A series of liquid crystalline polymers with two-dimensional mesogenic units were synthesized by solution polycondensation at low temperature. All the polymers were liquid crystalline. The melting temperature T;(exce...A series of liquid crystalline polymers with two-dimensional mesogenic units were synthesized by solution polycondensation at low temperature. All the polymers were liquid crystalline. The melting temperature T;(except that with substituent of methoxy) and the clearing temperature T;of the polymers change regularly with varying of the length of the alkyl substituent groups.展开更多
基金This work was supported by the FEYUT, SEDC, CHINA and by the National Natural Science Foundation of China.
文摘A series of liquid crystalline polymers with two-dimensional mesogenic units were synthesized by solution polycondensation at low temperature. All the polymers were liquid crystalline. The melting temperature T;(except that with substituent of methoxy) and the clearing temperature T;of the polymers change regularly with varying of the length of the alkyl substituent groups.