A novel coordination polymer, [Fe(C 5H 4NCOO) 2] n, was synthesized by hydrothermal reaction and characterized by elemental analysis as well as IR spectroscopy. The crystal structure (with a novel 3-D network) of this...A novel coordination polymer, [Fe(C 5H 4NCOO) 2] n, was synthesized by hydrothermal reaction and characterized by elemental analysis as well as IR spectroscopy. The crystal structure (with a novel 3-D network) of this compound belongs to monoclinic, space group P2 1/n, a=0.49544(1) nm, b=1.32443(2) nm, c=1.04983(1) nm, β=101.586(1)°. The diffuse reflectance spectra (200～2500 nm) showed that the polymer had strong absorbance in 375～563 nm (E g≈2.5 eV) region and weak absorbance from 720 to 2500 nm (near infrared spectra).展开更多
以1,3-二氯六甲基三硅烷相继与环戊二烯基钠、正丁基锂和四氯化钛作用合成了1,1′-(六甲基三硅撑)双环戊二烯基二氯化钛(1),1在氨基钠的存在下与对氯苯酚作用制得题目化合物(2).通过元素分析、~1H NMR 和 MS 鉴定了1与2的结构,并对2进行...以1,3-二氯六甲基三硅烷相继与环戊二烯基钠、正丁基锂和四氯化钛作用合成了1,1′-(六甲基三硅撑)双环戊二烯基二氯化钛(1),1在氨基钠的存在下与对氯苯酚作用制得题目化合物(2).通过元素分析、~1H NMR 和 MS 鉴定了1与2的结构,并对2进行 X 射线结构分析确证了其结构.2的晶体属单斜晶系的 P2_1/c 空间群.晶胞参数:a=1.0746(3),b=2.4865(7),c=1.2568(2)nm;β=113.42(2)°;V=3.08137nm^3;Z=4,D_σ(?)=1.305g·cm^(-3).化合物中三个硅原子的桥链发生明显扭曲.通过氧原子中心原子钛与苯环发生共轭,使整个分子形成共轭体系.展开更多
文摘A novel coordination polymer, [Fe(C 5H 4NCOO) 2] n, was synthesized by hydrothermal reaction and characterized by elemental analysis as well as IR spectroscopy. The crystal structure (with a novel 3-D network) of this compound belongs to monoclinic, space group P2 1/n, a=0.49544(1) nm, b=1.32443(2) nm, c=1.04983(1) nm, β=101.586(1)°. The diffuse reflectance spectra (200～2500 nm) showed that the polymer had strong absorbance in 375～563 nm (E g≈2.5 eV) region and weak absorbance from 720 to 2500 nm (near infrared spectra).
文摘以1,3-二氯六甲基三硅烷相继与环戊二烯基钠、正丁基锂和四氯化钛作用合成了1,1′-(六甲基三硅撑)双环戊二烯基二氯化钛(1),1在氨基钠的存在下与对氯苯酚作用制得题目化合物(2).通过元素分析、~1H NMR 和 MS 鉴定了1与2的结构,并对2进行 X 射线结构分析确证了其结构.2的晶体属单斜晶系的 P2_1/c 空间群.晶胞参数:a=1.0746(3),b=2.4865(7),c=1.2568(2)nm;β=113.42(2)°;V=3.08137nm^3;Z=4,D_σ(?)=1.305g·cm^(-3).化合物中三个硅原子的桥链发生明显扭曲.通过氧原子中心原子钛与苯环发生共轭,使整个分子形成共轭体系.
