With the development of mid-infrared (MIR) photoelectric devices, mid-infrared spectroscopy has become one of the important methods for non-invasive detection of blood glucose. The mid-infrared region (4000 - 400 cm&l...With the development of mid-infrared (MIR) photoelectric devices, mid-infrared spectroscopy has become one of the important methods for non-invasive detection of blood glucose. The mid-infrared region (4000 - 400 cm<sup>-1</sup>) has the well-known fingerprint region (1200 - 800 cm<sup>-1</sup>) of glucose, which has clearer characteristic absorption peaks and better specificity. There is a lot of molecular information about glucose in the MIR. The non-invasive detection of blood glucose by mid-infrared spectroscopy needs to achieve certain accuracy, and the quantitative model is an important factor affecting the accuracy of glucose detection. In this paper, the samples of imitation solution containing only glucose and the samples of imitation mixed solution are taken as the research objects, and the mid-infrared spectral data of the samples are collected. The full spectrum partial least squares Regression (PLSR) model, SNV + Ctr-PLSR model, MSC + Ctr-PLSR model, and convolutional neural networks (CNN) model of 3000 - 900 cm<sup>-1</sup> band were constructed. Full spectrum PLS model and CNN model of 1200 - 900 cm<sup>-1</sup> band were constructed. The experimental results show that the optimal model of the two bands is CNN, then the correlation coefficient of prediction set (Rp) of 3000 - 900 cm<sup>-1</sup> band is 0.95, and the root mean square error of pre-diction set (RMSEP) value is 22.10. The Rp of 1200 - 900 cm<sup>-1</sup> band is 0.95, and the RMSEP value is 22.54. The research results show that CNN is a promising method, which has higher accuracy than PLSR, and is especially suitable for modeling human complex environment. In addition, the study provides a theoretical and practical basis for CNN in feature selection and model interpretation.展开更多
为研究常规化学成分对市售卷烟感官品质特征的影响,采用偏最小二乘回归法(partial least square regression,PLSR)分析常规化学指标总糖、还原糖、烟碱、总氮等与卷烟感官品质的相关性。结果表明:总糖、还原糖、糖碱比与舒适感所有指标...为研究常规化学成分对市售卷烟感官品质特征的影响,采用偏最小二乘回归法(partial least square regression,PLSR)分析常规化学指标总糖、还原糖、烟碱、总氮等与卷烟感官品质的相关性。结果表明:总糖、还原糖、糖碱比与舒适感所有指标呈正相关;烟碱、总氮、钾与卷烟的舒适感特性呈负相关;钾氯比与口腔刺激/舌部灼烧和口腔残留/干燥感呈显著正相关。在卷烟的烟气特性中,总糖、还原糖、糖碱比与大部分烟气特性指标呈正相关;烟碱与丰富性呈显著负相关,与劲头呈显著正相关;钾氯比与杂气呈显著正相关。展开更多
针对污水处理过程出水总磷预测问题存在的强非线性、大时变等特征,提出了一种基于偏最小二乘回归自适应深度信念网络(partial least square regression adaptive deep belief network,PLSR-ADBN)的出水总磷预测方法。PLSR-ADBN是基于深...针对污水处理过程出水总磷预测问题存在的强非线性、大时变等特征,提出了一种基于偏最小二乘回归自适应深度信念网络(partial least square regression adaptive deep belief network,PLSR-ADBN)的出水总磷预测方法。PLSR-ADBN是基于深度学习模型DBN的一种改进型建模方法。首先,将自适应学习率引入到DBN的无监督预训练(pre-training)阶段,来提高网络收敛速度。其次,利用PLSR方法取代传统DBN中基于梯度的逐层权值精调(fine-tuning)方法,来提高网络预测精度。同时,通过构造李雅普诺夫函数证明了PLSR-ADBN学习过程的收敛性。最后,将PLSR-ADBN用于实际污水处理过程出水总磷预测中。实验结果表明所提出的PLSR-ADBN收敛速度快且预测精度高,能够满足实际污水处理过程对出水总磷监测精度和运行效率的要求。展开更多
文摘With the development of mid-infrared (MIR) photoelectric devices, mid-infrared spectroscopy has become one of the important methods for non-invasive detection of blood glucose. The mid-infrared region (4000 - 400 cm<sup>-1</sup>) has the well-known fingerprint region (1200 - 800 cm<sup>-1</sup>) of glucose, which has clearer characteristic absorption peaks and better specificity. There is a lot of molecular information about glucose in the MIR. The non-invasive detection of blood glucose by mid-infrared spectroscopy needs to achieve certain accuracy, and the quantitative model is an important factor affecting the accuracy of glucose detection. In this paper, the samples of imitation solution containing only glucose and the samples of imitation mixed solution are taken as the research objects, and the mid-infrared spectral data of the samples are collected. The full spectrum partial least squares Regression (PLSR) model, SNV + Ctr-PLSR model, MSC + Ctr-PLSR model, and convolutional neural networks (CNN) model of 3000 - 900 cm<sup>-1</sup> band were constructed. Full spectrum PLS model and CNN model of 1200 - 900 cm<sup>-1</sup> band were constructed. The experimental results show that the optimal model of the two bands is CNN, then the correlation coefficient of prediction set (Rp) of 3000 - 900 cm<sup>-1</sup> band is 0.95, and the root mean square error of pre-diction set (RMSEP) value is 22.10. The Rp of 1200 - 900 cm<sup>-1</sup> band is 0.95, and the RMSEP value is 22.54. The research results show that CNN is a promising method, which has higher accuracy than PLSR, and is especially suitable for modeling human complex environment. In addition, the study provides a theoretical and practical basis for CNN in feature selection and model interpretation.
文摘为研究常规化学成分对市售卷烟感官品质特征的影响,采用偏最小二乘回归法(partial least square regression,PLSR)分析常规化学指标总糖、还原糖、烟碱、总氮等与卷烟感官品质的相关性。结果表明:总糖、还原糖、糖碱比与舒适感所有指标呈正相关;烟碱、总氮、钾与卷烟的舒适感特性呈负相关;钾氯比与口腔刺激/舌部灼烧和口腔残留/干燥感呈显著正相关。在卷烟的烟气特性中,总糖、还原糖、糖碱比与大部分烟气特性指标呈正相关;烟碱与丰富性呈显著负相关,与劲头呈显著正相关;钾氯比与杂气呈显著正相关。
文摘针对污水处理过程出水总磷预测问题存在的强非线性、大时变等特征,提出了一种基于偏最小二乘回归自适应深度信念网络(partial least square regression adaptive deep belief network,PLSR-ADBN)的出水总磷预测方法。PLSR-ADBN是基于深度学习模型DBN的一种改进型建模方法。首先,将自适应学习率引入到DBN的无监督预训练(pre-training)阶段,来提高网络收敛速度。其次,利用PLSR方法取代传统DBN中基于梯度的逐层权值精调(fine-tuning)方法,来提高网络预测精度。同时,通过构造李雅普诺夫函数证明了PLSR-ADBN学习过程的收敛性。最后,将PLSR-ADBN用于实际污水处理过程出水总磷预测中。实验结果表明所提出的PLSR-ADBN收敛速度快且预测精度高,能够满足实际污水处理过程对出水总磷监测精度和运行效率的要求。
