Syntheses and properties of associative acrylamide copolymers containing short hydrophobic chains used in a friction reducer for slick-water fracturing

Two allyldimethylalkyl quaternary ammonium salt(AQAS)monomers,N,N-dimethylallylphenylpropylammonium bromide(AQAS1)and N,N-dimethylallylnonylammonium bromide(AQAS2),were synthesized and used to prepare modified polyacrylamide materials.Two new drag reducers were synthesized from acrylamide(AM),sodium acrylate(Na AA)and a cationic modified monomer(AQAS1 or AQAS2)via aqueous solution polymerization,and the copolymers were named P(AM/Na AA/AQAS1)and P(AM/Na AA/AQAS2),respectively.The structures of the drag reduction agents were confirmed by IR and1H NMR spectroscopies.The molecular weight(Mw)of P(AM/Na AA/AQAS1)was 1.79×10^(6)g/mol.When the copolymer concentration was 1000 mg/L and the flow rate was 45 L/min,in fresh water the highest drag reduction rate was 75.8%,in 10,000 mg/L Na Cl solution the drag reduction rate decreased to 72.9%.The molecular weight of P(AM/Na AA/AQAS2)was 3.17×10^(6)g/mol.When the copolymer concentration was500 mg/L and the flow rate was 45 L/min,the drag reduction rate reached 75.2%,and in 10,000 mg/L Na Cl solution the drag reduction rate was 73.3%,decreased by approximately 1.9%.The drag reduction rate for partially hydrolyzed polyacrylamide(HPAM)was also investigated,and the results showed that the drag reduction rates for 500 and 1000 mg/L HPAM solutions were merely 43.2%and 49.0%in brine,respectively.Compared with HPAM,both of the above copolymers presented better drag reduction capacities.

A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction

In reverse water gas shift （RWGS） reaction COa is converted to CO which in turn can be used to pro- duce beneficial chemicals such as methanol. In the present study, Mo/AlaO3, Fe/AlaO3 and Fe-Mo/Al2O3 catalysts were synthesised using impregnation method. The structures of catalysts were studied using X-ray diffraction （XRD）, Brunauer-Emmett-Teller （BET） method, inductively coupled plasma atomic emission spectrometer （ICP-AES）, temperature programmed reduction （H2-TPR）, CO chemisorption, energy dispersive X-ray （EDX） and scanning electron microscopy （SEM） techniques. Kinetic properties of all catalysts were investigated in a batch re- actor for RWGS reaction. The results indicated that Mo existence in structure of Fe-Mo/AlzO3 catalyst enhances its activity as compared to Fe/AlaO3. This enhancement is probably due to better Fe dispersion and smaller particle size of Fe species. Stability test of Fe-Mo/AlzO3 catalyst was carried out in a fixed bed reactor and a high CO yield for 60 h of time on stream was demonstrated. Fez（MoO4）3 phase was found in the structures of fresh and used catalysts. TPR results also indicate that Fez（MoO4）3 phase has low reducibility, therefore the Fe2（MoO4）3 phase significantly inhibits the reduction of the remaining Fe oxides in the catalyst, resulted in high stability of Fe-Mo/Al2O3 catalyst. Overall, this study introduces Fe-Mo/Al2O3 as a novel catalyst with high CO yield, almost no by-products and fairly stable for RWGS reaction.

Electrochemical Fabrication of rGO-embedded Ag-TiO2 Nanoring/Nanotube Arrays for Plasmonic Solar Water Splitting

Effective utilization of hot electrons generated from the decay of surface plasmon resonance in metal nanoparticles is conductive to improve solar water splitting efficiency.Herein,Ag nanoparticles and reduced graphene oxide(rGO)co-decorated hierarchical TiO2 nanoring/nanotube arrays(TiO2 R/T)were facilely fabricated by using two-step electrochemical anodization,electrodeposition,and photoreduction methods.Comparative studies were conducted to elucidate the effects of rGO and Ag on the morphology,photoresponse,charge transfer,and photoelectric properties of TiO2.Firstly,scanning electron microscope images confirm that the Ag nanoparticles adhered on TiO2 R/T and TiO2 R/T-rGO have similar diameter of 20 nm except for TiO2 R-rGO/T.Then,the UV-Vis DRS and scatter spectra reveal that the optical property of the Ag-TiO2 R/T-rGO ternary composite is enhanced,ascribing to the visible light absorption of plasmonic Ag nanoparticles and the weakening effect of rGO on light scattering.Meanwhile,intensity-modulated photocurrent spectroscopy and photoluminescence spectra demonstrate that rGO can promote the hot electrons transfer from Ag nanoparticles to Ti substrate,reducing the photogenerated electron-hole recombination.Finally,Ag-TiO2 R/T-rGO photoanode exhibits high photocurrent density(0.98 mA cm?2)and photovoltage(0.90 V),and the stable H2 evolution rate of 413μL h?1 cm?2 within 1.5 h under AM 1.5 which exceeds by 1.30 times than that of pristine TiO2 R/T.In line with the above results,this work provides a reliable route synergizing rGO with plasmonic metal nanoparticles for photocatalysis,in which,rGO presents a broad absorption spectrum and effective photogenerated electrons transfer.

A high salt tolerance and low adsorption drag reducer based on non-covalent enhancement

To formulate fluids with flowback water,produced water directly to improve the utilization rate of recycling and reduce the adsorption damage of slick water to reservoirs,a high salt tolerance and low adsorption drag reducer was designed and prepared by introducing polar cation fragments to enhance the non-covalent interactions between the chains.The drag reducer was characterized by IR and NMR.Friction resistance and viscosity tests were conducted to evaluate its salt resistance property.Static adsorption and dynamic adsorption retention tests were carried out to evaluate the damage of this reducer to shale reservoirs.The introduction of cation units into the molecular structure can weak the shielding effect of metal cations to some extent,so the drag reducer can keep a stable molecular structure and good resistant reducing performance under high salinity.The enhancement of non-covalent interaction between chains decreased the free polarity sites,further reduced the possibility of hydrogen bonding between drag reducer molecules and shale.In high salinity condition,both the adsorption capacity of the drag reducer on the shale surface and the average damage rate to the core permeability are low.Compared with the conventional salt-tolerant system,the overall liquid cost was reduced by 17%and the production per well increased by 44%.The application of this slick water system has achieved remarkable results.

THE SLUMP RETENTION OF N-2000 HIGH-RANGE WATER-REDUCING AND RETARDING ADMIXTURE

N-2000 is an admixture for concrete, with a low slump loss, high range water-reducing ratio and long-time retarding. The N-2000 is made up of naphthalene-sulfonic-maldehyde polycondensation (NSMP) and ATMP. Its characteristic results from the synergistic effects of NSMP and ATMP. The results show that when 0.7%-1.2% of N-2000 is added to concrete (by mass of cement), the water reducing ratio is up to 20%-30%, and the slump of fresh concrete can be retained for 2 hours without significant loss. N-2000 can not only improve the workability of fresh concrete but also increase the strength of the hardened concrete, especially early strength. It is also proved to have a good compatibility with various cements.

Five Years of Rice Cultivation in Paddy Fields for Treated Water from Humus Bioreactor-Type Rural Wastewater Treatment Plants

The treated sewage has a color as well as odor and is difficult to reuse.Physical methods to reduce color with odor are costly and more difficult to reuse.Since the color and odor were reduced by pellet-type bioreactor sewage treatment using humus,rice was cultivated for 3 years.Industrially,3 years is sufficient to investigate the stability of treatment facilities,but when biological treatment is applied,5 to 10 years of investigation is required.In addition,in rice cultivation,a similar 5 to 10 years survey is required to investigate the accumulation of low-concentration pollutants.This report is a five-year report and is the result of paddy rice cultivation in a stable wastewater treatment facility.The cultivated rice fully satisfied the edible standards and was able to obtain safe rice,and the effect of reducing fertilizer applied was obtained by using nitrogen and phosphorus from the treated water.In addition,the yield was able to be within the range of the standard yield of 500 kg to 550 kg/1,000 m^(2).

Sprinkler Irrigation and Soil Tillage Practices in Sugarcane Plantations as Influenced by Soil Texture and Water Storage in Northern Ivory Coast

Soil survey investigations were carried out in Ferk6 1 as well as Ferk6 2 sugar mills of northern Ivory Coast to determine soil texture and water storage capacity for sprinkler irrigation and tillage management. A 5-year term observation experiment on reduced tillage compared with conventional tillage was also conducted in Ferk6 1 over an irrigated cane crop of 28 ha for yield optimization purpose. Soil sampling was achieved after harvest or prior to re-plantation at five different spots along two transects over 30 cm depth in every farmland which covers about 30-40 ha with 432 m long cane rows as to get an average soil sample of 1.5-2 kg. Soil physical properties like texture and water retention curves were determined locally in the sugar company＇s soil laboratory. It came out that the majority of soils investigated was coarse-textured for about 64% in Ferk6 1 and 85% in Ferk6 2, with a lower to medium water storage capacity （70-89 mm） over 60 cm depth which corresponds to a readily available moisture less than 60 mm. Except for the sugarcane plant crop, no significant difference in cane yields resulting from tillage practices was observed over four consecutive cropping seasons. The yield decline from plant cane to first ratoon was very high under conventional tillage （-16 t/ha） compared with the reduced tillage （＋3 t/ha）. Even higher cane yield was obtained on the second ratoon （89 t/ha） compared with the conventional tillage （83 t/ha）.

Survey-Based Analysis of Water Consumption Law in High-Rise Public Buildings and Water-Saving Performance of Pressure-Reducing Measures

Facing the contradiction of water scarcity and water wastage in most cities of China, this study aims at probing into the factors influencing water-use efficiency and assessing water-saving potential by adopting pressure control measures based on field survey conducted in 23 high-rise buildings in Suqian, China and laboratory tests. Results showed that per capita water consumption (PCWC) exceeding water consumption norms is common in these buildings. The hourly water consumption variation law is quite different among different types of buildings. These differences should be considered in designing building water supply systems to lower water and energy consumption. On the basis of correlation analysis, the order of factors influencing the PCWC follows average tap water pressure, percapita building area, and building age, suggesting pressure management in high-rise buildings is a key water-saving measure. Field tests of outflow characteristics under different water pressures indicated that over-pressure outflow (OPO) is a common cause of water wastage in buildings, however, no branch pipe pressure control measures were found in all the surveyed buildings. Laboratory tests showed that branch pipe pressure-reducing measures can lower water consumption and improve the comfortability of use as well. Therefore, in addition to applying high efficiency water-saving devices, we strongly recommend that branch pipe pressure-reducing measures should be strictly implemented in designing new building water supply systems and reconstruction of existing old building water supply systems, thereby, promoting water, energy saving and development of green building.

水溶肥替代及减量对朝天椒产量、品质和土壤养分残留的影响

为探究适于朝天椒生产的水溶肥最佳施用方式,通过田间试验研究水溶肥替代常规化肥及减量对朝天椒产量、品质及土壤养分残留的影响,共设置7个处理:CK(常规化肥)、T1(100%替代)、T2(T1减量20%,100%替代)、T3(T1减量40%,100%替代)、T4(50%替代)、T5(T4减量20%,50%替代)、T6(T4减量40%,50%替代)。结果表明,与CK相比,T1和T4处理产量分别提高21.09%和26.92%,品质提高;减量20%条件下,T2和T5处理产量分别提高14.28%和15.23%,品质提高;减量40%条件下,T3和T6处理产量分别提高7.41%和4.29%,品质提高,土壤养分残留量降低。综合考虑朝天椒的产量、品质及环境效益,水溶肥50%替代优于100%替代,替代后减量20%~40%在生产上是可行的。T5处理是生产上适宜推广的最佳施用方式。

水分优化管理对稻虾共作模式水稻产量及土壤还原性物质的影响

通过探索水分优化管理对稻虾共作模式水稻产量及土壤还原性物质的影响,为该模式下水稻水分管理和土壤改良提供科学依据。在水稻直播和机插两种种植方式下,分别设置以水稻分蘖后期和成熟期两次重晒田等措施为主的水分优化管理处理、以水稻分蘖后期和成熟期两次轻晒田等措施为主的水分常规管理处理,于湖北省潜江市采用田间定位试验开展研究。结果表明,在水稻直播和机插条件下,水分优化管理相对于常规管理平均增产率分别为8.5%和9.4%,增产效果均达到显著水平。相对于常规管理,水分优化管理对水稻有效穗数和每穗粒数的正效应大于结实率和千粒质量。水稻分蘖后期,水分优化管理相对于常规管理0~10 cm土层亚铁含量下降40.8%~41.8%,0~20 cm土层还原性物质总量下降45.1%~46.4%;与分蘖后期相比,水稻收获后0~20 cm土层亚铁和还原性物质总量总体呈下降趋势。由此表明,稻虾共作模式下分蘖后期和成熟期两次重晒田等水分优化管理措施能够显著增加水稻产量,缓解土壤潜育化程度。

利用制浆黑液研制混凝土减水剂及其在建筑工程上的应用研究

在制浆造纸过程中产生的大量制浆黑液对环境有很大危害,处理制浆黑液时要把环境和水源的保护考虑在内。目前制浆黑液混凝土减水剂的研发及应用于建筑工程,是安全绿色处理制浆黑液的有效途径,不仅使废料重新利用,还节约了减水剂制造成本,达到双赢效果。制浆黑液研制的减水剂对混凝土制品抗压性能和抗渗性能的提升及其在建筑工程上的应用是建筑行业及制浆造纸行业的巨大突破。废料的二次利用不仅节约了制造成本,还降低了混凝土的生产成本,更好地保护了环境,从而实现了可持续发展,为以后的制浆黑液废液处理提供了新的思考方向和借鉴价值。

一种具有超长侧链的疏水缔合型聚合物的合成及减阻性能评价

采用曲拉通和丙烯酰氯醇解合成一种水溶性可聚合单体,仅使用水作为溶剂合成一种具有超长侧链的疏水缔合型聚丙烯酰胺(HAPAM)作为减阻剂,通过分子动力学模拟方法对比了聚丙烯酰胺、部分水解聚丙烯酰胺和合成的具有超长侧链的HAPAM与水的相互作用,并分别以去离子水和盐水配液改变HAPAM含量,测量不同HAPAM含量的滑溜水在不同流速下的摩阻,并计算相应的减阻率。实验结果表明,具有超长侧链的HAPAM与水的相互作用最强;减阻率随流速的增加而增大,HAPAM含量越高,减阻率达到70%所需的流速越高,减阻率最高可达80%以上;盐对滑溜水的减阻率和黏度有显著负面影响,需提高HAPAM含量才能获得理想的减阻率;SEM表征结果显示,HAPAM在清水和盐水中的分布形态均为网状结构。

预制构件用水泥基修补砂浆的制备及应用研究

为修补预制构件施工过程中缺角、裂缝等缺陷,以硅酸盐水泥、硫铝酸盐水泥和半水石膏作为胶凝体系,掺加适量减水剂、乳胶粉和其他助剂,制备一种凝结时间短、早期强度高的水泥基修补砂浆,并对其性能进行研究。结果表明,掺加减水剂可以提高修补砂浆的抗压强度和流动度,掺加乳胶粉会延长砂浆的凝结时间,降低抗压强度,同时砂浆流动度则随乳胶粉掺量的增加先增大后减小。减水剂掺量以0.20%为宜,乳胶粉掺量以5.0%为宜,此时修补砂浆的初、终凝时间分别为15.8、22.4 min,7、28 d抗压强度分别为32.2、55.1 MPa,流动度为212 mm。

水下流态固化土强度与流动性能试验研究

为了完善流态固化土水下施工性能与无侧限抗压强度研究,通过向不同初始含水率的土体中添加减水剂、水泥和絮凝剂,研究含水率、减水剂掺量、水泥掺量和絮凝剂掺量对流态固化土浆体的流动性、抗分散性和流态固化土的力学性能的演化规律。结果表明,只使用水泥不能明显调节流态固化土浆体的流动性和抗分散性;絮凝剂和水泥掺量的增加可以提高流态固化土浆体的抗分散性和固化土的力学性能,对流态固化土浆体的流动性有抑制作用;减水剂和含水率升高对流态固化土浆体的流动性具有促进作用,对流态固化土浆体的抗分散性和力学性能有抑制作用。

水能风机在循环水冷却系统的应用

介绍了循环水冷却系统中采用水能风机代替大功率电动机实现节能降耗的实施措施,分析了改造后带来的经济效益。

基于正交试验的外加剂对混凝土力学性能的试验研究

为了探究复掺外加剂对混凝土的韧性和抗裂性能的影响规律,以期解决工程防护和加固过程中的混凝土开裂、剥落等工程实际问题,通过正交试验研究了速凝剂、早强剂、膨胀剂和粉煤灰对混凝土的抗压强度和劈裂抗拉强度的影响规律。试验结果表明:速凝剂能显著改善混凝土的抗压强度和劈裂抗拉强度;复合早强剂能有效提高混凝土的劈裂抗拉强度;粉煤灰和膨胀剂对混凝土28d抗压强度和劈裂抗拉强度没有显著影响。通过方差分析和数据拟合,可得早强剂和速凝剂的建议掺量分别为4%和1.5%,膨胀剂的最优掺量为3%,粉煤灰的最优掺量为25%。

低品位砂岩气藏压裂技术研究及应用——以DF109H井为例

四川盆地中部东峰场地区上三叠统须家河组气藏孔隙度、渗透率特低,含水饱和度高,常压,前期采用常规压裂后天然气增产及稳产效果差。为了动用该区须家河组低品位天然气储量,在新井DF109H开展了压裂技术系统化攻关,通过对减小地层伤害、加快返排、增大改造体积、支撑剂高效铺置等开展研究,形成了地质工程一体化紧密结合的高效压裂技术。研究结果表明:①前置液氮气体增能及水性降阻剂工作液体系,在常压致密气藏能增加返排能量,加快排液,降低储层伤害,实现天然气产能快速突破;②优选测录井甜点射孔,差异化高密度布缝,通过大排量、复合暂堵等提升人造裂缝体积,降低渗流距离,提升远端供给能力;③提升裂缝长期有效性是稳产的关键,加砂阶段伴注纤维+分散剂,采用脉冲段塞注入模式,使支撑剂铺置更为均匀。结论认为,该技术体系应用后天然气产量大幅度提升,在致密气藏显示了较好适应性,成为该区致密砂岩气藏有效开发的重要技术措施。

河西灌区减氮条件下小麦复种绿肥的水分利用及经济效益

【目的】针对河西绿洲灌区作物生产中氮肥施用过量、水资源利用效率与经济效益较低等问题,探讨麦后复种绿肥及适量减施化学氮肥对小麦农田耗水特性及经济效益的影响。【方法】2019—2020年在甘肃省河西绿洲灌区进行裂区试验,主区设置麦后复种绿肥(W-G)和单作小麦(W)两种种植模式;副区为5个施氮水平,分别为不施氮肥(N_(0))、常规施氮(180 kg·hm^(-2),N_(4))、减施45%氮肥(N_(1))、减施30%氮肥(N_(2))和减施15%氮肥(N_(3))。测定不同处理下小麦绿肥体系产量、水资源利用效率及经济效益。【结果】麦后复种绿肥以及适量减施化学氮肥显著提高小麦籽粒产量和系统生物热能产,2019和2020年,W-G较W处理籽粒产量分别提高10.8%和12.4%,系统生物热能产分别提高37.8%和40.3%;麦后复种绿肥结合减氮15%(W-G-N_(3))较单作小麦结合减氮15%(W-N_(3))和单作小麦传统施氮(W-N_(4))处理小麦分别增产6.9%—16.7%和7.9%—13.6%,生物热能产提高52.0%—62.2%和27.1%—58.9%。W-G较W小麦生育阶段耗水量降低6.3%—16.0%,W-G-N_(3)较W-N_(3)和W-N_(4)小麦季耗水量分别降低13.4%—20.5%和20.8%—29.0%,W-G由于绿肥生长季消耗水分,总耗水量显著高于W。W-G较W小麦水分利用效率分别提高7.9%和19.2%;2019年度W-G-N_(3)较W-N_(3)和W-N_(4)小麦水分利用效率分别提高23.5%和5.1%,差异显著。W-G-N_(3)可有效提高系统单位耗水生物热能产,较W-N_(3)和W-N_(4)分别提高2.7%—14.5%和9.3%—17.5%。W-G较W增加了成本投入,总产值也随之提高;2019年度W-G-N_(3)较W-N_(3)和W-N_(4)纯收益分别提高9.8%和9.5%,2020年度W-G-N_(3)较W-N_(3)和W-N_(4)纯收益则分别降低了15.6%和15.7%;2019和2020年W-G较W产投比分别降低20.7%和23.1%,W-G-N_(3)较W-N_(3)和W-N_(4)产投比降低比例均为14.8%—23.1%,W-G因较多的资源投入降低了系统单方水效益。【结论】在河西绿洲灌区,麦后复种绿肥结合适量减施化学氮肥能够提高作物产量和经济效益,水资源利用效率也随之提高,其中麦后复种绿肥结合减量15%施氮处理的综合效果最好,可作为提高水资源利用及农民收益的理想种植模式及施氮水平。

无黏土水基钻井液用超支化聚合物降滤失剂的合成及性能评价

在高温条件下,聚丙烯酰胺类降滤失剂分子易发生降解,导致降滤失效果大幅下降。为此,通过超支化单体季戊四醇三烯丙基醚(APE)与2-丙烯酰胺-2-甲基丙磺酸(AMPS)、丙烯酰胺(AM)、对苯乙烯磺酸钠(SSS)共聚合成了一种耐高温的超支化聚合物降滤失剂JHPAS,以JHPAS为基础配制了一种新型的无黏土水基钻井液,分析其降滤失机理,评价其在高温、高盐条件下的流变性能和降滤失性能。结果表明:JHPAS具有很好的热稳定性,在水溶液中可形成网络结构,在无黏土水基钻井液中吸附于超细CaCO 3表面形成致密滤饼,并堵塞滤饼上的孔隙,进一步降低钻井液滤失量;构筑的无黏土水基钻井液在200℃老化16 h、饱和氯化钠盐水的条件下仍具有稳定的流变性和良好的降滤失性能,API滤失量和高温高压滤失量分别为5.5 mL和7.6 mL。研究成果有助于推动超支化聚合物在深层、超深层油藏钻井液中的研究与应用。

基于FCM-GA灌溉供水管网减压阀布设优化

为探究灌溉供水管网中存在的漏损过高以及局部压力过大的问题,提出了一种基于FCM-GA的供水管网减压阀布设优化方法,该方法借助MATLAB、EPANET、MATLAB-EPANET-Toolkit以及PlatEMO平台等工具,对西班牙的BIN管网进行分区布置减压阀并优化阀后压力,以不同分区方案的成本与降漏效果为控制指标,筛选出最优方案。结果显示:最优方案(分5个区)将整个管网的漏损率降低至7.45%,相较初始管网降低了20.04%,降低的漏损费用可达114€/d,在减压阀服务年限内可收回成本并达到盈利,并实现对整个管网系统的压力管理,提高了管网的稳定性和可靠性,有利于减少管网事故发生。因此,基于FCM-GA的灌溉供水管网减压阀布设优化是一种安全、低成本和高效益的降漏与控压方法,在有效降低灌溉用水费用的同时,可更好地实现节水灌溉。