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硅烷分子接枝ASZ陶瓷膜处理水中苯酚的研究 被引量:3
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作者 李丹 刘冰 +1 位作者 孙浩 姚杰 《水处理技术》 CAS CSCD 北大核心 2020年第2期25-28,32,共5页
为了提高陶瓷膜的疏水性,本研究选择硅烷分子对氧化铝支撑氧化锆(ASZ)陶瓷膜进行接枝改性。考察接枝硅烷分子结构(反应基团类型)、碳链长度、硅烷分子中含氟和十七氟癸基三乙氧基硅烷(F17C8OEt3)浓度对疏水性的影响。利用SEM-EDS、FTIR... 为了提高陶瓷膜的疏水性,本研究选择硅烷分子对氧化铝支撑氧化锆(ASZ)陶瓷膜进行接枝改性。考察接枝硅烷分子结构(反应基团类型)、碳链长度、硅烷分子中含氟和十七氟癸基三乙氧基硅烷(F17C8OEt3)浓度对疏水性的影响。利用SEM-EDS、FTIR、TGA和接触角测量仪对接枝改性ASZ膜或金属氧化物进行表征。研究结果表明,硅烷分子接枝ASZ膜的疏水性能显著提高,接触角从29°增加到136°。FT-IR、TGA结果证明了硅烷分子成功接枝在ASZ膜或金属氧化物上。利用F17C8OEt3硅烷分子接枝改性ASZ管式膜构建渗透蒸发系统处理水溶液中苯酚,实验结果表明,当进料液中苯酚浓度从672.3 mg/L增加至3 844.6 mg/L时,去除的苯酚浓度从29.1 mg/L增加到407.4mg/L;进料液的温度升高到80℃,去除的苯酚是进料液温度为40℃时的5倍。 展开更多
关键词 硅烷分子 asz陶瓷膜 疏水性 渗透蒸发 苯酚
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Ore Controls and Metallogenesis of Au-Ag Deposits at Atalla Mine,Central Eastern Desert of Egypt 被引量:1
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作者 Mohamed ABD EL MONSEF 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第5期1451-1470,共20页
Gold-silver deposits in the Atalla area occur as hydrothermal quartz veins in NE–SW pre-existing fractures within the Atalla granitic pluton.The orientation of such quartz veins has been attributed to extensional beh... Gold-silver deposits in the Atalla area occur as hydrothermal quartz veins in NE–SW pre-existing fractures within the Atalla granitic pluton.The orientation of such quartz veins has been attributed to extensional behavior related to the Atalla Shear Zone(ASZ).The Atalla area is covered by a variety of lithologies that are(from oldest to youngest):metasedimentary rocks,metavolcanic rocks,ophiolite assemblage(serpentinites/talc-carbonates),Atalla granite and Dokhan volcanic rocks.Microscopically,Atalla granite ranges in composition from granodiorite to monzogranite.Wholerock geochemistry constrains the calc-alkaine affinity of the Atalla granite that was intruded within an orogenic(syncollision)tectonic regime.The ore minerals are represented by gold/silver(electrum),pyrite(Py1&Py2),arsenopyrite,pyrrhotite,sphalerite,chalcopyrite,galena,covellite and goethite.The temperature of ore formation ranges from 240 to 285℃and the estimated fluid pressure is in the range of 20–100 MPa.Based on the geological setting,ore textures and fluid characteristics;the Atalla Au-Ag deposits are considered to be orogenic in nature,formed from a continental collision(~653-590 Ma),synchronous with the emplacement of calc-alkaline magmatism during the evolutionary history of the Arabian Nubian Shield(ANS).The initial ore-forming fluid was primarily derived from a metamorphic source related to ophiolitic-serpentinite rocks under deep regional conditions of greenschist-amphibolite facies,where the Atalla granitic eruption provided the required temperature conditions for the metamorphic process to take place.Under such conditions,the transportation of ore metals as bisulfide complexes is favoured.The deposition of ore minerals was triggered by fluidwallrock interaction through fracture pathways in conjunction with a temperature-pressure drop that is likely to have been related to uplift into the crustal levels. 展开更多
关键词 Gold-silver arsenopyrite geothermometry fluid inclusions orogenic deposits Atalla Shear Zone(asz)
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Influence of Y_2O_3 Adding Method on Microstructure and Properties of Al_2O_3 Strengthened Y-TZP
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作者 梁小平 杨正方 +1 位作者 袁启明 靳正国 《Journal of Rare Earths》 SCIE EI CAS CSCD 2003年第S1期120-123,共4页
The effects of Y_2O_3 adding methods (i.e.,co-precipitated and mixed) on the microstructure and properties of alumina-strengthened ytrria-stabilized tetragonal zirconia polycrystal (ASZ) were investigated. CYASZ and M... The effects of Y_2O_3 adding methods (i.e.,co-precipitated and mixed) on the microstructure and properties of alumina-strengthened ytrria-stabilized tetragonal zirconia polycrystal (ASZ) were investigated. CYASZ and MYASZ were made by different adding method of Y_2O_3,co-precipitated and mixed,respectively. The results show that CYASZ is of uniform microstructure with fine grain size,however,MYASZ is of inhomogeneous microstructure due to the inhomogeneous distribution of ytrria. Comparing with CYASZ,the density and the strength of MYASZ are decreased,but the toughness is changed only a little. Under sliding wear test,the wear resistance of CYASZ is better than that of MYASZ. 展开更多
关键词 alumina strengthened Y_2O_3 stabilized tetragonal zirconia polycrystal (asz) microstructure mechanical properties wear rare earths
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