 30–50 day periodic oscillation of atmospheric heat sources between the SCS area and the western Pacific warm pool has a reverse phase distribution before the middle of July and the low frequency oscillation of heat sources in SCS area has an obvious longitudinal propagation. The 30–50 day low frequency oscillation has vital modificatory effects on the summer monsoon evolution during 1998. Key words Apparent heat sources - Apparent moisture sinks - The South China Sea monsoon - Diagnostic Study Sponsored by the National Key Project of Fundamental Research “ SCSMEX” and the Research Fund for the Doctoral Program of Higher Education: “ Study of the Air-sea Interaction in the SCS Monsoon Region”.

Hydrological analysis of Kuroshio water intrusion into the South China Sea

Using CFD and ADCP data collected by four research vessels from both sides of the Taiwan Strait in the northeastern area of the forth China Sea in August - September 1994 and incorporating with CTD data collected in the same area in March 1992 and some historical hydrologic data, the water features and the intrusion of Kuroshio water into the South China Sea are discussed, which shows that the water mass distribution in the survey period was similar to that in the cruise of late winter and early spring (March 1992), that is, the water structure in the northeast of the sea and in the Northwest Pacific had their own independent features of temperature and salinity. Though the intrusion of Kuroshio water into the sea was found, it was very weak. Therefore there would be no direct Kuroshio branch into the sea in the late summer and early autumn. Even the Kuroshio water intrusion from the Bashi Channel into the Taiwan Strait, its influence was also very weak. Analysis of isopycnic surface and geretrophic current and the Observed ADCP data show that there was a rather strong northward flow in the southeast pat of the survey area which flowed northward along the west coast of Philippines, rounded the northwest corner of Luzon Island and then flowed northeastward. Some kind of mixing with Kuroshio water was shown in the Bashi Channel. The water mass was obviously of high temperature and low salinity in winter and comparatively low temperature and low salinity in summer.

Mass movements in small canyons in the northeast of Baiyun deepwater area, north of the South China Sea

The process of mass movements and their consequent turbidity currents in large submarine canyons has been widely reported, however, little attention was paid to that in small canyons. In this paper, we document mass movements in small submarine canyons in the northeast of Baiyun deepwater area, north of the South China Sea （SCS）, and their strong effects on the evolution of the canyons based on geophysical data. Submarine canyons in the study area arrange closely below the shelf break zone which was at the depth of -500 m. Within submarine canyons, seabed surface was covered with amounts of failure scars resulted from past small-sized landslides. A complex process of mass transportation in the canyons is indicated by three directions of mass movements. Recent mass movement deposits in the canyons exhibit translucent reflections or parallel reflections which represent the brittle deformation and the plastic deformation, respectively. The area of most landslides in the canyons is less than 3 km2. The trigger mechanisms for mass movements in the study area are gravitational overloading, slope angle and weak properties of soil. Geophysical data indicate that the genesis of submarine canyons is the erosion of mass movements and consequent turbidity currents. The significant effects of mass movements on canyon are incision and sediment transportation at the erosion phases and fillings supply at the fill phases. This research will be helpful for the geological risk assessments and understanding the sediment transportation in the northern margin of the SCS.

Geochemical Indications of Possible Gas Hydrates in the Northeastern South China Sea

Gas hydrate, mainly composed of hydrocarbon gas and water, is considered to be a clean energy in the 21st century. Many indicators such as BSRs （Bottom-Simulating Reflections）, which are thought to be related to gas hydrate, are found in the South China Sea （SCS） in recent years. The northeastern part of the SCS is taken as one of the most potentials in the area by many scientists. It is situated in the conjunction of the northern divergent continental margin and the eastern convergent island margin, whose geological settings are much preferable for gas hydrate to occur. Through this study, brightness temperature anomalies recorded by satellite-based thermal infrared remotely sensed images before or within the imminent earthquake, the high content of hydrocarbon gas acid-degassed from subsurface sediment and the high radioactive thermoluminescence value of subsurface sediment were found in the region. Sometimes brightness temperature anomalies alone exist in the surrounding of the Dongsha Islands. The highest content of hydrocarbon gas amounts to 393 μL methane per kilogram sediment and the highest radioactive thermoluminescence value is 31752 unit; their geometric averages are 60.5 μL/kg and 2688.9 unit respectively. What is more inspiring is that there are three sites where the methane contents are up to 243, 268 and 359μL/kg and their radioactive thermoluminescence values are 8430, 9537 and 20826 unit respectively. These three locations are just in the vicinity of one of the highest confident BSRs identified by predecessors. Meanwhile, the anomalies are generally coincident with other results such as headspace gas anomaly in the sediment and chloride anomaly in the interstitial water in the site 1146 of Leg 184. The above-mentioned anomalies are most possibly to indicate the occurrence of gas hydrate in the northeastern SCS.

Multi-scale variability of subsurface temperature in the South China Sea

Using Morlet wavelet transform and harmonic analysis the multi-scale variability of subsurface temperature in the South China Sea is studied by analyzing one-year (from April 1998 to April 1999) ATLAS mooring data. By wavelet transform, annual and semi-annual cycle as well as intrasea-sonal variations are found, with different dominance, in subsurface temperature. For annual harmonic cycle, both the downward net surface heat flux and thermocline vertical movement partially control the subsurface temperature variability. For semi-annual cycle and intraseasonal variability, the subsurface temperature variability is mainly linked to the vertical displacement of thermocline.

Experience on offshore cathodic protection retrofitting in the northern South China Sea

Platforms I and II are steel structures located in offshore areas southeast of the Zhujiang (Pearl) River Delta, the northern South China Sea,. in about 110 in water depth. The jackets, with aluminum sacrificial anodes for cathodic protection (CP) of the immersed zone, were launched in March 1995. In May 096 a CP survey showed that, after almost one year of service, a low polarization level had been achieved and some extended unprotected zones existed; mainly in the deepest part of the Platform II. Further to this, a joint activity was decided in order to assess the need of a possible retrofitting of the CP systems. The results of the activity carried out are dealt with, including technical and economical comparisons amongst several retrofitting options, both with sacrificial anodes and with impressed current systems. The adopted solution is illustrated and data are reported on the level of protection presently achieved.

An Anomalous Seamount on the Southwestern Mid-Ridge of the South China Sea

Objective The development of continental rifting and seafloor spreading can be predominated by magmatic upwelling （magma-rich） or tectonic stretching （magma-poor）. Located in the terminal portion of propagating seafloor spreading of the South China Sea （SCS）, the southwestern mid-ridge of the southwest sub-basin （SWSB） of the SCS was found with much thin crust and numerous faulted blocks coupling with magma-poor continental margins along its flanks. Therefore, the southwestern part of the SWSB is most likely to be a tectonic-dominated basin. To justify the hypothesis with further evidence, we investigated the nature of seamounts on the southwestern mid-ridge of the SWSB which may inherit seafloor spreading.

Seasonal variation and formation mechanism of the South China Sea warm water

The South China Sea warm water (SCSWW) is identified as the warm water body withtemperature no less than 28*. There are three stages in the seasonal variation of the SCSWW. The SCSWW expands rapidly and deepens quickly in the developing stage. The warm water thickness decreases near the coast of Vietnam and increases near Palawan Island in the steady stage. The SCSWW flinches southward while its thickness off Palawan Island remains no less than 50 m in the flinching stage. The maximum thickness of the SCSWW is always located near the southeastern SCS. The seasonal variation of the SCSWW has a close relationship with seasonal variation of the thermocline. According to the analysis of the numerical experiment results from the Princeton Ocean Model (POM), the mechanism of the seasonal variation of the SCSWW can be interpreted as: (1) in the developing stage, the rapidly expanding and thickening feature of the SCSWW is mainly due to buoyancy flux effect (67% contribution). The weak wind and anticyclonic wind stress curl (22% contribution) present an environment which facilitates the accumulation of warm water; (2) in the steady stage, the decrease feature near the Vietnam coast and increase eature in southeast of the SCSWW thickness are mainly caused by wind stress (70% contribution); (3) in the flinching stage, the thickness reduction of the SCSWW is mainly due to upwelling and enhanced turbulent mixing caused by wind stress (accounts for 60%).

A possible role of the South China Sea in ENSO cycle

A data-based hypothesis on the role of the South China Sea (SCS) in ENSO cycle is proposed: during El Nino, there are westerly wind anomaly over the western equatorial Pacific and positive SST anomaly in the eastern equatorial Pacific. Meanwhile anomalous convection moves to the central Pacific with anomalous sinking over Indonesian Archipelago. The latter can cause southerly wind anomaly over the north of South China Sea (NSCS) and makes the NSCS warmer. The warm NSCS can attract the anomalous convection to it in some degree. This attraction is in favor for producing easterly wind anomaly over the western equatorial Pacific, so it helps to form a cycle.

A new type of internal solitary waves with a re-appearance period of 23 h observed in the South China Sea

The South China Sea （SCS）, in particular the northern SCS, is one of ocean areas where energetic internal solitary waves （ISWs）occur most frequently （Cai et al., 2012; Zheng, 2017）. Based on the re-appearance period （RP） at an observation station, Ramp et al.（2004） divided the ISWs into two types：Type-a and Type-b. Type-a ISWs arrive regularly at the same time every day, i.e., the RP is about 24 h, and Type-b ISWs arrive about one hour late every day, i.e., the RP is about 25 h.