美国国家公园体系(National Park System,NPS)发展引领了世界自然保护地建设,也形成了较为完善的国家公园科学。遴选150多年来与NPS相关的10954篇科学论文,运用TF⁃IDF与LDA两种文本算法,分析国家公园科学的总体构成与发展趋势。主要结...美国国家公园体系(National Park System,NPS)发展引领了世界自然保护地建设,也形成了较为完善的国家公园科学。遴选150多年来与NPS相关的10954篇科学论文,运用TF⁃IDF与LDA两种文本算法,分析国家公园科学的总体构成与发展趋势。主要结果发现:①NPS公园科学形成了“四梁八柱”的总体框架,“四梁”是植物、动物、自然环境、人类行为4种主要关注对象,“八柱”为公共管理、地质与土壤等8个关键研究领域。②18个代表性特征词的研究热度演变表明公园科学存在明显分层,并具有整体上升、过程各异的特点。高热度区间是土地等永恒话题,中热度区间是生物等基础研究和气候变化等新兴领域,低热度区间多为火等偶现性研究。③公园科学与NPS发展过程密切相关:体制初创期围绕自然资源普查以及体制建立的驱动因素;体系完善期聚焦于国家公园制度和基础设施;时事导向期围绕着大萧条、二战等重大事件;多学科融合期呈现出以生态学为基础的多元发展。认识NPS公园科学对于中国国家公园体系建设和科学研究具有非常重要的借鉴意义。展开更多
Effects of factors such as slope, surface soil textuie, fertilization andcrop cover with different rainfall intensities on phosphorus (P) losses in farmland runoff of theDianchi Lake Watershed in Yunnan Province of Ch...Effects of factors such as slope, surface soil textuie, fertilization andcrop cover with different rainfall intensities on phosphorus (P) losses in farmland runoff of theDianchi Lake Watershed in Yunnan Province of China were studied through a rainfall simulation testusing a red soil, one of the most widely distributed soils of the study area. Results showed thatthe runoff concentrations of total phosphorus (TP) and P losses differed with the slope, beinghighest when the slope was 18 deg. At twodifferent rainfall intensities, the runoff TP and P losseshad a similar decreasing trend as the surface soil texture became coarser, therefore applying thegrit would decrease P in runofi from soils of farmland on slopes with heavier textures. With wheatas a crop cover the runoff TP concentrations and P losses were significantly lower than those of thebare soil. This showed that plant cover would greatly decrease P in runoff from the farmland of thestudy area. The TP concentration in runoff from the soil two days after fertilization doubled whencompared with that from the non-fertilized soil, indicating that fertilization could mean a dramaticrise in P runoff if irrigation or heavy rainfall occurred immediately after application and that nofertilization before a rain and no irrigation immediately after fertilization would reduce runoff Ploss from the farmland of the study area.展开更多
Nanotechnology has revolutionized cancer drug delivery,and recent research continues to focus on the development of“one-size-fits-all,”i.e.,“all-in-one”delivery nanovehicles.Although nanomedicines can address sign...Nanotechnology has revolutionized cancer drug delivery,and recent research continues to focus on the development of“one-size-fits-all,”i.e.,“all-in-one”delivery nanovehicles.Although nanomedicines can address significant shortcomings of conventional therapy,biological barriers remain a challenge in their delivery and accumulation at diseased sites.To achieve long circulation time,immune evasion,and targeted accumulation,conventional nanocarriers need modifications,e.g.,PEGylation,peptide/aptamer attachment,etc.One such modification is a biomimetic coating using cell membrane(CM),which can offer long circulation or targeting,or both.This top-down CM coating process is facile and can provide some advantageous features over surface modification by synthetic polymers.Herein,an overview is provided on the engineering of CM camouflaged polymer nanoparticles.A short section on CM and the development of CM coating technology has been provided.Detailed description of the preparation and characterization of CM camouflaged polymer NPs and their applications in cancer treatment has been reported.A brief comparison between CM coating and PEGylation has been highlighted.Various targeting approaches to achieve tumor-specific delivery of CM coated NPs have been summarized here.Overall,this review will give the readers a nice picture of CM coated polymer NPs,along with their opportunities and challenges.展开更多
Elemental state matter-heteroatom-doped carbon composites are of great importance for the development of anode in lithium ion batteries(LIBs).In this article,metal–organic frameworks(MOFs)are adopted as precursor to ...Elemental state matter-heteroatom-doped carbon composites are of great importance for the development of anode in lithium ion batteries(LIBs).In this article,metal–organic frameworks(MOFs)are adopted as precursor to prepare Co composites via metallurgical pyrolysis under controllable conditions.The obtained nitrogen-doped porous carbon-Co nanocomposite possesses core–shell structure(Co@C–N).Co@C–N exhibits the best Li storage performances as anode active matter.After the 200th cycles at current density of 0.2 A g^(-1),a reversible capacity of 870 mAh g^(-1)is retained.A reversible capacity of 275 mAh g^(-1)still maintains with 5 A g^(-1).Co@C–N presents a high reversible capacity with excellent cycle stability.Considering the corresponding experimental and theoretical results,the Co0-based N-doped porous carbon composite is proposed to work as LIBs anode matter.These results provide a new design idea for electrode matters of metallic ion battery,and demonstrate that MOFs pyrolysis is an effective method for the construction of elemental state anode materials.展开更多
Ultraviolet(UV)radiation can cause degradation or aging of many polymers and shorten the working-life of their products.Thus,UV protective covers are required in various occasions.Textiles with the UV-shielding functi...Ultraviolet(UV)radiation can cause degradation or aging of many polymers and shorten the working-life of their products.Thus,UV protective covers are required in various occasions.Textiles with the UV-shielding function possess unique properties compared with those covers in board or film shapes.TiO_2 nanoparticles(NPs),which were reported to have superior UV blocking function,can be used to produce UV protective covers in combination with fabric.However,efficient and environmentally friendly immobilization of TiO_2 Nps onto the fabrics is challenging.Polydopamine(PDA),a biomimetic synthetic polymer,has attracted great attentions recently due to its superior affinity to various materials and facile application procedure.Hence,in this research,the surface of nylon fabrics was modified by PDA to immobilizeTiO_2 NPs.Themodificationconditionswere systematically optimized.The immobilization of the NPs was confirmed by Fourier transform infrared spectrometer(FTIR)and scanning electron microscope(SEM).The functionalized nylon fabrics were proved to exhibit improved UV protection properties even after washing.This work provides a new and versatile surface modification technique for textiles.展开更多
文摘美国国家公园体系(National Park System,NPS)发展引领了世界自然保护地建设,也形成了较为完善的国家公园科学。遴选150多年来与NPS相关的10954篇科学论文,运用TF⁃IDF与LDA两种文本算法,分析国家公园科学的总体构成与发展趋势。主要结果发现:①NPS公园科学形成了“四梁八柱”的总体框架,“四梁”是植物、动物、自然环境、人类行为4种主要关注对象,“八柱”为公共管理、地质与土壤等8个关键研究领域。②18个代表性特征词的研究热度演变表明公园科学存在明显分层,并具有整体上升、过程各异的特点。高热度区间是土地等永恒话题,中热度区间是生物等基础研究和气候变化等新兴领域,低热度区间多为火等偶现性研究。③公园科学与NPS发展过程密切相关:体制初创期围绕自然资源普查以及体制建立的驱动因素;体系完善期聚焦于国家公园制度和基础设施;时事导向期围绕着大萧条、二战等重大事件;多学科融合期呈现出以生态学为基础的多元发展。认识NPS公园科学对于中国国家公园体系建设和科学研究具有非常重要的借鉴意义。
基金Project supported by the Applied and Basic Research Foundation of Yunnan Province (No. 1999C0011G).
文摘Effects of factors such as slope, surface soil textuie, fertilization andcrop cover with different rainfall intensities on phosphorus (P) losses in farmland runoff of theDianchi Lake Watershed in Yunnan Province of China were studied through a rainfall simulation testusing a red soil, one of the most widely distributed soils of the study area. Results showed thatthe runoff concentrations of total phosphorus (TP) and P losses differed with the slope, beinghighest when the slope was 18 deg. At twodifferent rainfall intensities, the runoff TP and P losseshad a similar decreasing trend as the surface soil texture became coarser, therefore applying thegrit would decrease P in runofi from soils of farmland on slopes with heavier textures. With wheatas a crop cover the runoff TP concentrations and P losses were significantly lower than those of thebare soil. This showed that plant cover would greatly decrease P in runoff from the farmland of thestudy area. The TP concentration in runoff from the soil two days after fertilization doubled whencompared with that from the non-fertilized soil, indicating that fertilization could mean a dramaticrise in P runoff if irrigation or heavy rainfall occurred immediately after application and that nofertilization before a rain and no irrigation immediately after fertilization would reduce runoff Ploss from the farmland of the study area.
文摘Nanotechnology has revolutionized cancer drug delivery,and recent research continues to focus on the development of“one-size-fits-all,”i.e.,“all-in-one”delivery nanovehicles.Although nanomedicines can address significant shortcomings of conventional therapy,biological barriers remain a challenge in their delivery and accumulation at diseased sites.To achieve long circulation time,immune evasion,and targeted accumulation,conventional nanocarriers need modifications,e.g.,PEGylation,peptide/aptamer attachment,etc.One such modification is a biomimetic coating using cell membrane(CM),which can offer long circulation or targeting,or both.This top-down CM coating process is facile and can provide some advantageous features over surface modification by synthetic polymers.Herein,an overview is provided on the engineering of CM camouflaged polymer nanoparticles.A short section on CM and the development of CM coating technology has been provided.Detailed description of the preparation and characterization of CM camouflaged polymer NPs and their applications in cancer treatment has been reported.A brief comparison between CM coating and PEGylation has been highlighted.Various targeting approaches to achieve tumor-specific delivery of CM coated NPs have been summarized here.Overall,this review will give the readers a nice picture of CM coated polymer NPs,along with their opportunities and challenges.
基金the National Natural Science Foundation of China(Nos.31530010 and 21401168)the Special Project of Guangdong Province to Introduce Innovation and Entrepreneurship Team(No.2016ZT06N467)is acknowledged.
文摘Elemental state matter-heteroatom-doped carbon composites are of great importance for the development of anode in lithium ion batteries(LIBs).In this article,metal–organic frameworks(MOFs)are adopted as precursor to prepare Co composites via metallurgical pyrolysis under controllable conditions.The obtained nitrogen-doped porous carbon-Co nanocomposite possesses core–shell structure(Co@C–N).Co@C–N exhibits the best Li storage performances as anode active matter.After the 200th cycles at current density of 0.2 A g^(-1),a reversible capacity of 870 mAh g^(-1)is retained.A reversible capacity of 275 mAh g^(-1)still maintains with 5 A g^(-1).Co@C–N presents a high reversible capacity with excellent cycle stability.Considering the corresponding experimental and theoretical results,the Co0-based N-doped porous carbon composite is proposed to work as LIBs anode matter.These results provide a new design idea for electrode matters of metallic ion battery,and demonstrate that MOFs pyrolysis is an effective method for the construction of elemental state anode materials.
基金National Natural Science Foundation of China(No.51503031)Pujiang Project from Shanghai Science and Technology Committee,China(No.15PJ1400300)+1 种基金Scientific Research Foundation for the Returned Overseas Scholars from the Ministry of Education,China(No.15B10127)Fundamental Research Funds for the Central Universities,China(No.2232015D3-02)
文摘Ultraviolet(UV)radiation can cause degradation or aging of many polymers and shorten the working-life of their products.Thus,UV protective covers are required in various occasions.Textiles with the UV-shielding function possess unique properties compared with those covers in board or film shapes.TiO_2 nanoparticles(NPs),which were reported to have superior UV blocking function,can be used to produce UV protective covers in combination with fabric.However,efficient and environmentally friendly immobilization of TiO_2 Nps onto the fabrics is challenging.Polydopamine(PDA),a biomimetic synthetic polymer,has attracted great attentions recently due to its superior affinity to various materials and facile application procedure.Hence,in this research,the surface of nylon fabrics was modified by PDA to immobilizeTiO_2 NPs.Themodificationconditionswere systematically optimized.The immobilization of the NPs was confirmed by Fourier transform infrared spectrometer(FTIR)and scanning electron microscope(SEM).The functionalized nylon fabrics were proved to exhibit improved UV protection properties even after washing.This work provides a new and versatile surface modification technique for textiles.
