In this paper, superlattice patterns have been investigated by using a two linearly coupled Brusselator model. It is found that superlattice patterns can only be induced in the sub-system with the short wavelength. Th...In this paper, superlattice patterns have been investigated by using a two linearly coupled Brusselator model. It is found that superlattice patterns can only be induced in the sub-system with the short wavelength. Three different coupling methods have been used in order to investigate the mode interaction between the two Turing modes. It is proved in the simulations that interaction between activators in the two sub-systems leads to spontaneous formation of black eye pattern and/or white eye patterns while interaction between inhibitors leads to spontaneous formation of super-hexagonal pattern. It is also demonstrated that the same symmetries of the two modes and suitable wavelength ratio of the two modes should also be satisfied to form superlattice patterns.展开更多
Considering the compliance control problem of a hexapod robot under different environments, a control strategy based on the improved adaptive control algorithm is proposed. The model of robot structure and impedance c...Considering the compliance control problem of a hexapod robot under different environments, a control strategy based on the improved adaptive control algorithm is proposed. The model of robot structure and impedance control is established. Then, the indirect adaptive control algorithm is derived. Through the analysis of its parameters, it can be noticed that the algorithm does not meet the requirements of the robot compliance control in a complex environment. Therefore, the fuzzy control algorithm is used to adjust the adaptive control parameters. The satisfied system response can be obtained based on the adjustment in real time according to the error between input and output. Comparative experiments and analysis of traditional adaptive control and the improved adaptive control algorithm are presented. It can be verified that not only desired contact force can be reached quickly in different environments, but also smaller contact impact and sliding avoidance are guaranteed, which means that the control strategy has great significance to enhance the adaptability of the hexapod robot.展开更多
The removal of chromium(Vl) from an aqueous solution using persimmon gel was examined. The amount of chromium(VI) removed was strongly affected by the pH of the solution, with all ehromium(VI) being removed at p...The removal of chromium(Vl) from an aqueous solution using persimmon gel was examined. The amount of chromium(VI) removed was strongly affected by the pH of the solution, with all ehromium(VI) being removed at pH 2 or lower. However, in a solution containing, 15 mg dry weight of immobilized persimmon gel, the amount of removed chromium(VI) decreased as the pH increased. A part of chromium(VI) was reduced another oxidation stage, mainly chromium(III), by immobilized persimmon gel. The amount of reduced chromium(III) in the solution was increased with decreasing the pH of the solution. As a result, the amount of total chromium removed was maximal at pH 2. The amount of chromium removed were affected by the chromium concentration and the amount of gel. The maximal amount of chromium removed by the column system was also discussed.展开更多
This article deals with implementation of the classification and regression trees into the DMAIC phases of Six Sigma methodology. Six Sigma methodology seeks to improve the quality of manufacturing process by identify...This article deals with implementation of the classification and regression trees into the DMAIC phases of Six Sigma methodology. Six Sigma methodology seeks to improve the quality of manufacturing process by identifying and minimizing variability of this process. Using the classification, regression and segmentation trees as a part of the Data Mining methods could improve results of DMAIC phases. This improvement has a direct impact on the Sigma performance level of processes. The author introduces research results of implementation Data Mining algorithms into retail sales promotion. The author implements classification and regression techniques in our research. As a software tool has been selected SPSS PASW Modeler. The author deals with more data mining algorithms ad their implementation in the DMAIC phases. The article is divided into several parts. The first part is the introduction to Six Sigma methodology, the second deals with classification and regression trees. The third part describes tree research focused on the implementation of data mining algorithms and the fourth section summarizes the research results.展开更多
Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe...Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe 3d, while that of hexagonal pyrrhotite is from Fe 3d, Fe 3p and S 3s. The hexagonal pyrrhotite is more reactive than monoclinic pyrrhotite because of large density of states near the Fermi level. The hexagonal pyrrhotite shows antiferromagnetism. S—Fe bonds mainly exist in monoclinic pyrrhotite as the covalent bonds, while hexagonal pyrrhotite has no covalency. The main contributions of higest occupied molecular orbital(HOMO) and lowest unoccupied molecular obital(LUMO) for monoclinic pyrrhotite come from S and Fe. The main contribution of HOMO for hexagonal pyrrhotite comes from Fe, while that of LUMO comes from S. The coefficient of Fe atom is much larger than that of S atom of HOMO for hexagonal pyrrhotite, which contributes to the adsorption of Ca OH+ on the surface of hexagonal pyrrhotite when there is lime. As a result, lime has the inhibitory effect on the floatation of hexagonal pyrrhotite and the coefficient of Fe is very close to that of S for monoclinic pyrrhotite. Therefore, the existence of S prevents the adsorption of Ca OH+on the surface of monoclinic pyrrhotite, which leads to less inhibitory effect on the flotation of monoclinic pyrrhotite.展开更多
A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by...A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by LiF and PF5 at room temperature(20-30℃)for 4 h.The synthesized LiPF6 was characterized by infrared spectrometry and X-ray diffraction(XRD). Atomic absorption and ion chromatography results show that the purity of synthesized LiPF6 reaches 99.98%.Thermal stability of self-synthesized LiPF6 was analyzed by differential thermal analysis and thermogravimetry.The results indicate that the self-synthesized LiPF6 has higher purity,lower impurity contents and better thermal stability than the commercial LiPF6.展开更多
Uncertainties in engineering design may lead to low reliable solutions that also exhibit high sensitivity to uncontrollable variations. In addition, there often exist several conflicting objectives and constraints in ...Uncertainties in engineering design may lead to low reliable solutions that also exhibit high sensitivity to uncontrollable variations. In addition, there often exist several conflicting objectives and constraints in various design environments. In order to obtain solutions that are not only "multi-objectively" optimal, but also reliable and robust, a probabilistic optimization method was presented by integrating six sigma philosophy and multi-objective genetic algorithm. With this method, multi-objective genetic algorithm was adopted to obtain the global Pareto solutions, and six sigma method was used to improve the reliability and robustness of those optimal solutions. Two engineering design problems were provided as examples to illustrate the proposed method.展开更多
By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consist...By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consisted of sword-like nanobelts and toothed nanosaws with a single-crystal hexagonal wurtzite structure. The deposition temperature played an important role in determining the size and morphology of the CdS nanostruetures. A combination of vapor-liquid-solid and vapor-solid growth mechanisms were proposed to interpret the formation of CdS nanostructures. Photoluminescence measurement indicated that the nanobelts and nanosaws have a prominent green emission at about 512 nm, which is the band-to-band emission of CdS. The waveguide characteristics of both types of CdS nanos-truetures were observed and discussed.展开更多
An optimal measurement pose number searching method was designed to improve the pose selection method.Several optimal robot measurement configurations were added to an initial pre-selected optimal configuration set to...An optimal measurement pose number searching method was designed to improve the pose selection method.Several optimal robot measurement configurations were added to an initial pre-selected optimal configuration set to establish a new configuration set for robot calibration one by one.The root mean squares (RMS) of the errors of each end-effector poses after being calibrated by these configuration sets were calculated.The optimal number of the configuration set corresponding to the least RMS of pose error was then obtained.Calibration based on those poses selected by this algorithm can get higher end-effector accuracy,meanwhile consumes less time.An optimal pose set including optimal 25 measurement configurations is found during the simulation.Tracking errors after calibration by using these poses are 1.54,1.61 and 0.86 mm,and better than those before calibration which are 7.79,7.62 and 8.29 mm,even better than those calibrated by the random method which are 2.22,2.35 and 1.69 mm in directions X,Y and Z,respectively.展开更多
Synthesis of ZnO nanoparticles by hydrothermal technique in presence of cetyltrimethylammonium bromide (CTAB) as surfactant was carried out by statistically designed experiments based on Box Behnken method. The mean...Synthesis of ZnO nanoparticles by hydrothermal technique in presence of cetyltrimethylammonium bromide (CTAB) as surfactant was carried out by statistically designed experiments based on Box Behnken method. The mean parameters, surfactant concentration, time and temperature have been studied to show their effect on ZnO particle size and morphology. The results of experimental design indicate that the surfactant concentration, reaction time and temperature were significant. ZnO particles were investigated using XRD and SEM and the findings show that ZnO nanoparticles were formed at 100 ℃ and their crystallinity were improved with temperature rise from 100 to 200 ℃. Particle size of ZnO in the range of 39-76 nm is achieved using this technique.展开更多
It is investigated the interaction of Ge(IV) with bis(2,3,4-trigodroksifenolazo) benzidine (R) in the presence of KSAS (cationic surface active substances)-CPCl (cetylpyridinium chloride), CPBr (cetylpyridi...It is investigated the interaction of Ge(IV) with bis(2,3,4-trigodroksifenolazo) benzidine (R) in the presence of KSAS (cationic surface active substances)-CPCl (cetylpyridinium chloride), CPBr (cetylpyridinium bromide) and CTMABr (cetyltrimethylammonium bromide). It is studied the effect pH, time on the formation of ternary complexes. It is determinated of molar absorption coefficients and stability constants of germanium. Binary (Ge-R) and triple (Ge-R-CPCI, Ge-R-CPBr, Ge-R-CTMaBr) complex form at pH 4 and pH 1, respectively. The composition proportion of binar system is 1:2 and the composition proportion triple complex is 1:1:2. The concentration interval of germanium which obeying beer low in the Ge-R 0.12-2.92 mkq/mL, in the Ge-R-CPCI is 0.04-1.46 mkq/mL, in the Ge-R-CPBr is 0.00-1.00 mkq/mL and in the Ge-R-CTMaBr is 0.00-1.00 mkq/mL. Molar absorbtivities of complexes are 45,000, 57,000, 59,000 and 60,000, respectively. The effect of interfering ions and masking agents has been learned. Stability constants of complexes have been determined: lgKl = 7.21 + 0.06 (Ge-R),' lgK1 = 12.08 _+ 0.05 (Ge-R-CPCI), lgK1 = 12.12 + 0.07 (Ge-R-CPBr) and lgK1 = 12.85 + 0.06 (Ge-R-CTMaBr). It is developed highly selective method of photometric determination of trace amounts of Ge(IV) in petroleum coke.展开更多
Complex formation of cerium (Ⅲ) with l-phenyl-2,3-dimethylpyrazolone-5-azo-4-pyrogallole (L) in the presence and absence ofcetylpyridine chloride (CPC) was investigated. Homogeneous CeL- and mixed ligand CeL-CP...Complex formation of cerium (Ⅲ) with l-phenyl-2,3-dimethylpyrazolone-5-azo-4-pyrogallole (L) in the presence and absence ofcetylpyridine chloride (CPC) was investigated. Homogeneous CeL- and mixed ligand CeL-CPC compounds are formed at pH 6. Constants of stability of the complexes are (IgKD 5.15±0.02 (CeL), 7.98±0.03 (CeL-CPC). Ratio of reagents in composition of homogeneous is (1 :2) and in different ligand it equals to (1:2:2). Beer's law is observed in interval of concentration 1.12-11.2 μg/ml Ce. The technique for photometric determination of cerium was worked out in artificial mixture.展开更多
The purpose of this paper is to present and evaluate a method of free gait generation for HITCRI,a hexapod walking robot.The HITCR-I is designed as a modularized structure of legs that is based upon a four-bar linkage...The purpose of this paper is to present and evaluate a method of free gait generation for HITCRI,a hexapod walking robot.The HITCR-I is designed as a modularized structure of legs that is based upon a four-bar linkage mechanism and with force sensors in the tip of legs,distributed hardware structure and a modular software structure of the control system.Based on a set of local rules between adjacent legs,finite state machine(FSM) model is built to control the coordination of legs.An automatic smooth transition of gait pattern is achieved through deriving the mathematical relation between gait pattern and locomotion parameters.The disordered inter-leg phase sequence is adjusted to a regular state smoothly and quickly by the local rules based FSM,and the gait pattern can transform automatically adapting to irregular terrain.The experiment on HITCR-I has demonstrated that it can walk through irregular terrain reliably and expeditiously with the free gait controller designed in this paper.展开更多
The metastable phase 3c-Fe7S8 with the hexagonal platelet morphology has been prepared by using solvothermal route. The product was characterized by means of X-ray powder diffraction (XRD) and transmission electron mi...The metastable phase 3c-Fe7S8 with the hexagonal platelet morphology has been prepared by using solvothermal route. The product was characterized by means of X-ray powder diffraction (XRD) and transmission electron microscopy (TEM) and X-ray photoelectron spectra (XPS). The experiment results show that the as-prepared Fe7S8 is a metastable phase with the hexagonal platelet morphology.展开更多
Based on the coordinate rotation digital computer(CORDIC)algorithm,the high-speed kinematicscalculation for a six degree of freedom(DOF)space manipulator is implemented in a field programmablegate array(FPGA)co-proces...Based on the coordinate rotation digital computer(CORDIC)algorithm,the high-speed kinematicscalculation for a six degree of freedom(DOF)space manipulator is implemented in a field programmablegate array(FPGA)co-processor.A pipeline architecture is adopted to reduce the complexity and time-consumption of the kinematics calculation .The CORDIC soft-core and the CORDIC-based pipelined kine-matics calculation co-processor are described with the very-high-speed integrated circuit hardware descrip-tion language(VHDL)language and realized in the FPGA .Finally,the feasibility of the design is vali-dated in the Spartan-3 FPGA of Xilinx Inc.,and the performance specifications of FPGA co-processor arediscussed.The results show that time-consumption of the kinematics calculation is greatly reduced.展开更多
In this paper,we construct a new sixth order iterative method for solving nonlinear equations.The local convergence and order of convergence of the new iterative method is demonstrated.In order to check the validity o...In this paper,we construct a new sixth order iterative method for solving nonlinear equations.The local convergence and order of convergence of the new iterative method is demonstrated.In order to check the validity of the new iterative method,we employ several chemical engineering applications and academic test problems.Numerical results show the good numerical performance of the new iterative method.Moreover,the dynamical study of the new method also supports the theoretical results.展开更多
Objective The present retrospective study was to explore the clinical value of Six-Item Screener (SIS), which is constituted by 6 items from mini-mental status examination (MMSE), to identify cognitive impairment....Objective The present retrospective study was to explore the clinical value of Six-Item Screener (SIS), which is constituted by 6 items from mini-mental status examination (MMSE), to identify cognitive impairment. Methods A total number of 1976 patients aged over 50 years, from the Memory Clinic of Huashan Hospital were employed in a battery of neuropsychological tests including MMSE. Subjects with severe conditions, unable to cooperate, or having been previously enrolled, were excluded from this study. The employed subjects were divided into 3 groups: subjective memory complaints (SMCs) (475 cases), patients with mild cognitive impairment (MCI) (440 cases), and patients with Alzheimer's disease (AD) (1061 cases, including 555 mild, 339 moderate, and 167 severe). A total score of MMSE and a score of SIS composed of date, month, year, three-word delayed recall from MMSE were calculated. Data were analyzed based on educational background. Results The cut-off of SIS score was 〈 2 for illiterate, 〈 3 for elementary, and 〈 4 for junior high school or above. The sensitivity and specificity of SIS for detecting mild AD were 88.5% and 78.3%, respectively, with an overall accuracy of 83.8%, while for detecting MCI, the sensitivity and specificity were 34.3% and 90.1%, respectively, with an overall accuracy of 63.2%. Conclusion SIS is an effective and reliable instrument for dementia detection in outpatient department. However, it has limited value for MCI identification.展开更多
Obstacle avoidance is quite an important issue in the field of legged robotic applications, such as rescuing and detecting in complicated environment. Most related researchers focused on the legged robot’s gait gener...Obstacle avoidance is quite an important issue in the field of legged robotic applications, such as rescuing and detecting in complicated environment. Most related researchers focused on the legged robot’s gait generation after ssuming that obstacles have been detected and the walking path has been given. In this paper we propose and validate a novel obstacle avoidance framework for a six-legged walking robot Hexapod-III in unknown environment. Throughout the paper we highlight three themes: (1) The terrain map modeling and the obstacle detection; (2) the obstacle avoidance path planning method; (3) motion planning for the legged robot. Concretely, a novel geometric feature grid map (GFGM) is proposed to describe the terrain. Based on the GFGM, the obstacle detection algorithm is presented. Then the concepts of virtual obstacles and safe conversion pose are introduced. Virtual obstacles restrict the robot to walk on the detection terrain. A safe path based on Bezier curves, passing through safe conversion poses, is obtained by minimizing a penalty function taking into account the path length subjected to obstacle avoidance. Thirdly, motion planning for the legged robot to walk along the generated path is discussed in detail. At last, we apply the proposed framework to the Hexapod-III robot. The experimental result shows that our methodology allows the robot to walk safely without encountering with any obstacles in unknown environment.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos. 10975043, 10947166 and 10775037the Foundation of Bureau of Education, Hebei Province, China under Grant No. 2009108the Natural Science Foundation of Hebei Province, China under Grant No. A2008000564)
文摘In this paper, superlattice patterns have been investigated by using a two linearly coupled Brusselator model. It is found that superlattice patterns can only be induced in the sub-system with the short wavelength. Three different coupling methods have been used in order to investigate the mode interaction between the two Turing modes. It is proved in the simulations that interaction between activators in the two sub-systems leads to spontaneous formation of black eye pattern and/or white eye patterns while interaction between inhibitors leads to spontaneous formation of super-hexagonal pattern. It is also demonstrated that the same symmetries of the two modes and suitable wavelength ratio of the two modes should also be satisfied to form superlattice patterns.
基金Project(51221004) supported by the Science Fund for Creative Research Groups of National Natural Science Foundation of ChinaProject(2010R50036) supported by the Program for Zhejiang Leading Team of S&T Innovation,China
文摘Considering the compliance control problem of a hexapod robot under different environments, a control strategy based on the improved adaptive control algorithm is proposed. The model of robot structure and impedance control is established. Then, the indirect adaptive control algorithm is derived. Through the analysis of its parameters, it can be noticed that the algorithm does not meet the requirements of the robot compliance control in a complex environment. Therefore, the fuzzy control algorithm is used to adjust the adaptive control parameters. The satisfied system response can be obtained based on the adjustment in real time according to the error between input and output. Comparative experiments and analysis of traditional adaptive control and the improved adaptive control algorithm are presented. It can be verified that not only desired contact force can be reached quickly in different environments, but also smaller contact impact and sliding avoidance are guaranteed, which means that the control strategy has great significance to enhance the adaptability of the hexapod robot.
文摘The removal of chromium(Vl) from an aqueous solution using persimmon gel was examined. The amount of chromium(VI) removed was strongly affected by the pH of the solution, with all ehromium(VI) being removed at pH 2 or lower. However, in a solution containing, 15 mg dry weight of immobilized persimmon gel, the amount of removed chromium(VI) decreased as the pH increased. A part of chromium(VI) was reduced another oxidation stage, mainly chromium(III), by immobilized persimmon gel. The amount of reduced chromium(III) in the solution was increased with decreasing the pH of the solution. As a result, the amount of total chromium removed was maximal at pH 2. The amount of chromium removed were affected by the chromium concentration and the amount of gel. The maximal amount of chromium removed by the column system was also discussed.
文摘This article deals with implementation of the classification and regression trees into the DMAIC phases of Six Sigma methodology. Six Sigma methodology seeks to improve the quality of manufacturing process by identifying and minimizing variability of this process. Using the classification, regression and segmentation trees as a part of the Data Mining methods could improve results of DMAIC phases. This improvement has a direct impact on the Sigma performance level of processes. The author introduces research results of implementation Data Mining algorithms into retail sales promotion. The author implements classification and regression techniques in our research. As a software tool has been selected SPSS PASW Modeler. The author deals with more data mining algorithms ad their implementation in the DMAIC phases. The article is divided into several parts. The first part is the introduction to Six Sigma methodology, the second deals with classification and regression trees. The third part describes tree research focused on the implementation of data mining algorithms and the fourth section summarizes the research results.
基金Project supported by the Open Foundation of Guangxi Key Laboratory for Advanced Materials and Manufacturing Technology,China
文摘Electronic structures of monoclinic and hexagonal pyrrhotite were studied using density functional theory method,together with their flotation behavior. The main contribution of monoclinic pyrrhotite is mainly from Fe 3d, while that of hexagonal pyrrhotite is from Fe 3d, Fe 3p and S 3s. The hexagonal pyrrhotite is more reactive than monoclinic pyrrhotite because of large density of states near the Fermi level. The hexagonal pyrrhotite shows antiferromagnetism. S—Fe bonds mainly exist in monoclinic pyrrhotite as the covalent bonds, while hexagonal pyrrhotite has no covalency. The main contributions of higest occupied molecular orbital(HOMO) and lowest unoccupied molecular obital(LUMO) for monoclinic pyrrhotite come from S and Fe. The main contribution of HOMO for hexagonal pyrrhotite comes from Fe, while that of LUMO comes from S. The coefficient of Fe atom is much larger than that of S atom of HOMO for hexagonal pyrrhotite, which contributes to the adsorption of Ca OH+ on the surface of hexagonal pyrrhotite when there is lime. As a result, lime has the inhibitory effect on the floatation of hexagonal pyrrhotite and the coefficient of Fe is very close to that of S for monoclinic pyrrhotite. Therefore, the existence of S prevents the adsorption of Ca OH+on the surface of monoclinic pyrrhotite, which leads to less inhibitory effect on the flotation of monoclinic pyrrhotite.
基金Project(2007CB613607)supported by the National Basic Research Program of China
文摘A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by LiF and PF5 at room temperature(20-30℃)for 4 h.The synthesized LiPF6 was characterized by infrared spectrometry and X-ray diffraction(XRD). Atomic absorption and ion chromatography results show that the purity of synthesized LiPF6 reaches 99.98%.Thermal stability of self-synthesized LiPF6 was analyzed by differential thermal analysis and thermogravimetry.The results indicate that the self-synthesized LiPF6 has higher purity,lower impurity contents and better thermal stability than the commercial LiPF6.
基金The National Natural Science Foundation of China(No. 50475020)
文摘Uncertainties in engineering design may lead to low reliable solutions that also exhibit high sensitivity to uncontrollable variations. In addition, there often exist several conflicting objectives and constraints in various design environments. In order to obtain solutions that are not only "multi-objectively" optimal, but also reliable and robust, a probabilistic optimization method was presented by integrating six sigma philosophy and multi-objective genetic algorithm. With this method, multi-objective genetic algorithm was adopted to obtain the global Pareto solutions, and six sigma method was used to improve the reliability and robustness of those optimal solutions. Two engineering design problems were provided as examples to illustrate the proposed method.
文摘By a simple one-step H2-assisted thermal evaporation method, high quality CdS nanos- tructures have been successfully fabricated on Au coated Si substrates in large scale. The as-synthesized CdS nanostructures consisted of sword-like nanobelts and toothed nanosaws with a single-crystal hexagonal wurtzite structure. The deposition temperature played an important role in determining the size and morphology of the CdS nanostruetures. A combination of vapor-liquid-solid and vapor-solid growth mechanisms were proposed to interpret the formation of CdS nanostructures. Photoluminescence measurement indicated that the nanobelts and nanosaws have a prominent green emission at about 512 nm, which is the band-to-band emission of CdS. The waveguide characteristics of both types of CdS nanos-truetures were observed and discussed.
基金Project(2008AA04Z203) supported by the National High Technology Research and Development Program of China
文摘An optimal measurement pose number searching method was designed to improve the pose selection method.Several optimal robot measurement configurations were added to an initial pre-selected optimal configuration set to establish a new configuration set for robot calibration one by one.The root mean squares (RMS) of the errors of each end-effector poses after being calibrated by these configuration sets were calculated.The optimal number of the configuration set corresponding to the least RMS of pose error was then obtained.Calibration based on those poses selected by this algorithm can get higher end-effector accuracy,meanwhile consumes less time.An optimal pose set including optimal 25 measurement configurations is found during the simulation.Tracking errors after calibration by using these poses are 1.54,1.61 and 0.86 mm,and better than those before calibration which are 7.79,7.62 and 8.29 mm,even better than those calibrated by the random method which are 2.22,2.35 and 1.69 mm in directions X,Y and Z,respectively.
文摘Synthesis of ZnO nanoparticles by hydrothermal technique in presence of cetyltrimethylammonium bromide (CTAB) as surfactant was carried out by statistically designed experiments based on Box Behnken method. The mean parameters, surfactant concentration, time and temperature have been studied to show their effect on ZnO particle size and morphology. The results of experimental design indicate that the surfactant concentration, reaction time and temperature were significant. ZnO particles were investigated using XRD and SEM and the findings show that ZnO nanoparticles were formed at 100 ℃ and their crystallinity were improved with temperature rise from 100 to 200 ℃. Particle size of ZnO in the range of 39-76 nm is achieved using this technique.
文摘It is investigated the interaction of Ge(IV) with bis(2,3,4-trigodroksifenolazo) benzidine (R) in the presence of KSAS (cationic surface active substances)-CPCl (cetylpyridinium chloride), CPBr (cetylpyridinium bromide) and CTMABr (cetyltrimethylammonium bromide). It is studied the effect pH, time on the formation of ternary complexes. It is determinated of molar absorption coefficients and stability constants of germanium. Binary (Ge-R) and triple (Ge-R-CPCI, Ge-R-CPBr, Ge-R-CTMaBr) complex form at pH 4 and pH 1, respectively. The composition proportion of binar system is 1:2 and the composition proportion triple complex is 1:1:2. The concentration interval of germanium which obeying beer low in the Ge-R 0.12-2.92 mkq/mL, in the Ge-R-CPCI is 0.04-1.46 mkq/mL, in the Ge-R-CPBr is 0.00-1.00 mkq/mL and in the Ge-R-CTMaBr is 0.00-1.00 mkq/mL. Molar absorbtivities of complexes are 45,000, 57,000, 59,000 and 60,000, respectively. The effect of interfering ions and masking agents has been learned. Stability constants of complexes have been determined: lgKl = 7.21 + 0.06 (Ge-R),' lgK1 = 12.08 _+ 0.05 (Ge-R-CPCI), lgK1 = 12.12 + 0.07 (Ge-R-CPBr) and lgK1 = 12.85 + 0.06 (Ge-R-CTMaBr). It is developed highly selective method of photometric determination of trace amounts of Ge(IV) in petroleum coke.
文摘Complex formation of cerium (Ⅲ) with l-phenyl-2,3-dimethylpyrazolone-5-azo-4-pyrogallole (L) in the presence and absence ofcetylpyridine chloride (CPC) was investigated. Homogeneous CeL- and mixed ligand CeL-CPC compounds are formed at pH 6. Constants of stability of the complexes are (IgKD 5.15±0.02 (CeL), 7.98±0.03 (CeL-CPC). Ratio of reagents in composition of homogeneous is (1 :2) and in different ligand it equals to (1:2:2). Beer's law is observed in interval of concentration 1.12-11.2 μg/ml Ce. The technique for photometric determination of cerium was worked out in artificial mixture.
基金Supported by the National High Technology Research and Development Programme of China(No.2007AA041550)the National NaturalScience Foundation of China(No.51105101)
文摘The purpose of this paper is to present and evaluate a method of free gait generation for HITCRI,a hexapod walking robot.The HITCR-I is designed as a modularized structure of legs that is based upon a four-bar linkage mechanism and with force sensors in the tip of legs,distributed hardware structure and a modular software structure of the control system.Based on a set of local rules between adjacent legs,finite state machine(FSM) model is built to control the coordination of legs.An automatic smooth transition of gait pattern is achieved through deriving the mathematical relation between gait pattern and locomotion parameters.The disordered inter-leg phase sequence is adjusted to a regular state smoothly and quickly by the local rules based FSM,and the gait pattern can transform automatically adapting to irregular terrain.The experiment on HITCR-I has demonstrated that it can walk through irregular terrain reliably and expeditiously with the free gait controller designed in this paper.
基金This work was supported by the National Natural Science Foundation of China.
文摘The metastable phase 3c-Fe7S8 with the hexagonal platelet morphology has been prepared by using solvothermal route. The product was characterized by means of X-ray powder diffraction (XRD) and transmission electron microscopy (TEM) and X-ray photoelectron spectra (XPS). The experiment results show that the as-prepared Fe7S8 is a metastable phase with the hexagonal platelet morphology.
基金supported by the High Technology Research and Development Programme of China(No.2005AA742050)
文摘Based on the coordinate rotation digital computer(CORDIC)algorithm,the high-speed kinematicscalculation for a six degree of freedom(DOF)space manipulator is implemented in a field programmablegate array(FPGA)co-processor.A pipeline architecture is adopted to reduce the complexity and time-consumption of the kinematics calculation .The CORDIC soft-core and the CORDIC-based pipelined kine-matics calculation co-processor are described with the very-high-speed integrated circuit hardware descrip-tion language(VHDL)language and realized in the FPGA .Finally,the feasibility of the design is vali-dated in the Spartan-3 FPGA of Xilinx Inc.,and the performance specifications of FPGA co-processor arediscussed.The results show that time-consumption of the kinematics calculation is greatly reduced.
基金supported by the National Natural Science Foundation of China (No.12271518)the Key Program of the National Natural Science Foundation of China (No.62333016)。
文摘In this paper,we construct a new sixth order iterative method for solving nonlinear equations.The local convergence and order of convergence of the new iterative method is demonstrated.In order to check the validity of the new iterative method,we employ several chemical engineering applications and academic test problems.Numerical results show the good numerical performance of the new iterative method.Moreover,the dynamical study of the new method also supports the theoretical results.
文摘Objective The present retrospective study was to explore the clinical value of Six-Item Screener (SIS), which is constituted by 6 items from mini-mental status examination (MMSE), to identify cognitive impairment. Methods A total number of 1976 patients aged over 50 years, from the Memory Clinic of Huashan Hospital were employed in a battery of neuropsychological tests including MMSE. Subjects with severe conditions, unable to cooperate, or having been previously enrolled, were excluded from this study. The employed subjects were divided into 3 groups: subjective memory complaints (SMCs) (475 cases), patients with mild cognitive impairment (MCI) (440 cases), and patients with Alzheimer's disease (AD) (1061 cases, including 555 mild, 339 moderate, and 167 severe). A total score of MMSE and a score of SIS composed of date, month, year, three-word delayed recall from MMSE were calculated. Data were analyzed based on educational background. Results The cut-off of SIS score was 〈 2 for illiterate, 〈 3 for elementary, and 〈 4 for junior high school or above. The sensitivity and specificity of SIS for detecting mild AD were 88.5% and 78.3%, respectively, with an overall accuracy of 83.8%, while for detecting MCI, the sensitivity and specificity were 34.3% and 90.1%, respectively, with an overall accuracy of 63.2%. Conclusion SIS is an effective and reliable instrument for dementia detection in outpatient department. However, it has limited value for MCI identification.
基金supported by the National Basic Research Program of China (Grant No. 2013CB035501)
文摘Obstacle avoidance is quite an important issue in the field of legged robotic applications, such as rescuing and detecting in complicated environment. Most related researchers focused on the legged robot’s gait generation after ssuming that obstacles have been detected and the walking path has been given. In this paper we propose and validate a novel obstacle avoidance framework for a six-legged walking robot Hexapod-III in unknown environment. Throughout the paper we highlight three themes: (1) The terrain map modeling and the obstacle detection; (2) the obstacle avoidance path planning method; (3) motion planning for the legged robot. Concretely, a novel geometric feature grid map (GFGM) is proposed to describe the terrain. Based on the GFGM, the obstacle detection algorithm is presented. Then the concepts of virtual obstacles and safe conversion pose are introduced. Virtual obstacles restrict the robot to walk on the detection terrain. A safe path based on Bezier curves, passing through safe conversion poses, is obtained by minimizing a penalty function taking into account the path length subjected to obstacle avoidance. Thirdly, motion planning for the legged robot to walk along the generated path is discussed in detail. At last, we apply the proposed framework to the Hexapod-III robot. The experimental result shows that our methodology allows the robot to walk safely without encountering with any obstacles in unknown environment.