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合金化元素Al和Cu的微量添加对铽晶界渗透的影响
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作者 韩卫平 周磊 +1 位作者 程星华 刘涛 《广东化工》 CAS 2022年第16期15-18,共4页
研究了(Al+Cu)质量分数为0.23%、0.3%、0.35%和0.55%时烧结钕铁硼Tb晶界扩散对磁性能、外观和微区成分的影响。随着(Al+Cu)含量的增加,大尺寸产品(宽度大于20 mm)表面的麻坑现象越来越严重,H提高的幅度越来越小。微观EDS分析发现,当(Al+... 研究了(Al+Cu)质量分数为0.23%、0.3%、0.35%和0.55%时烧结钕铁硼Tb晶界扩散对磁性能、外观和微区成分的影响。随着(Al+Cu)含量的增加,大尺寸产品(宽度大于20 mm)表面的麻坑现象越来越严重,H提高的幅度越来越小。微观EDS分析发现,当(Al+Cu)含量增加时,晶界扩散后晶界内Tb含量减少。(Al+Cu)形成的共晶化合物主要分布在晶界处,在高温扩散时,增加了扩散通道的液相浸润性,少量时有利于晶界扩散,而(Al+Cu)含量较高时,对于Tb置换出来的Nd形成的新的富钕相的延展具有阻碍作用,不利于渗透;这种液相的富足也是导致外观不良主要诱因。 展开更多
关键词 晶界扩散 烧结钕铁硼 矫顽力 (al+cu)含量 Tb含量
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Effects of zinc content on strength and wear performance of Al-12Si-3Cu based alloy 被引量:3
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作者 Yasin ALEMDAG Murat BEDER 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第12期2463-2471,共9页
The effects of Zn content on strength and wear performance of Al-12Si-3 Cu alloy synthesized by gravity casting were systematically investigated.The microstructure and mechanical properties of the alloys were evaluate... The effects of Zn content on strength and wear performance of Al-12Si-3 Cu alloy synthesized by gravity casting were systematically investigated.The microstructure and mechanical properties of the alloys were evaluated using OM,XRD,SEM as well as hardness,tension,compression and Charpy impact tests.Their dry sliding wear tests were carried out with a ball-on-disk tester.Microscopic examinations revealed that the microstructure of the base alloy consisted of theα(Al)dendrites,needle-type and coarse Si particles,and CuAl2(θ)phase.The addition of Zn to this alloy resulted in the formation ofα-solid solution phase and the increase of coarse Si particles.The hardness,yield,tensile and compressive strengths,elongation to fracture and impact toughness of the Al-12Si-3 Cu-Zn alloys increased with increasing Zn content,but tendency in the tensile and compressive strengths and ductility reversed after adding 1.5%-2%Zn.In addition,the friction coefficient and volume loss of the Al-12Si-3 Cu-Zn alloys decreased with increasing Zn content.The study showed that the addition of Zn to Al-12Si-3 Cu alloy can improve its potential applications as tribological material. 展开更多
关键词 al-Si-cu alloy Zn content MICROSTRUCTURE mechanical properties wear performance
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Influence of Cu content on microstructure and mechanical properties of thixoformed Al-Si-Cu-Mg alloys 被引量:7
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作者 M.S.SALLEH M.Z.OMAR 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第11期3523-3538,共16页
The effects of Cu content on the microstructure and mechanical properties of thixoformed Al-6Si-xCu-0.3Mg(x= 3,4,5and 6,mass fraction,%) alloys were studied.The samples were thixoformed at 50%liquid content and severa... The effects of Cu content on the microstructure and mechanical properties of thixoformed Al-6Si-xCu-0.3Mg(x= 3,4,5and 6,mass fraction,%) alloys were studied.The samples were thixoformed at 50%liquid content and several of the samples were treated with the T6 heat treatment.The samples were then examined by optical microscopy(OM),scanning electron microscopy(SEM),energy dispersive X-ray(EDX) spectroscopy and X-ray diffraction(XRD) analysis,as well as hardness and tensile tests.The results show that the cooling slope casting and thixoforming process promote the formation of very fine and well distributed intermetallic compounds in the aluminium matrix and the mechanical properties of the alloys increase considerably compared with the permanent mould casting.The results also reveal that as the Cu content in the alloy increases,the hardness and tensile strength of the thixoformed alloys also increase.The ultimate tensile strength,yield strength and elongation to fracture of the thixoformed heat-treated Al-6Si-3Cu-0.3Mg alloy are 298 MPa,201 MPa and 4.5%,respectively,whereas the values of the thixoformed heat-treated alloy with high Cu content(6%) are 361 MPa,274 MPa and 1.1%,respectively.The fracture of the thixoformed Al-6Si-3Cu-0.3Mg alloy shows a dimple rupture,whereas in the alloy that contains the highest Cu content(6%),a cleavage fracture is observed. 展开更多
关键词 al-Si-cu-Mg alloy cu content THIXOFORMING T6 heat treatment mechanical properties
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Influence of Mg addition and T6 heat treatment on microstructure,mechanical and tribological properties of Al-12Si-3Cu based alloy 被引量:2
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作者 M.BEDER Y.ALEMDAG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第8期2208-2219,共12页
The aim of the present study was to investigate the influence of Mg addition and T6 heat treatment on microstructure,mechanical and tribological properties of the Al-Si-Cu-Mg alloys.In this context,a series of Al-12Si... The aim of the present study was to investigate the influence of Mg addition and T6 heat treatment on microstructure,mechanical and tribological properties of the Al-Si-Cu-Mg alloys.In this context,a series of Al-12Si-3Cu-(0.5-2.5)Mg(wt.%)alloys were produced by permanent mould casting,and then subjected to T6 treatment.Their microstructure and mechanical properties were investigated using OM,XRD,SEM,EDS along with hardness,tension,compression and Charpy impact tests.Dry sliding friction and wear properties of the alloys were studied using a ball-on-disk type tester.It was observed that the microstructure of as-cast Al-12Si-3 Cu-Mg alloys consisted of a(Al),Si,O-CuAb,0-Mg_(2)Si,0-AbMg_(8)Cu(2)Si_(6) and π-AhMg_(3)FeSi_(6) phases.T6 heat treatment gave rise to nearly spherodization of eutectic Si particles,formation of finer 0-CuAH and 0-Mg_(2)Si precipitates and elimination of Chinese script morphology of 0-Mg_(2)Si phase.The addition of Mg up to 2.5 wt.%decreased the hardness,tensile and compressive strengths,tensile elongation and impact toughness of the as-cast and T6-treated alloys and increased their friction coefficient and volume loss.T6 treatment,on the other hand,led to a significant increase in mechanical properties and wear resistance of as-cast alloys. 展开更多
关键词 al-Si-cu alloys Mg content T6 treatment MICROSTRUCTURE mechanical properties wear properties fracture surface
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Influence of minor Sc additions on grain refinement and microstructure characteristics of a high Zn-containing Al-Zn-Mg-Cu-Zr alloy 被引量:3
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作者 WEN Kai LI Xi-wu +5 位作者 XIONG Bai-qing LIU Hong-lei WANG Ying-jun LI Zhi-hui ZHANG Yong-an LI Ya-nan 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第3期780-794,共15页
In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cas... In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cast microstructure characteristics including grains and phases were thoroughly investigated. The results indicated that fine grain boundaries existed in these alloys and fine MgZn2phases discontinuously distributed on them. Besides,AlZnMgCu eutectic phases and Sc, Zr-containing phases with flocculent morphology were observed. As scandium contents vary from 0.06 wt.% to 0.17 wt.%, the average grain size continuously decreased and its equiaxial characteristics were strengthened. Meanwhile, the content of AlZnMgCu eutectic phase showed a decrease trend. When scandium contents were 0.20 wt.% and 0.25 wt.%, no further enhancement on grain refinement was observed, so as to the reduction of AlZnMgCu eutectic phase content. Besides, Sc, Zr-containing phases with blocky morphology were observed and the alloy with a scandium content of 0.25 wt.% possessed a larger amount of blocky Sc, Zr-containing phase than the alloy with a scandium content of 0.20 wt.%. Grain refinement and reduction of AlZnMgCu eutectic phase content associated with scandium addition were discussed. 展开更多
关键词 al-Zn-Mg-cu-Zr alloy high zinc content microstructure Sc addition grain refinement phase evolution
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烧结钕铁硼中(Al+Cu)含量对晶界扩散的影响 被引量:4
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作者 刘涛 张昕 +5 位作者 李建 陈杰 程星华 周磊 喻晓军 李波 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2021年第10期3765-3770,共6页
对(Al+Cu)质量分数分别为0.25%和0.5%的钕铁硼基体分别进行Dy晶界扩散,并分析了其矫顽力、Dy含量分布和微观结构。通过比较2种磁体的成分、性能发现,在Dy增加量基本相同的情况下,高(Al+Cu)磁体扩散后的矫顽力提高量相较于低(Al+Cu)磁体... 对(Al+Cu)质量分数分别为0.25%和0.5%的钕铁硼基体分别进行Dy晶界扩散,并分析了其矫顽力、Dy含量分布和微观结构。通过比较2种磁体的成分、性能发现,在Dy增加量基本相同的情况下,高(Al+Cu)磁体扩散后的矫顽力提高量相较于低(Al+Cu)磁体高37~44 kA/m。进一步进行成分和矫顽力的梯度分析发现,基体的(Al+Cu)含量变化并没有改变扩散后磁体内部Dy元素随扩散深度的浓度分布,但是矫顽力梯度分析结果显示,高(Al+Cu)样品的各片层矫顽力提升量均比低(Al+Cu)样品各片层高40~80 kA/m。后续的EPMA的Dy面分布图显示,高(Al+Cu)基体扩散后Dy在晶界处富集条纹更清晰、连续,而TEM的EDS分析结果也显示,高(Al+Cu)样品中晶界附近Dy含量更高。(Al+Cu)含量的提高,使得晶界相的流动性增强,Dy更加连续包裹主相晶粒,使得在整体Dy增加量相同的情况下进一步提升矫顽力。 展开更多
关键词 烧结钕铁硼 晶界扩散 矫顽力 Dy含量 (al+cu)含量
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