The microstructural features and the consequent mechanical properties were characterized in aluminium borate whisker(ABOw)(5, 10 and 15 wt.%) reinforced commercially-pure aluminium composites fabricated by conventiona...The microstructural features and the consequent mechanical properties were characterized in aluminium borate whisker(ABOw)(5, 10 and 15 wt.%) reinforced commercially-pure aluminium composites fabricated by conventional powder metallurgy technique. The aluminium powder and the whisker were effectively blended by a semi-powder metallurgy method. The blended powder mixtures were cold compacted and sintered at 600 ℃. The sintered composites were characterized for microstructural features by optical microscopy(OM), scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS), transmission electron microscopy(TEM) and X-ray diffraction(XRD) analysis. Porosity in the composites with variation in ABOw contents was determined. The effect of variation in content of ABOw on mechanical properties, viz. hardness, bending strength and compressive strength of the composites was evaluated. The dry sliding wear behaviour was evaluated at varying sliding distance at constant loads. Maximum flexural strength of 172 MPa and compressive strength of 324 MPa with improved hardness around HV 40.2 are obtained in composite with 10 wt.% ABOw. Further increase in ABOw content deteriorates the properties. A substantial increase in wear resistance is also observed with 10 wt.% ABOw. The excellent combination of mechanical properties of Al-10 wt.%ABOw composites is attributed to good interfacial bonds, less porosity and uniformity in the microstructure.展开更多
Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrolo...Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolu- tion, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios （δ13C = 2.14%o, 8180 = -5.77‰）, and was precipitated early. It was precipitated di- rectly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid（ δ180 = -3‰）, which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios （δ13C = -2.36%0, 8180 = -15.68‰）. This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2＋, Fe3＋ and Mg2＋ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the buri- al process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite ce- ments in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone （δ13C = 1.93%o, δ180 = -6.11‰）, demonstrating that the two are from the same source that had a heavier oxygen isotope ratio （δ180 of about 2.2‰）. The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different wa- ter-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles （lithic quartz sand- stone） has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.展开更多
基金support provided by the Central Instrument Facility Centre(CIFC)of IIT(BHU)the Department of Ceramic Engineering especially Advance Refractory Lab(ARL)of IIT(BHU)Varanasi。
文摘The microstructural features and the consequent mechanical properties were characterized in aluminium borate whisker(ABOw)(5, 10 and 15 wt.%) reinforced commercially-pure aluminium composites fabricated by conventional powder metallurgy technique. The aluminium powder and the whisker were effectively blended by a semi-powder metallurgy method. The blended powder mixtures were cold compacted and sintered at 600 ℃. The sintered composites were characterized for microstructural features by optical microscopy(OM), scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS), transmission electron microscopy(TEM) and X-ray diffraction(XRD) analysis. Porosity in the composites with variation in ABOw contents was determined. The effect of variation in content of ABOw on mechanical properties, viz. hardness, bending strength and compressive strength of the composites was evaluated. The dry sliding wear behaviour was evaluated at varying sliding distance at constant loads. Maximum flexural strength of 172 MPa and compressive strength of 324 MPa with improved hardness around HV 40.2 are obtained in composite with 10 wt.% ABOw. Further increase in ABOw content deteriorates the properties. A substantial increase in wear resistance is also observed with 10 wt.% ABOw. The excellent combination of mechanical properties of Al-10 wt.%ABOw composites is attributed to good interfacial bonds, less porosity and uniformity in the microstructure.
基金supported by the State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Foundation (Grant No. PLC201101)the National Natural Science Foundation of China (Grant Nos. 41172119 and 41272130)
文摘Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolu- tion, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios （δ13C = 2.14%o, 8180 = -5.77‰）, and was precipitated early. It was precipitated di- rectly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid（ δ180 = -3‰）, which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios （δ13C = -2.36%0, 8180 = -15.68‰）. This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2＋, Fe3＋ and Mg2＋ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the buri- al process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite ce- ments in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone （δ13C = 1.93%o, δ180 = -6.11‰）, demonstrating that the two are from the same source that had a heavier oxygen isotope ratio （δ180 of about 2.2‰）. The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different wa- ter-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles （lithic quartz sand- stone） has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.
