This paper presents the derivation of an analytical model for a multi-queue nodes network router, which is referred to as the multi-queue nodes （mQN） model. In this model, expressions are derived to calculate two pe...This paper presents the derivation of an analytical model for a multi-queue nodes network router, which is referred to as the multi-queue nodes （mQN） model. In this model, expressions are derived to calculate two performance metrics, namely, the queue node and system utilization factors. In order to demonstrate the flexibility and effectiveness of the mQN model in analyzing the performance of an mQN network router, two scenarios are performed. These scenarios investigated the variation of queue nodes and system utilization factors against queue nodes dropping probability for various system sizes and packets arrival routing probabilities. The performed scenarios demonstrated that the mQN analytical model is more flexible and effective when compared with experimental tests and computer simulations in assessing the performance of an mQN network router.展开更多
The semiempirical AMI method, ah initio (HF/3-21G, 6-31G, 6-31G(d), 6-31+G(d)) and DFT (B3LYP/6-31G(d), 6-31+G(d)) methods were used to optimize the geometry of DDQ and its anion radical DDQ-. Nelsen’s model was used...The semiempirical AMI method, ah initio (HF/3-21G, 6-31G, 6-31G(d), 6-31+G(d)) and DFT (B3LYP/6-31G(d), 6-31+G(d)) methods were used to optimize the geometry of DDQ and its anion radical DDQ-. Nelsen’s model was used to calculate the internal reorganization energy λi of self-exchange electron transfer (ET) reactions. The calculated λi results of DDQ/DDQ-. by AM1 and B3LYP/ 6-31G(d), 6-31+G(d) methods are close to each other and consistent with the reported values; while those from Har-tree-Fock methods are too large because of not consideringthe effect of electron correlation. The structure and ET behavior of MQ0 /MQ0- couple were studied by AM1 and DFT (B3LYP/6-31G(d), 6-31+ G(d, p)) methods, and those of MQ0 /MQn-(n=1-7) were studied by AM1 method for the first time. The results indicate that the values of the heat of formation of MQn increases with the increasing of the length of the isoamylene substituent chains. It also shows that the length of substituent has little effect on the bond lengths,展开更多
文摘This paper presents the derivation of an analytical model for a multi-queue nodes network router, which is referred to as the multi-queue nodes （mQN） model. In this model, expressions are derived to calculate two performance metrics, namely, the queue node and system utilization factors. In order to demonstrate the flexibility and effectiveness of the mQN model in analyzing the performance of an mQN network router, two scenarios are performed. These scenarios investigated the variation of queue nodes and system utilization factors against queue nodes dropping probability for various system sizes and packets arrival routing probabilities. The performed scenarios demonstrated that the mQN analytical model is more flexible and effective when compared with experimental tests and computer simulations in assessing the performance of an mQN network router.
基金This work was supportedby the National Natural Science Foundation of China (Grant Nos. 29733100 and 39890390) and the State Key Basic Research and Development Plan (Grant No. G1998010100).
文摘The semiempirical AMI method, ah initio (HF/3-21G, 6-31G, 6-31G(d), 6-31+G(d)) and DFT (B3LYP/6-31G(d), 6-31+G(d)) methods were used to optimize the geometry of DDQ and its anion radical DDQ-. Nelsen’s model was used to calculate the internal reorganization energy λi of self-exchange electron transfer (ET) reactions. The calculated λi results of DDQ/DDQ-. by AM1 and B3LYP/ 6-31G(d), 6-31+G(d) methods are close to each other and consistent with the reported values; while those from Har-tree-Fock methods are too large because of not consideringthe effect of electron correlation. The structure and ET behavior of MQ0 /MQ0- couple were studied by AM1 and DFT (B3LYP/6-31G(d), 6-31+ G(d, p)) methods, and those of MQ0 /MQn-(n=1-7) were studied by AM1 method for the first time. The results indicate that the values of the heat of formation of MQn increases with the increasing of the length of the isoamylene substituent chains. It also shows that the length of substituent has little effect on the bond lengths,
