On the basis of hydrographic data obtained in August 2000 cruise, the circulation in the South China Sea (SCS) is computed by the modified inverse method in combination with SSH data from TOPEX/ERS-2 analysis. For stu...On the basis of hydrographic data obtained in August 2000 cruise, the circulation in the South China Sea (SCS) is computed by the modified inverse method in combination with SSH data from TOPEX/ERS-2 analysis. For study of the dynamical mechanism, which causes the pattern of summer circulation in the SCS, the diagnostic model (Yuan et al. 1982. Acta Oceanologica Sinica,4(1):1-11; Yuan and Su. 1992. Numerical Computation of Physical Oceanography.474-542) is used to simulate numerically the summer circulation in the SCS. The following results have been obtained. (1) The central and southwestern SCSs are dominated mainly by anticy-clonic circulation systems. They are mainly as follows. 1) There is strong anticyclonic eddy southeast of Vietnam (W1). Its horizontal scale is about 300 km, and it extends vertically from the surface to the about 1 000 m level. 2) There are a warm eddy W2 southeast of Zhongsha Islands and the anticyclonic circulation system W3 west off the Luzon Island. 3) There is a stronger cyclonic eddy C1 between the anticyclonic eddies W1 and W2.4) A strong northward coastal jet is present near the coast of Vietnam, and separates from the coast of Vietnam at about 12° N to the northeast.(2)The northern SCS is dominated mainly by a cyclonic circulation system. There is a cyclonic circulation system near and north of Section N2. (3) The southeastern SCS is dominated mainly by the cyclonic circulation system. (4) Comparing the results of circulation in the SCS during the summer of 2000 with those during the summer of 1998, it is found that they agree qualitatively, but there is the some difference between them in quantity.This shows that the circulation in the SCS has obviously seasonal feature. (5) The dynamical mechanism which products the basic pattern of summer circulation is because the following two reasons: 1) the joint effect of the baroclinity and relief (JEBAR) is essential dynamical cause; and 2) it is next important dynamical cause that the interaction between the wind stress and bottom topography under the southerly monsoon. (6) Comparing the hydrographic structure and distribution of stream functions with the SSH data from TOPEX/ERS-2 analysis in the SCS during August of 2000, they agree qualitatively.展开更多
This paper presents a proper splitting iterative method for comparing the general restricted linear euqations Ax=b, x ∈T (where, b ∈AT, and T is an arbitrary but fixed subspace of C<sup>m</sup>) and th...This paper presents a proper splitting iterative method for comparing the general restricted linear euqations Ax=b, x ∈T (where, b ∈AT, and T is an arbitrary but fixed subspace of C<sup>m</sup>) and the generalized in A<sub>T,S</sub> For the special case when b ∈AT and dim(T)=dim(AT), this splitting iterative methverse A<sub>T,S</sub> hod converges to A<sub>T,S</sub>b (the unique solution of the general restricted system Ax=bx ∈T).展开更多
A novel method to fabricate composition- (IO) films using a positive sacrificial ZnO and topology-controlled ZnO/TiO2 inverse opals IO template has been developed. This method includes a two-step process, preparatio...A novel method to fabricate composition- (IO) films using a positive sacrificial ZnO and topology-controlled ZnO/TiO2 inverse opals IO template has been developed. This method includes a two-step process, preparation of ZnO IO by a simple electrochemical deposition using a self-assembly polystyrene colloidal crystal template and preparation of ZnO/TiO2 IO by a liquid phase deposition (LPD) process at room temperature. The composition and topology of ZnO/TiO2 IO can be easily controlled by changing the duration of the LPD. After 20 min LPD process, a ZnO/TiO2 composite IO with non-close-packed face-centered cubic air sphere array was obtained. Prolonging the duration to 60 min, a pure TiO2 IO (TIO-LPD60) with obviously thickened walls was formed. The formation mechanism for the compositional and topological variation was discussed. A preliminary study on UV photocatalytic property of the samples for degradation of methylene blue reveals that the composition and topology significantly influenced the photocatalytic activity of the IO film. The ZnO/TiO2 composite IO demonstrates a higher degree of activity than both pure ZnO and pure TiO2 IO, although they have a similar IO wall thickness. Moreover, with increasing IO wall thickness from -52 nm to -90 nm, TIO-LPD60 exhibits the highest level of photocatalytic performance.展开更多
An inverse spinel-type metal oxide, magnesium-manganese-titanium oxide (Mg2Mn0.5Ti0.5O4), were prepared using the coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material ...An inverse spinel-type metal oxide, magnesium-manganese-titanium oxide (Mg2Mn0.5Ti0.5O4), were prepared using the coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigated by X-ray, saturation capacity of exchange, pH titration, and distribution coefficient (Kd) measurement. The acid treatments of Mg2Mn0.5Ti0.5O4 caused Mg^2+ extractions of more than 81%, whereas the dissolutions of Mn^4+ and Ti^4+ were less than 10%. The experimental results proved that the acid-treated sample has a capacity of exchange 56 mg·g^-1 for Li^+ in the solution. The chemical analysis showed that the Li^+ extraction/insertion progressed mainly by ion-exchange mechanism and surface adsorption.展开更多
Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the r...Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the relatively low detectivity of the lead-free halide perovskites which seriously restrain its commercialization.Here,we developed a solution inverse temperature crystal growth(ITCG)method to bring-up high quality Cs_(3)Cu_(2)I_(5)crystals with large size of centimeter order,in which the oleic acid(OA)is introduced as an antioxidative ligand to inhibit the oxidation of cuprous ions effieiently,as well as to decelerate the crystallization rate remarkalby.Based on these fine crystals,the vapor deposition technique is empolyed to prepare high quality Cs_(3)Cu_(2)I_(5)films for efficient X-ray imaging.Smooth surface morphology,high light yields and short decay time endow the Cs_(3)Cu_(2)I_(5)films with strong radioluminescence,high resolution(12 lp/mm),low detection limits(53 nGyair/s)and desirable stability.Subsequently,the Cs_(3)Cu_(2)I_(5)films have been applied to the practical radiography which exhibit superior X-ray imaging performance.Our work provides a paradigm to fabricate nonpoisonous and chemically stable inorganic halide perovskite for X-ray imaging.展开更多
This study presents a novel two-step approach to assess plate-like structural laminar damages,particularly for delamination damage detection of composite structures.Firstly,a 2-D continuous wavelet transform is employ...This study presents a novel two-step approach to assess plate-like structural laminar damages,particularly for delamination damage detection of composite structures.Firstly,a 2-D continuous wavelet transform is employed to identify the damage location and sizes from vibration curvature data.An inverse method is subsequently then used to determine the bending stiffness reduction ratio along a specified direction,enabling the quantification of the delamination severity.The method employed in this study is an extension of the one-dimensional inverse method developed in a previous work of the authors.The applicability of the two-step inverse approach is demonstrated in a simulation analysis and by an experimental study on a cantilever composite plate containing a single delamination.The inverse method is shown to have the capacity to reveal the detailed damage information of delamination within a constrained searching space and can be used to determine the effective flexural stiffness of composite plate structures,even in cases of complex delamination damage.展开更多
Let X be the limit of an inverse system {Xα, παβ, ∧} and and let λ be the cardinal number of A. Assume that each projection πα : X → Xα is an open and onto map and X is A-paracompact. We prove that if each ...Let X be the limit of an inverse system {Xα, παβ, ∧} and and let λ be the cardinal number of A. Assume that each projection πα : X → Xα is an open and onto map and X is A-paracompact. We prove that if each Xα is B(LF, ω^2)-refinable (hereditarily B(LF, ω^2)- refinable), then X is B(LF, ω^2)-refinable (hereditarily B(LF,ω ^2)-refinable). Furthermore, we show that B(LF, ω^2)-refinable spaces can be preserved inversely undcr closed maps.展开更多
In this paper,we prove that if X is an almost convex and 2-strictly convex space,linear operator T:X→Y is bounded,N(T)is an approximative compact Chebyshev subspace of X and R(T)is a 3-Chebyshev hyperplane,then there...In this paper,we prove that if X is an almost convex and 2-strictly convex space,linear operator T:X→Y is bounded,N(T)is an approximative compact Chebyshev subspace of X and R(T)is a 3-Chebyshev hyperplane,then there exists a homogeneous selection T^(σ)of T^(■)such that continuous points of T^(σ)and T^(■)are dense on Y.展开更多
Chitosan (CS) was successfully modified in supercritical carbon dioxide ( scCOz ) by grafting method to enhance its water solubility. In this work, a three.arm star-like fluorinated polymer was synthesized by atom...Chitosan (CS) was successfully modified in supercritical carbon dioxide ( scCOz ) by grafting method to enhance its water solubility. In this work, a three.arm star-like fluorinated polymer was synthesized by atom transfer radical polymerization ( ATRP ) method and applied as a surfactant in supereriticul carbon dioxide (scCO2 ). Then 2-acrylamido-2-methyl propane sulfonie acid (AMPS) was grafted onto CS (CS-g-PAMPS) in H2O/scCO2 inverse emulsion. The effects of mass ratio of water and surfactants (Rw/s ) and pressure of scCO2 on the grafting reaction were investigated. The grafting rate, partide size, and dispersity in water of CS-g-PAMPS varied greatly as Rw/s and pressure of scCO2 changed. It could be found that the value of Rw/s at 12 and the pressure of scCO2 at 30 MPa were the optimum conditions for the grafting reaction. CS-g-PAMPS prepared in this reaction system has higher grafting rate, smaller particle sizes, and better dispersity in water than those prepared via conventional methods.展开更多
For the 2-D wave inverse problems introduced from geophysical exploration, in this paper, the author presents integration-characteristic method to solve the velocity parameter, and then applies it to common shotpoint ...For the 2-D wave inverse problems introduced from geophysical exploration, in this paper, the author presents integration-characteristic method to solve the velocity parameter, and then applies it to common shotpoint model data, in noise-free case. The accuracy is quite good.展开更多
In this paper, the authors introduce and study the concept of (1, 2)^*-generalized closed sets with respect to an ideal in a bitopological space. Also, some characterizations and applications of(1, 2)^*-generali...In this paper, the authors introduce and study the concept of (1, 2)^*-generalized closed sets with respect to an ideal in a bitopological space. Also, some characterizations and applications of(1, 2)^*-generalized closed sets are given.展开更多
Recently, semiconductor quantum dot (QD) sensitized solar cells (QDSSCs) are expected to achieve higher conversion efficiency because of the large light absorption coefficient and multiple exciton generation in QDs. T...Recently, semiconductor quantum dot (QD) sensitized solar cells (QDSSCs) are expected to achieve higher conversion efficiency because of the large light absorption coefficient and multiple exciton generation in QDs. The morphology of TiO2 electrode is one of the most important factors in QDSSCs. Inverse opal (IO) TiO2 electrode, which has periodic mesoporous structure, is useful for QDSSCs because of better penetration of electrolyte than conventional nanoparticulate TiO2 electrode. In addition, the ordered three dimensional structure of IO-TiO2 would be better for electron transport. We have found that open circuit voltage Voc of QDSSCs with IO-TiO2 electrodes was much higher (0.2 V) than that with nanoparticulate TiO2 electrodes. But short circuit current density Jsc was lower in the case of IO-TiO2 electrodes because of the smaller surface area of IO-TiO2. In this study, for increasing surface area of IO-TiO2, we applied TiCl4 post treatment on IO-TiO2 and investigated the effect of the post treatment on photovoltaic properties of CdSe QD sensitized IO-TiO2 solar cells. It was found that Jsc could be enhanced due to TiCl4 post treatment, but decreased again for more than one cycle treatment, which indicates excess post treatment may lead to worse penetration of electrolyte. Our results indicate that the appropriate post treatment can improve the energy conversion efficiency of the QDSSCs.展开更多
The 2D data processing adopted by the high-density resistivity method regards the geological structures as two degrees, which makes the results of the 2D data inversion only an approximate interpretation;the accuracy ...The 2D data processing adopted by the high-density resistivity method regards the geological structures as two degrees, which makes the results of the 2D data inversion only an approximate interpretation;the accuracy and effect can not meet the precise requirement of the inversion. Two typical models of the geological bodies were designed, and forward calculation was carried out using finite element method. The forward-modeled profiles were obtained. 1% Gaussian random error was added in the forward models and then 2D and 3D inversions using a high-density resistivity method were undertaken to realistically simulate field data and analyze the sensitivity of the 2D and 3D inversion algorithms to noise. Contrast between the 2D and 3D inversion results of least squares inversion shows that two inversion results of high-density resistivity method all can basically reflect the spatial position of an anomalous body. However, the 3D inversion can more effectively eliminate the influence of interference from Gaussian random error and better reflect the distribution of resistivity in the anomalous bodies. Overall, the 3D inversion was better than 2D inversion in terms of embodying anomalous body positions, morphology and resistivity properties.展开更多
In this work,a sponge-like polysulfonamide(PSA)/SiO_2 composite membrane is unprecedentedly prepared by the phase inversion method,and successfully demonstrated as a novel separator of lithium-ion batteries(LIBs).Comp...In this work,a sponge-like polysulfonamide(PSA)/SiO_2 composite membrane is unprecedentedly prepared by the phase inversion method,and successfully demonstrated as a novel separator of lithium-ion batteries(LIBs).Compared to the commercial polypropylene(PP) separator,the sponge-like PSA/SiO_2 composite possesses better physical and electrochemical properties,such as higher porosity,ionic conductivity,thermal stability and flame retarding ability.The LiCoO_2/Li half-cells using the sponge-like composite separator demonstrate superior rate capability and cyclability over those using the commercial PP separator.Moreover,the sponge-like composite separator can ensure the normal operation of LiCoO_2/Li half-cell at an extremely high temperature of 90 °C,while the commercial PP separator cannot.All these encouraging results suggest that this phase inversion based sponge-like PSA/SiO_2 composite separator is really a promising separator for high performance LIBs.展开更多
The diagnosis of the recurrent optic neuritis is commonly established clinically,and sometimes it could be challenging because the involved optic nerve does not always show significant enhancement on conventional cont...The diagnosis of the recurrent optic neuritis is commonly established clinically,and sometimes it could be challenging because the involved optic nerve does not always show significant enhancement on conventional contrast enhanced-T1 weighted imaging(CE-T1W1).In this paper,we reported a middle-aged female with early diagnosis of recurrent optic neuritis using contrast-enhanced T2 fluid-attenuated inversion recovery imaging(CET2FLAIR).The involved optic nerve presented evident enhancement on CE-T2FLAIR and no enhancement on CE-T1W1.This case suggested that the CE-T2FLAIR may be a useful diagnostic tool specifically for the recurrent optic neuritis in clinical practice.展开更多
2-D velocity structure and tectonics of the crust and upper mantle is revealed by inversion of seismic refraction and wide-angle reflection traveltimes acquired along the profile L1 in the Changbaishan-Tianchi volcani...2-D velocity structure and tectonics of the crust and upper mantle is revealed by inversion of seismic refraction and wide-angle reflection traveltimes acquired along the profile L1 in the Changbaishan-Tianchi volcanic region. It is used in this study that seismic traveltime inversion for simultaneous determination of 2-D velocity and interface structure of the crust and upper mantle. The result shows that, under Changbaishan-Tianchi crater, there exists a low-velocity body in the shape of an inverted triangle, and the crustal reflecting boundaries and Moho all become lower by a varying margin of 2-6 km, forming a crustal root which is assumed to be the Changbaishan-Tianchi volcanic system. Finally, we make a comparison between our 2-D velocity model and the result from the studies by using trial-and-error forward modeling with SEIS83.展开更多
基金the Major State Basic Research Program of China un der contract No.G1999043805.
文摘On the basis of hydrographic data obtained in August 2000 cruise, the circulation in the South China Sea (SCS) is computed by the modified inverse method in combination with SSH data from TOPEX/ERS-2 analysis. For study of the dynamical mechanism, which causes the pattern of summer circulation in the SCS, the diagnostic model (Yuan et al. 1982. Acta Oceanologica Sinica,4(1):1-11; Yuan and Su. 1992. Numerical Computation of Physical Oceanography.474-542) is used to simulate numerically the summer circulation in the SCS. The following results have been obtained. (1) The central and southwestern SCSs are dominated mainly by anticy-clonic circulation systems. They are mainly as follows. 1) There is strong anticyclonic eddy southeast of Vietnam (W1). Its horizontal scale is about 300 km, and it extends vertically from the surface to the about 1 000 m level. 2) There are a warm eddy W2 southeast of Zhongsha Islands and the anticyclonic circulation system W3 west off the Luzon Island. 3) There is a stronger cyclonic eddy C1 between the anticyclonic eddies W1 and W2.4) A strong northward coastal jet is present near the coast of Vietnam, and separates from the coast of Vietnam at about 12° N to the northeast.(2)The northern SCS is dominated mainly by a cyclonic circulation system. There is a cyclonic circulation system near and north of Section N2. (3) The southeastern SCS is dominated mainly by the cyclonic circulation system. (4) Comparing the results of circulation in the SCS during the summer of 2000 with those during the summer of 1998, it is found that they agree qualitatively, but there is the some difference between them in quantity.This shows that the circulation in the SCS has obviously seasonal feature. (5) The dynamical mechanism which products the basic pattern of summer circulation is because the following two reasons: 1) the joint effect of the baroclinity and relief (JEBAR) is essential dynamical cause; and 2) it is next important dynamical cause that the interaction between the wind stress and bottom topography under the southerly monsoon. (6) Comparing the hydrographic structure and distribution of stream functions with the SSH data from TOPEX/ERS-2 analysis in the SCS during August of 2000, they agree qualitatively.
基金This project is supported by Science and Technology Foundation of Shanghai Higher Eduction,Doctoral Program Foundation of Higher Education in China.National Nature Science Foundation of China and Youth Science Foundation of Universities in Shanghai.
文摘This paper presents a proper splitting iterative method for comparing the general restricted linear euqations Ax=b, x ∈T (where, b ∈AT, and T is an arbitrary but fixed subspace of C<sup>m</sup>) and the generalized in A<sub>T,S</sub> For the special case when b ∈AT and dim(T)=dim(AT), this splitting iterative methverse A<sub>T,S</sub> hod converges to A<sub>T,S</sub>b (the unique solution of the general restricted system Ax=bx ∈T).
基金Supported by National High Technology Research and Development Program of China (863 Program) (2007AA04Z239) and National Natural Science Foundation of China (60621001, 60975060)
文摘A novel method to fabricate composition- (IO) films using a positive sacrificial ZnO and topology-controlled ZnO/TiO2 inverse opals IO template has been developed. This method includes a two-step process, preparation of ZnO IO by a simple electrochemical deposition using a self-assembly polystyrene colloidal crystal template and preparation of ZnO/TiO2 IO by a liquid phase deposition (LPD) process at room temperature. The composition and topology of ZnO/TiO2 IO can be easily controlled by changing the duration of the LPD. After 20 min LPD process, a ZnO/TiO2 composite IO with non-close-packed face-centered cubic air sphere array was obtained. Prolonging the duration to 60 min, a pure TiO2 IO (TIO-LPD60) with obviously thickened walls was formed. The formation mechanism for the compositional and topological variation was discussed. A preliminary study on UV photocatalytic property of the samples for degradation of methylene blue reveals that the composition and topology significantly influenced the photocatalytic activity of the IO film. The ZnO/TiO2 composite IO demonstrates a higher degree of activity than both pure ZnO and pure TiO2 IO, although they have a similar IO wall thickness. Moreover, with increasing IO wall thickness from -52 nm to -90 nm, TIO-LPD60 exhibits the highest level of photocatalytic performance.
文摘An inverse spinel-type metal oxide, magnesium-manganese-titanium oxide (Mg2Mn0.5Ti0.5O4), were prepared using the coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigated by X-ray, saturation capacity of exchange, pH titration, and distribution coefficient (Kd) measurement. The acid treatments of Mg2Mn0.5Ti0.5O4 caused Mg^2+ extractions of more than 81%, whereas the dissolutions of Mn^4+ and Ti^4+ were less than 10%. The experimental results proved that the acid-treated sample has a capacity of exchange 56 mg·g^-1 for Li^+ in the solution. The chemical analysis showed that the Li^+ extraction/insertion progressed mainly by ion-exchange mechanism and surface adsorption.
基金the financially support of the National Natural Science Foundation of China(12164051)the Joint Foundation of Provincial Science and Technology Department-Double First-class Construction of Yunnan University(2019FY003016)+4 种基金the Young Top Talent Project of Yunnan Province(YNWR-QNBJ-2018-229)the financially support by Yunnan Major Scientific and Technological Projects(202202AG050016)Advanced Analysis and Measurement Center of Yunnan University for the sample characterization service and the Postgraduate Research and Innovation Foundation of Yunnan University(2021Y036)the financially support of the National Natural Science Foundation of China(62064013)the Application Basic Research Project of Yunnan Province[2019FB130]。
文摘Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the relatively low detectivity of the lead-free halide perovskites which seriously restrain its commercialization.Here,we developed a solution inverse temperature crystal growth(ITCG)method to bring-up high quality Cs_(3)Cu_(2)I_(5)crystals with large size of centimeter order,in which the oleic acid(OA)is introduced as an antioxidative ligand to inhibit the oxidation of cuprous ions effieiently,as well as to decelerate the crystallization rate remarkalby.Based on these fine crystals,the vapor deposition technique is empolyed to prepare high quality Cs_(3)Cu_(2)I_(5)films for efficient X-ray imaging.Smooth surface morphology,high light yields and short decay time endow the Cs_(3)Cu_(2)I_(5)films with strong radioluminescence,high resolution(12 lp/mm),low detection limits(53 nGyair/s)and desirable stability.Subsequently,the Cs_(3)Cu_(2)I_(5)films have been applied to the practical radiography which exhibit superior X-ray imaging performance.Our work provides a paradigm to fabricate nonpoisonous and chemically stable inorganic halide perovskite for X-ray imaging.
文摘This study presents a novel two-step approach to assess plate-like structural laminar damages,particularly for delamination damage detection of composite structures.Firstly,a 2-D continuous wavelet transform is employed to identify the damage location and sizes from vibration curvature data.An inverse method is subsequently then used to determine the bending stiffness reduction ratio along a specified direction,enabling the quantification of the delamination severity.The method employed in this study is an extension of the one-dimensional inverse method developed in a previous work of the authors.The applicability of the two-step inverse approach is demonstrated in a simulation analysis and by an experimental study on a cantilever composite plate containing a single delamination.The inverse method is shown to have the capacity to reveal the detailed damage information of delamination within a constrained searching space and can be used to determine the effective flexural stiffness of composite plate structures,even in cases of complex delamination damage.
基金Supported by the National Natural Science Foundation of China (10671173)
文摘Let X be the limit of an inverse system {Xα, παβ, ∧} and and let λ be the cardinal number of A. Assume that each projection πα : X → Xα is an open and onto map and X is A-paracompact. We prove that if each Xα is B(LF, ω^2)-refinable (hereditarily B(LF, ω^2)- refinable), then X is B(LF, ω^2)-refinable (hereditarily B(LF,ω ^2)-refinable). Furthermore, we show that B(LF, ω^2)-refinable spaces can be preserved inversely undcr closed maps.
基金supported by the“China Natural Science Fund under grant 11871181”the“China Natural Science Fund under grant 11561053”。
文摘In this paper,we prove that if X is an almost convex and 2-strictly convex space,linear operator T:X→Y is bounded,N(T)is an approximative compact Chebyshev subspace of X and R(T)is a 3-Chebyshev hyperplane,then there exists a homogeneous selection T^(σ)of T^(■)such that continuous points of T^(σ)and T^(■)are dense on Y.
基金National Natural Science Foundation of China(No.20674017)Shanghai Key Laboratory Project of China(No.08DZ2230500)
文摘Chitosan (CS) was successfully modified in supercritical carbon dioxide ( scCOz ) by grafting method to enhance its water solubility. In this work, a three.arm star-like fluorinated polymer was synthesized by atom transfer radical polymerization ( ATRP ) method and applied as a surfactant in supereriticul carbon dioxide (scCO2 ). Then 2-acrylamido-2-methyl propane sulfonie acid (AMPS) was grafted onto CS (CS-g-PAMPS) in H2O/scCO2 inverse emulsion. The effects of mass ratio of water and surfactants (Rw/s ) and pressure of scCO2 on the grafting reaction were investigated. The grafting rate, partide size, and dispersity in water of CS-g-PAMPS varied greatly as Rw/s and pressure of scCO2 changed. It could be found that the value of Rw/s at 12 and the pressure of scCO2 at 30 MPa were the optimum conditions for the grafting reaction. CS-g-PAMPS prepared in this reaction system has higher grafting rate, smaller particle sizes, and better dispersity in water than those prepared via conventional methods.
文摘For the 2-D wave inverse problems introduced from geophysical exploration, in this paper, the author presents integration-characteristic method to solve the velocity parameter, and then applies it to common shotpoint model data, in noise-free case. The accuracy is quite good.
文摘In this paper, the authors introduce and study the concept of (1, 2)^*-generalized closed sets with respect to an ideal in a bitopological space. Also, some characterizations and applications of(1, 2)^*-generalized closed sets are given.
文摘Recently, semiconductor quantum dot (QD) sensitized solar cells (QDSSCs) are expected to achieve higher conversion efficiency because of the large light absorption coefficient and multiple exciton generation in QDs. The morphology of TiO2 electrode is one of the most important factors in QDSSCs. Inverse opal (IO) TiO2 electrode, which has periodic mesoporous structure, is useful for QDSSCs because of better penetration of electrolyte than conventional nanoparticulate TiO2 electrode. In addition, the ordered three dimensional structure of IO-TiO2 would be better for electron transport. We have found that open circuit voltage Voc of QDSSCs with IO-TiO2 electrodes was much higher (0.2 V) than that with nanoparticulate TiO2 electrodes. But short circuit current density Jsc was lower in the case of IO-TiO2 electrodes because of the smaller surface area of IO-TiO2. In this study, for increasing surface area of IO-TiO2, we applied TiCl4 post treatment on IO-TiO2 and investigated the effect of the post treatment on photovoltaic properties of CdSe QD sensitized IO-TiO2 solar cells. It was found that Jsc could be enhanced due to TiCl4 post treatment, but decreased again for more than one cycle treatment, which indicates excess post treatment may lead to worse penetration of electrolyte. Our results indicate that the appropriate post treatment can improve the energy conversion efficiency of the QDSSCs.
基金Projects(41074085,41374118)supported by the National Natural Science Foundation of ChinaProject(20120162110015)supported by Doctoral Fund of Ministry of Education of ChinaProject(NCET-12-0551)supported by Program for New Century Excellent Talents in University,China
文摘The 2D data processing adopted by the high-density resistivity method regards the geological structures as two degrees, which makes the results of the 2D data inversion only an approximate interpretation;the accuracy and effect can not meet the precise requirement of the inversion. Two typical models of the geological bodies were designed, and forward calculation was carried out using finite element method. The forward-modeled profiles were obtained. 1% Gaussian random error was added in the forward models and then 2D and 3D inversions using a high-density resistivity method were undertaken to realistically simulate field data and analyze the sensitivity of the 2D and 3D inversion algorithms to noise. Contrast between the 2D and 3D inversion results of least squares inversion shows that two inversion results of high-density resistivity method all can basically reflect the spatial position of an anomalous body. However, the 3D inversion can more effectively eliminate the influence of interference from Gaussian random error and better reflect the distribution of resistivity in the anomalous bodies. Overall, the 3D inversion was better than 2D inversion in terms of embodying anomalous body positions, morphology and resistivity properties.
基金Supported by the funding from "135" Projects Fund of CAS-QIBEBT Director Innovation FoundationThink-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research+3 种基金Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technologythe Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105)National Natural Science Foundation of China(51502319)Shandong Provincial Natural Science Foundation(ZR2016BQ18)
文摘In this work,a sponge-like polysulfonamide(PSA)/SiO_2 composite membrane is unprecedentedly prepared by the phase inversion method,and successfully demonstrated as a novel separator of lithium-ion batteries(LIBs).Compared to the commercial polypropylene(PP) separator,the sponge-like PSA/SiO_2 composite possesses better physical and electrochemical properties,such as higher porosity,ionic conductivity,thermal stability and flame retarding ability.The LiCoO_2/Li half-cells using the sponge-like composite separator demonstrate superior rate capability and cyclability over those using the commercial PP separator.Moreover,the sponge-like composite separator can ensure the normal operation of LiCoO_2/Li half-cell at an extremely high temperature of 90 °C,while the commercial PP separator cannot.All these encouraging results suggest that this phase inversion based sponge-like PSA/SiO_2 composite separator is really a promising separator for high performance LIBs.
文摘The diagnosis of the recurrent optic neuritis is commonly established clinically,and sometimes it could be challenging because the involved optic nerve does not always show significant enhancement on conventional contrast enhanced-T1 weighted imaging(CE-T1W1).In this paper,we reported a middle-aged female with early diagnosis of recurrent optic neuritis using contrast-enhanced T2 fluid-attenuated inversion recovery imaging(CET2FLAIR).The involved optic nerve presented evident enhancement on CE-T2FLAIR and no enhancement on CE-T1W1.This case suggested that the CE-T2FLAIR may be a useful diagnostic tool specifically for the recurrent optic neuritis in clinical practice.
基金Key Project (95-11-02-01) from China Seismological Bureau.Contribution No. RCEG200129, Research Center of Exploration Geophysi
文摘2-D velocity structure and tectonics of the crust and upper mantle is revealed by inversion of seismic refraction and wide-angle reflection traveltimes acquired along the profile L1 in the Changbaishan-Tianchi volcanic region. It is used in this study that seismic traveltime inversion for simultaneous determination of 2-D velocity and interface structure of the crust and upper mantle. The result shows that, under Changbaishan-Tianchi crater, there exists a low-velocity body in the shape of an inverted triangle, and the crustal reflecting boundaries and Moho all become lower by a varying margin of 2-6 km, forming a crustal root which is assumed to be the Changbaishan-Tianchi volcanic system. Finally, we make a comparison between our 2-D velocity model and the result from the studies by using trial-and-error forward modeling with SEIS83.