Spatiotemporal variation and driving factors of vegetation net primary productivity in the Guan-zhong Plain Urban Agglomeration,China from 2001 to 2020

Studying the spatiotemporal variation and driving mechanisms of vegetation net primary productivity(NPP)in the Guanzhong Plain Urban Agglomeration(GPUA)of China is highly important for regional green and low-carbon development.This study used the Theil-Sen trend analysis,Mann-Kendall trend test,coefficient of variation,Hurst index,and machine learning method(eXtreme Gradient Boosting and SHapley Additive exPlanations(XGBoost-SHAP))to analyze the spatiotemporal variation of NPP in the GPUA from 2001 to 2020 and reveal its response to climate change and human activities.The results found that during 2001-2020,the averageNPP in the GPUA showed a significant upward trend,with an annual growth rate of 10.84 g C/(m^(2)•a).The multi-year average NPP in the GPUA was 484.83 g C/(m^(2)•a),with higher values in the southwestern Qinling Mountains and lower values in the central and northeastern cropland and built-up areas.The average coefficient of variation of NPP in the GPUA was 0.14,indicating a relatively stable state overall,but 72.72%of the study area showed weak anti-persistence,suggesting that NPP in most areas may have declined in the short term.According to XGBoost-SHAP analyses,elevation,land use type and precipitation were identified as the main driving factors of NPP.Appropriate precipitation and higher temperatures promote NPP growth,whereas extreme climates,high population density,and nighttime lighting inhibit NPP.This study has important theoretical and practical significance for achieving regional sustainable development,offers a scientific basis for formulating effective ecological protection and restoration strategies,and promotes green,coordinated,and sustainable development in the GPUA.

Territorial Ecological Restoration with a High-carbon Storage Focus in the Beibu Gulf Urban Agglomeration of China:Insights from Carbon Metabolism Spatial Security Patterns

This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking and neutrality goals.This research ana-lyzes the spatial characteristics of carbon metabolism from 2000 to 2020 and uses models to identify stable carbon sink areas,positive carbon flow corridors,and carbon sequestration nodes.The goal is to construct a carbon metabolism spatial security pattern(CMSSP)and propose territorial ecological restoration strategies under different development demand scenarios.The results show the following:1)in 2020,the study area’s carbon sink decreased by 8.29×10^(4) t C/yr compared with that in 2010 and by 10.83×10^(4) t C/yr compared with that in 2000.High-carbon sinks were found mainly in mountainous areas,whereas low-carbon sinks are concentrated in urban con-struction land,rural residential areas,and land margins.2)From 2000 to 2020,the spatial security pattern of carbon metabolism tended to be‘high in the middle of the east and west and low in the gulf.’In 2000,2010,and 2020,16 stable carbon sinks were identified.The carbon energy flow density in Guangxi was greater than that in Guangdong and Hainan,with positive carbon flow corridors located primarily in Guangxi and Guangdong.The number of carbon sequestration nodes remained stable at approximately 15,mainly in Guangxi and Hainan.3)Scenario simulations revealed that under the Nature-based mild restoration scenario,the carbon sink rate will reach 611.85×10^(4) t C/yr by 2030 and increase to 612.45×10^(4) t C/yr by 2060,with stable carbon sinks increasing to 18.In the restora-tion scenario based on Anti-globalization,the carbon sink will decrease from 610.24×10^(4) t C/yr in 2030 to 605.19×10^(4) t C/yr in 2060,with the disappearance of some positive carbon flow corridors and stable carbon sinks.Under the Human-based sustainable restoration scenario,the carbon sink area will decrease from 607.00×10^(4) t C/yr in 2030 to 596.39×10^(4) t C/yr in 2060,with carbon sink areas frag-menting and positive carbon flow corridors becoming less dense.4)On the basis of the current and predicted CMSSPs,this study ex-plores spatial ecological restoration strategies for high-carbon storage areas in bay urban agglomerations at four levels:the land control region,urban agglomeration structure system,carbon sink structure and bay structure control region.

Bipolar charged aerosol agglomeration and collection by a two-zone agglomerator

In older to collect fine particles more efficiently, a new-type electrostatic agglomerator with two zones was developed. The distinguishing feature of this electrostatic agglomerator is that the particles are bipolarly charged and coagulated in the same alternating electric field simultaneously. The silica flour with 2 fun mass median diameter and the smoke from burning wood powder were used as test aerosol. The comparison experimental results have shown that when the mean electric field is 4 kV/cm the collection efficiency of the new electrostatic agglomerator was 98.2% for silica flour and 67.4% for wood powder smoke, Under the same experimental condition. the collection efficiency of the electrostatic agglomerator with three zones was 97.4% for collecting silica flour and the collection efficiency of the electrostatic precipitator was 56.3% for wood powder smoke.

Impact of Anthropogenic Heat Release on Regional Climate in Three Vast Urban Agglomerations in China

We simulated the impact of anthropogenic heat release （AHR） on the regional climate in three vast city agglomerations in China using the Weather Research and Forecasting model with nested high-resolution modeling.Based on energy consumption and high-quality land use data,we designed two scenarios to represent no-AHR and current-AHR conditions.By comparing the results of the two numerical experiments,changes of surface air temperature and precipitation due to AHR were quantified and analyzed.We concluded that AHR increases the temperature in these urbanized areas by about 0.5℃-1℃,and this increase is more pronounced in winter than in other seasons.The inclusion of AHR enhances the convergence of water vapor over urbanized areas.Together with the warming of the lower troposphere and the enhancement of ascending motions caused by AHR,the average convective available potential energy in urbanized areas is increased.Rainfall amounts in summer over urbanized areas are likely to increase and regional precipitation patterns to be altered to some extent.

An Experimental Investigation of Agglomeration with One and Two Nozzle Atomisation

Water-droplet size and velocity measurements were taken throughout two different sprays produced by a single nozzle and two nozzles pointed towards each other. The aim of this investigation was to understand the manner in which the motion of the droplets in a spray leads to agglomeration of these droplets. It appears that the inertia of the droplets plays an important role in the redistribution of droplets throughout a spray. Larger droplets tend to concentrate at the outer portions of the spray, because they are able to maintain their radial momentum farther downstream of a nozzle, while the smaller droplets follow the airflow more closely and thus collect in the core of the spray. Agglomeration can result from both turbulent collisions and collisions due to the relative velocities of the droplets. The difference between the agglomeration rates in the sprays from a single nozzle and two-nozzles pointed towards each other was difficult to resolve in these experiments, although the results suggest that the outer portions of both sprays should be investigated more closely for evidence of agglomeration.

STUDY ON THE CHARACTERISTICS OF AGGLOMERATION AND CYCLONE SEPARATION OF DIESEL PARTICULATE

A particulate separation system that can be used to study the characteristics of the diesel particulate agglomeration and cyclone separation is developed It includes a diesel particulate agglomerator and a cyclone separator mainly A preliminary investigation on the cyclone separation tech nology for controlling the exhaust particulate from a diesel engine is conducted The experimental results show that the diameter distribution of the diesel particulate is changed after they pass through the agglomerator,almost 30%～40% o f the particulate agglomerated from less than 1.0μm to larger than 1.0μm ,this change contributes to trap diesel particulate With this system installed on the exhaust pipe of a single cylinder engine,the particulate separation efficiency is around 40%～60% under typical engine running condition The back pressure of this system is less than 5 kPa on full load condition,much less than that of other methods of particulate filtration This technology has the possibility to open a new prospect for particulate reduction because of its simplicity,reliability and low resistance.

Particle agglomeration and inhibition method in the fluidized pyrolysis reaction of waste resin

This work investigated the pyrolysis reaction of waste resin in a fluidized bed reactor.It was found that the pyrolysis-generated ash would adhere to the surface of ceramic particles,causing particle agglomeration and defluidization.Adding kaolin could effectively inhibit the particle agglomeration during the fluidized pyrolysis reaction through physical isolation and chemical reaction.On the one hand,kaolin could form a coating layer on the surface of ceramic particles to prevent the adhesion of organic ash generated by the pyrolysis of resin.On the other hand,when a sufficient amount of kaolin(-0.2%(mass))was added,the activated kaolin could fully contact with the Na+ ions generated by the pyrolysis of resin and react to form a high-melting aluminosilicate mineral(nepheline),which could reduce the formation of low-melting-point sodium sulfate and thereby avoid the agglomeration of ceramic particles.

Assessing economic performance of the three major urban agglomerations in China by using Malmquist productivity index

Forty years of reform and opening up,China has become to the world’s second-largest economy with great success.However,it is an undoubted actuality that the economic mode of Chinese development is still at the extensive stage.China’s economy has shifted from a high-speed growth phase to a high-quality development phase.In this study,we analyzed three major urban agglomerations’total factor productivity index dynamically by means of Malmquist productivity i?ndex method.The results showed that MPI of Beijing-Tianjin-Hebei urban agglomeration was the highest,as the reasons of the effectiveness of dual-wheel driving both the technology progress and the cluster scale.The mean of MPI of Yangtze River Delta urban agglomeration was fallen into decline by an average of 1.3%annually due to the rate of increase of the size of the cluster towards to optimal frontier was inferior to the relative risk reduction of technology progress.Pearl River Delta urban agglomeration MPI declined by an average of 2.2%annually as a result of the contribution of technology progress reducing.The study of the economic performance of three major urban agglomerations provides a theoretical basis and important practical value for urban development of high quality optimization.

Measurement of Urban Economic Gravity of China’s Three Major Agglomerations and Its Implications for the Coordinated Development of the Beijing-Tianjin-Hebei Region

This paper adopts the perspective of urban economic linkage and the modified urban economic gravity model to conduct a comparative analysis of the economic gravity among cities in China’s three major urban agglomerations,including the Beijing-Tianjin-Hebei region,the Yangtze River Delta,and the Pearl River Delta.The results show that,despite the ever-tightening economic linkages among cities in the urban agglomerations,the development of the Beijing-Tianjin-Hebei region falls behind that of the Yangtze River Delta and the Pearl River Delta in terms of coordination,closeness,and balance.The economic linkages among cities in the Beijing-Tianjin-Hebei region are not as cohesive as they could be and display a significant“siphon effect”through Beijing and Tianjin as well as a prominently unidirectional economic flow.This study suggests that efforts should be put into directing the orderly flow of resources from Beijing and Tianjin to cities in Hebei and promoting a balanced economic flow among cities,thus facilitating the coordination of regional development.

Investment Promotion for Development Zones in China:Underlying Rationale and Policy Options

Development zones(DZs)have emerged as a significant policy initiative for promoting regional coordination and facilitating resources allocation.They serve as an organizational framework for fostering industrial agglomeration and driving high-quality development.DZs attract and accommodate resource factors,firms,and projects,thereby functioning as a central catalyst for economic growth.This study utilizes data collected at the“DZ,City and Countrycountry”levels through manual compilation,textual analysis,and innovation measurement.It aims to empirically examine the theoretical rationale and practical preferences for promoting business and investment in China’s DZs.This study considers several factors such as industry attribute,firm attribute,agglomeration theory,and industrial chain layout.Based on our research findings,DZs exhibit distinct preferences.First,industry attribute:DZs align with both national and regional strategic planning and adhere to the industrial endowments of the respective areas.Second,firm attribute:DZs prioritize attracting firms that are productive and innovative,and have an international presence,rather than those that primarily contribute to taxes and job creation.Third,DZs are guided by the agglomeration theory,which suggests that they prefer firms that generate strong agglomeration externalities.Lastly,DZs also consider the industrial chain layout,aiming to attract firms that not only align with their existing industrial strengths but also extend to the upstream and downstream supply chain links.These conclusions are substantiated by the performance of robustness test.The success of DZs in China can be attributed to the five key principles:Adherence to national and regional strategic planning,prioritizing the actual industrial foundation,incorporating the theory of agglomeration externalities,strengthening corporate competitiveness,and expanding industrial chains.

Agglomeration of coal and polyethylene mixtures during fixed‑bed co‑gasification

The article presents the results of experimental studies on the gasification of mixtures of brown coal and polyethylene(up to 20 wt%fraction)in a laboratory reactor.The work aims to study the agglomeration process during the heating and oxidation of the mixtures.The measurement results(gas composition,pressure drop)provide indirect information on the dynamics of thermal decomposition and structural changes in the fuel bed.We have shown that the interaction between polyethylene and a coal surface leads to the formation of dense agglomerates,in which the molten polymer acts as a binder.Clinkers form as a result of interfacial interactions between components and filtration flow rearranging.The hydrogen/carbon ratio in the solid residue of coal-polyethylene co-gasification increases from 0.07–0.2 to 1.11,indicating the formation of stable hydrocarbon compounds on the carbon surface.The conducted research makes it possible to identify possible interactions between chemical reactions and transfer processes that lead to agglomeration in mixtures of coal with polyethylene.

Study on the spatial and temporal evolutionary characteristics of ozone concentration and the impact of human activities in China in 2019

Ozone(O_(3))pollution has a profound impact on human health,vegetation development,and the ecological environment,making it a critical focus of global academic research.In recent years,O_(3)pollution in China has been on a steady rise,with ozone emerging as the sole conventional pollutant to consistently increase in concentration without any decline.This study conducted a quantitative analysis of O_(3)concentrations across 367 Chinese cities in 2019,examining spatial autocorrelation and local clustering of O_(3)levels,and investigated the diverse relationships between human activity factors and O_(3)concentration.The seasonal fluctuation of O_(3)exhibited the“M-type”pattern,with peak concentrations in winter and the lowest levels in summer.The center of O_(3)pollution migrated southeastward,with the area of highest concentration progressively shifting south along the eastern coast.Moreover,O_(3)concentration showed a strong positive correlation with population density,road freight volume,and industrial emissions,suggesting that human activities,vehicle emissions,and industrial operations are significant contributors to O_(3)production.The results provide comprehensive information on the characteristics,causes,and occurrence mechanism of O_(3)in Chinese cities that can be utilized by global government departments to formulate strategies to prevent and control O_(3)pollution.

Evaluation and Influencing Factors on Particle Agglomeration in RAP

Asphalt extraction test and scanning electron microscopy(SEM) were used for analysis of agglomerations of reclaimed asphalt pavement(RAP) particles. In order to quantify the agglomeration degree of RAP, the fineness modulus ratio(FMR) and the percentage loss index(PLI) were proposed. In addition, grey correlation analysis was conducted to discuss the relationship between particle agglomerations and RAP size,asphalt content(AC), and surface area. Two indexes indicate that the agglomeration degree increases in general as the RAP size reduces. This can be attributed to that particles are prone to agglomeration in the case of higher AC. Based on the SEM images and the material composition of RAP, the particle agglomeration in RAP can be classified into weak agglomeration and strong agglomeration. Grey correlation analysis shows that AC is the crucial factor affecting the agglomeration degree and RAP variability. In order to produce consistent and stable reclaimed mixtures, disposal measures of RAP are suggested to lower the AC of RAP.

Inhibition of wax crystallization and asphaltene agglomeration by core-shell polymer@SiO_(2) hybride nano-particles

The gelation of crude oil with high wax and asphaltene content at low temperatures often results in the block of transportation pipeline in Africa. In recent years, it was reported that surface hydrophobicmodified nanoparticles have important applications in crude oil flow modification. In this work, four kinds of core-shell hybride nanoparticles by grafting poly(octadecyl, docosyl acrylate) and poly(acrylate-α-olefin) onto the surface of nano-sized SiO_(2) were synthesized by grafting polymerization method.The chemical structure of nanoparticles was analyzed by Fourier transform infrared spectroscopy(FT-IR),scanning electron microscopy(SEM) and thermogravimetric analysis(TGA). The rheological behaviors of crude oil and precipitation of asphaltenes in the presence of nanoparticles were studied by measuring the viscose-temperature relationship curve, the cumulative wax precipitation amount, and morphology of waxes and asphaltenes. The results indicate that the docosyl polyacrylate@SiO_(2) nanoparticle(PDA@SiO_(2)) can reduce the cumulative wax precipitation amount of crude oil by 72.8%, decline the viscosity of crude oil by 85.6% at 20℃, reduce the average size of wax crystals by 89.7%, and inhibit the agglomeration of asphaltene by 74.8%. Therefore, the nanoparticles not only adjust the crystalline behaviors of waxes, but also inhibit the agglomeration of asphaltenes. Apparently, core-shell hybride nanoparticles provides more heterogeneous nucleation sites for the crystallization of wax molecules,thus inhibiting the formation of three-dimensional network structure. The core-shell polymer@SiO_(2) hybride nanoparticles are one of promising additives for inhibiting crystallization of waxes and agglomeration of asphaltenes in crude oil.

Effect of Process Parameters on the Agglomeration Behavior and Tensile Response of Graphene Reinforced Magnesium Matrix Composites Based on Molecular Dynamics Model

The mechanical properties of graphene reinforced composites are often hampered by challenges related to the dispersion and aggregation of graphene within the matrix.This paper explores the mechanism of cooling rate,process temperature,and process pressure’s influence on the agglomeration behavior of graphene and the tensile response of composites from a computer simulation technology,namely molecular dynamics.Our findings reveal that the cooling rate exerts minimal influence on the tensile response of composites.Conversely,processing temperature significantly affects the degree of graphene aggregation,with higher temperatures leading to the formation of larger-sized graphene clusters.In contrast,processing pressure exhibits negligible impact on the degree of graphene aggregation,and increasing pressure effectively mitigates the formation of large-sized graphene clusters.Moreover,we elucidate the intrinsic factors governing the mechanical response to variations in processing parameters.Notably,we observe that the stretching process facilitates the decomposition of large-sized graphene clusters into smaller ones.This research contributes to the advancement of lightweight metal matrix composites by offering insights into optimizing processing parameters.Additionally,it provides crucial theoretical underpinnings for developing high-performance graphene-reinforced composites.

A new fluorocarbon adhesive:Inhibiting agglomeration during combustion of propellant via efficient F-Al_(2)O_(3) preignition reaction

Inhibiting the agglomeration of molten aluminum particles packed in the binder network is a promising scheme to achieve efficient combustion of solid propellants.In this investigation,the hydroxyl-terminated structured fluorinated alcohol compound(PFD)was introduced to modify the traditional polyethylene glycol/polytetrahydrofuran block copolymerization(HTPE)binder;that is,a unique fluorinated polyether(FTPE)binder was synthesized by embedding fluorinated organic segments into the HTPE binder via crosslinking curing.The FTPE was applied in aluminum-based propellants for the first time.Due to the complete release of fluorinated organic active segments in the range of 300℃to 400℃,the burning rate of FTPEbased propellant increased from 4.07(0%PFD)to 6.36 mm/s(5%PFD),increased by 56.27%under 1 MPa.The reaction heat of FTPE propellants increased from 5.95(0%PFD)to 7.18 MJ/kg(5%PFD)under 3.0 MPa,indicating that HTPE binder modified with PFD would be conducive to inhibiting the D90 of condensed combustion products(CCPs)dropped by 81.84%from 75.46(0%PFD)to 13.71μm(5%PFD)under 3.0 MPa,in consistent with the significant reduction of aluminum agglomerates observed on the quenched burning surface of the propellants.Those results demonstrated that a novel FTPE binder with PFD can release fluorinated organic active segments,which motivate preignition reaction with the alumina shell in the early stage of aluminum combustion,and then enhance the melting diffusion effect of aluminum to inhibit the agglomeration.

Evolution and Determinants of Population Agglomeration in Less Developed Metropolitan Areas:A Case Study of the Taiyuan Metropolitan Area,China

It is of importance to enhance the urban areas'capacity for population aggregation in underdeveloped regions,aiming to rectify the imbalanced and insufficient pattern of economic development in China.Taking the Taiyuan Metropolitan Area(TMA)in central China as a case study,this paper examines the evolutionary process and characteristics of population agglomeration from 2000 to 2020,and identifies factors associated with agglomeration and their spatial effects.The findings indicated that:1)against the background of sustained population shrinkage in the provincial area,the TMA showed a demographic trend of steady increase,albeit with a decelerated growth rate.In the metropolitan area,urban population size continued to grow rapidly,whereas the rural areas endured sustained losses.Disparities in city size continued to widen,and the polarization of concentrated population in the core cities kept increasing.2)Agglomerations in both secondary and service industries had significant positive effects on local population agglomeration,with the former effect being stronger.Regional economic development,government fiscal expenditure,and financial advancement all contributed to facilitating local population clustering.From a spatial spillover perspective,service agglomeration and financial development promoted population agglomeration in surrounding areas.Conversely,fiscal expenditure inhibited such agglomeration.As for industrial agglomeration and regional economic development,their spatial spillover effects were non-significant.The results obtained reveal several policy implications aimed at enhancing the population agglomeration capacity of the metropolitan area in underdeveloped regions during the new era.

Dynamic Development Characteristics and Driving Factors of High Quality Development Level in China’s Five Major Urban Agglomerations

High-quality development is the primary task of comprehensively building a socialist,modern country,as well as the primary task of building urban agglomerations in China.Based on the five development concepts,this paper used the entropy method to measure the High Quality Development Index(HQDI)of the five major urban agglomerations.The results showed that the HQDI of the five major urban agglomerations shows a fluctuating upward trend.First,using the Dagum Gini coefficient to explore the sources of HQDI development differences in urban agglomerations,we found that the main source of HQDI differences in urban agglomerations was inter-regional differences,while intra-regional differences were not important.Second,kernel density estimation was used to test the dynamic evolution trend of HQDI within urban agglomerations.There was a polarisation phenomenon in the HQDI of urban agglomerations,such as the Pearl River Delta urban agglomeration and the Chengdu-Chongqing urban agglomeration.But overall,the degree of imbalance had decreased.Third,using geographic detectors to examine the driving factors of HQDI in urban agglomerations,we found that the main driving forces for improving HQDI in urban agglomerations were economic growth,artificial intelligence technology and fiscal decentralisation.All the interaction factors had greater explanatory power for the spatial differentiation of HQDI,which can be divided into two types:two-factor improvement and non-linear improvement.This study is conducive to improving and enriching the theoretical system for evaluating the high quality development of urban agglomerations,and provides policy references for promoting the high quality development of urban agglomerations.

Analysis of Urban Agglomeration Network Structure Based on Baidu Migration Data: A Case Study of the Guangdong-Hong Kong-Macao Greater Bay Urban Agglomeration

The inter-city linkage heat data provided by Baidu Migration is employed as a characterization of inter-city linkages in order to facilitate the study of the network linkage characteristics and hierarchical structure of urban agglomeration in the Greater Bay Area through the use of social network analysis method.This is the inaugural application of big data based on location services in the study of urban agglomeration network structure,which represents a novel research perspective on this topic.The study reveals that the density of network linkages in the Greater Bay Area urban agglomeration has reached 100%,indicating a mature network-like spatial structure.This structure has given rise to three distinct communities:Shenzhen-Dongguan-Huizhou,Guangzhou-Foshan-Zhaoqing,and Zhuhai-Zhongshan-Jiangmen.Additionally,cities within the Greater Bay Area urban agglomeration play different roles,suggesting that varying development strategies may be necessary to achieve staggered development.The study demonstrates that large datasets represented by LBS can offer novel insights and methodologies for the examination of urban agglomeration network structures,contingent on the appropriate mining and processing of the data.

Spherizone工艺多区反应器内聚丙烯结块的问题

介绍了Spherizone工艺的原理,指出了采用该工艺生产的主要聚丙烯(PP)产品与采用传统工艺生产的主要PP相比的优势和生产控制过程中的技术难点。分析了反应器内物料结块的主要原因是高活性细粉黏结、静电结块和反应器内PP物料循环不充分造成的。重点提出了开工前清理反应器,合理控制反应器下降段柱塞流,优化出料阀振荡程序,控制物料循环速率、Atmer163型抗静电剂以及反应器制造质量等是避免反应器内物料结块的关键。