A new polymer [Zn2(cam)2(bpmp)]n 1 (H2cam = D-(+)-camphoric acid, bpmp = bis(4-pyridylmethyl)piperazine) was synthesized under hydrothermal conditions. The compound crystallizes in the monoclinic system, sp...A new polymer [Zn2(cam)2(bpmp)]n 1 (H2cam = D-(+)-camphoric acid, bpmp = bis(4-pyridylmethyl)piperazine) was synthesized under hydrothermal conditions. The compound crystallizes in the monoclinic system, space group P21/n with a = 12.305(9), b = 12.945(9), c = 13.619(10) A, β = 116.833(8)°, V= 1936(2)A3, Z = 4, Mr = 397.76, Dc= 1.365 Mg/m3,μ = 1.292 mm-1, F(000) = 832, the final R = 0.0578 and wR = 0.1678 for 2838 observed reflections with I 〉 2σ(I). The compound presents a three-dimensional (3D) network extended by homochiral 2D layer and bpmp ligands. From the topology point of view, the structure could be described as a 3D 6-connected mab net with (44.610.8) topology. In addition, infrared spectroscopy, elemental analyses, thermogravimetric analysis and powder X-ray diffraction properties of 1 are also investigated.展开更多
基金Supported by the National Natural Science Foundation of China(No.21076063)Foundation of Henan Educational Committee(No.13A150244)
文摘A new polymer [Zn2(cam)2(bpmp)]n 1 (H2cam = D-(+)-camphoric acid, bpmp = bis(4-pyridylmethyl)piperazine) was synthesized under hydrothermal conditions. The compound crystallizes in the monoclinic system, space group P21/n with a = 12.305(9), b = 12.945(9), c = 13.619(10) A, β = 116.833(8)°, V= 1936(2)A3, Z = 4, Mr = 397.76, Dc= 1.365 Mg/m3,μ = 1.292 mm-1, F(000) = 832, the final R = 0.0578 and wR = 0.1678 for 2838 observed reflections with I 〉 2σ(I). The compound presents a three-dimensional (3D) network extended by homochiral 2D layer and bpmp ligands. From the topology point of view, the structure could be described as a 3D 6-connected mab net with (44.610.8) topology. In addition, infrared spectroscopy, elemental analyses, thermogravimetric analysis and powder X-ray diffraction properties of 1 are also investigated.
基金the financial supports from the National Key R&D Program of China (No. 2020YFC1909203)the National Natural Science Foundation of China (Nos.51974364, 52074355, 51904339)the Key Laboratory of Hunan Province for Clean and Efficiency Utilization of Strategic Calciumcontaining Mineral Resources, China (No. 2018TP1002)。