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螺[3,2′]吡咯烷氧化吲哚的化学拆分
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作者 黄志诚 邹滢 +2 位作者 宋祥家 田芳 王立新 《合成化学》 CAS 2023年第8期636-640,共5页
对螺[3,2′]吡咯烷氧化吲哚及其衍生物的化学拆分进行了研究,通过对手性拆分试剂种类,手性拆分试剂用量以及结晶溶剂进行优化,最终以二对甲苯酰基-L-酒石酸[(-)-DDTA]为拆分剂并以43%收率,94%ee实现了1-苄基螺[3,2′]吡咯烷氧化吲哚拆... 对螺[3,2′]吡咯烷氧化吲哚及其衍生物的化学拆分进行了研究,通过对手性拆分试剂种类,手性拆分试剂用量以及结晶溶剂进行优化,最终以二对甲苯酰基-L-酒石酸[(-)-DDTA]为拆分剂并以43%收率,94%ee实现了1-苄基螺[3,2′]吡咯烷氧化吲哚拆分。该拆分方法为获得这类螺环手性的候选生理活性物质提供了新的方法。 展开更多
关键词 螺环 氧化吲哚 手性 化学拆分 (-)-ddta
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Improving performance by creating a native join-index for OLAP 被引量:3
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作者 Yansong ZHANG Shan WANG Jiaheng LU 《Frontiers of Computer Science》 SCIE EI CSCD 2011年第2期236-249,共14页
The performance of online analytical processing (OLAP) is critical for meeting the increasing requirements of massive volume analytical applications. Typical techniques, such as in-memory processing, column-storage,... The performance of online analytical processing (OLAP) is critical for meeting the increasing requirements of massive volume analytical applications. Typical techniques, such as in-memory processing, column-storage, and join indexes focus on high perfor- mance storage media, efficient storage models, and reduced query processing. While they effectively perform OLAP applications, there is a vital limitation: main- memory database based OLAP (MMOLAP) cannot provide high performance for a large size data set. In this paper, we propose a novel memory dimension table model, in which the primary keys of the dimension table can be directly mapped to dimensional tuple addresses. To achieve higher performance of dimensional tuple access, we optimize our storage model for dimension tables based on OLAP query workload features. We present directly dimensional tuple accessing (DDTA) based join (DDTA- JOIN), a technique to optimize query processing on the memory dimension table by direct dimensional tuple access. We also contribute by proposing an optimization of the predicate tree to shorten predicate operation length by pruning useless predicate processing. Our experimental results show that the DDTA-JOIN algorithm is superior to both simulated row-store main memory query processing and the open-source column-store main memory database MonetDB, thanks to the reduced join cost and simple yet efficient query processing. 展开更多
关键词 directly dimensional tuple accessing (ddta) ddta JOIN native join index predicate tree
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