Cation exchange capacity (CEC) is one of the most important properties of soils. The NH<sub>4</sub>OAc (pH = 7.0) exchange method is usually recommended to determine CEC (CEC<sub>1</sub>) of al...Cation exchange capacity (CEC) is one of the most important properties of soils. The NH<sub>4</sub>OAc (pH = 7.0) exchange method is usually recommended to determine CEC (CEC<sub>1</sub>) of all soils with different pH values, particularly for studies on soil taxonomy. But comparatively the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is more authentic in determining CEC (CEC<sub>2</sub>) of tropical and subtropical highly-weathered acid soils. But so far little is known about the difference between CEC<sub>1</sub> and CEC<sub>2</sub>. In this study, the physiochemical data of 114 acid B horizon soils from 112 soil series of tropical and subtropical China were used, CEC<sub>1</sub> and CEC<sub>2</sub> were determined and compared, the influencing factors were analyzed for the difference between CEC<sub>1</sub> and CEC<sub>2</sub>, and then a regression model was established between CEC<sub>1</sub> and CEC<sub>2</sub>. The results showed that CEC<sub>2</sub> was significantly lower than CEC<sub>1</sub> (p < 0.01), CEC<sub>2</sub> was 14.76% - 63.31% with a mean of 36.32% of CEC<sub>1</sub>. In view of the contribution to CEC from other properties, CEC<sub>2</sub> was mainly determined by pH (45.92%), followed by silt (21.05%), free Fe<sub>2</sub>O<sub>3</sub> (17.35%) and clay contents (12.76%), CEC<sub>1</sub> was mainly decided by free Fe<sub>2</sub>O<sub>3</sub> content (40.38%), followed by pH (28.39%) and silt content (27.29%;and the difference between CEC<sub>1</sub> and CEC<sub>2</sub> was mainly affected by free Fe<sub>2</sub>O<sub>3</sub> (50.92%), followed by silt content (26.46%) and pH (21.80%). The acceptable optimal regression model between CEC<sub>2</sub> and CEC<sub>1</sub> was established as CEC<sub>2</sub> = 2.3114 × CEC<sub>1</sub><sup>1.1496</sup> (R<sup>2</sup> = 0.410, P < 0.001, RMSE = 0.15). For the studies on soil taxonomy, the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is recommended in determining CEC of the highly-weathered acid soils in the tropical and subtropical regions.展开更多
Homogeneous and dispersed Y3 Al5 O12（yttrium aluminum garnet,YAG） nanopowders were synthesized via a homogeneous co-precipitation method from the mixed solutions of yttrium nitrate,aluminum nitrate and a small amoun...Homogeneous and dispersed Y3 Al5 O12（yttrium aluminum garnet,YAG） nanopowders were synthesized via a homogeneous co-precipitation method from the mixed solutions of yttrium nitrate,aluminum nitrate and a small amount of ammonium sulfate using hot urea as the precipitant.The method has the superiorities that co-precipitation of cations is ensured and continuous decomposition of the hot urea is achieved to obtain the narrow size distribution particles.The addition of small amount of ammonium sulfate surfactant,although has no influence on YAG garnet phase formation,has significant effect on dispersion,particles distribution and sinterability of the resultant YAG and Yb：YAG powders.Compared with the undoped sample,the green body of Yb：YAG doped with ammonium sulfate has higher total shrinkage,linear shrinkage rate and relative density through sintering at 1600 ℃.The resultant Yb：YAG powders can be sintered into transparent ceramics at 1700 ℃ through vacuum sintering.The influence of the sulfate ions on characteristics of the resultant powders was thoroughly studied.展开更多
文摘Cation exchange capacity (CEC) is one of the most important properties of soils. The NH<sub>4</sub>OAc (pH = 7.0) exchange method is usually recommended to determine CEC (CEC<sub>1</sub>) of all soils with different pH values, particularly for studies on soil taxonomy. But comparatively the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is more authentic in determining CEC (CEC<sub>2</sub>) of tropical and subtropical highly-weathered acid soils. But so far little is known about the difference between CEC<sub>1</sub> and CEC<sub>2</sub>. In this study, the physiochemical data of 114 acid B horizon soils from 112 soil series of tropical and subtropical China were used, CEC<sub>1</sub> and CEC<sub>2</sub> were determined and compared, the influencing factors were analyzed for the difference between CEC<sub>1</sub> and CEC<sub>2</sub>, and then a regression model was established between CEC<sub>1</sub> and CEC<sub>2</sub>. The results showed that CEC<sub>2</sub> was significantly lower than CEC<sub>1</sub> (p < 0.01), CEC<sub>2</sub> was 14.76% - 63.31% with a mean of 36.32% of CEC<sub>1</sub>. In view of the contribution to CEC from other properties, CEC<sub>2</sub> was mainly determined by pH (45.92%), followed by silt (21.05%), free Fe<sub>2</sub>O<sub>3</sub> (17.35%) and clay contents (12.76%), CEC<sub>1</sub> was mainly decided by free Fe<sub>2</sub>O<sub>3</sub> content (40.38%), followed by pH (28.39%) and silt content (27.29%;and the difference between CEC<sub>1</sub> and CEC<sub>2</sub> was mainly affected by free Fe<sub>2</sub>O<sub>3</sub> (50.92%), followed by silt content (26.46%) and pH (21.80%). The acceptable optimal regression model between CEC<sub>2</sub> and CEC<sub>1</sub> was established as CEC<sub>2</sub> = 2.3114 × CEC<sub>1</sub><sup>1.1496</sup> (R<sup>2</sup> = 0.410, P < 0.001, RMSE = 0.15). For the studies on soil taxonomy, the BaCl<sub>2</sub>-MgSO<sub>4</sub> forced-exchange method is recommended in determining CEC of the highly-weathered acid soils in the tropical and subtropical regions.
基金National Natural Science Foundation of China(51602042,51602045)the Fundamental Research Funds for the Central Universities(N162304004,N162304013)+1 种基金the Natural Science Foundation of Hebei Province(E2017501082)the Scientific Research Foundation of Northeastern University at Qinhuangdao(XNB201715)
文摘Homogeneous and dispersed Y3 Al5 O12（yttrium aluminum garnet,YAG） nanopowders were synthesized via a homogeneous co-precipitation method from the mixed solutions of yttrium nitrate,aluminum nitrate and a small amount of ammonium sulfate using hot urea as the precipitant.The method has the superiorities that co-precipitation of cations is ensured and continuous decomposition of the hot urea is achieved to obtain the narrow size distribution particles.The addition of small amount of ammonium sulfate surfactant,although has no influence on YAG garnet phase formation,has significant effect on dispersion,particles distribution and sinterability of the resultant YAG and Yb：YAG powders.Compared with the undoped sample,the green body of Yb：YAG doped with ammonium sulfate has higher total shrinkage,linear shrinkage rate and relative density through sintering at 1600 ℃.The resultant Yb：YAG powders can be sintered into transparent ceramics at 1700 ℃ through vacuum sintering.The influence of the sulfate ions on characteristics of the resultant powders was thoroughly studied.
