配电网参数受天气条件和负载条件等因素影响会发生变化。由于传感装置安装有限、数据延时传输等因素,无法实时获得配电网准确参数,进而给传统故障定位方法的精度带来影响。针对以上问题,通过建立配电网数字孪生模型,基于配电网数字孪生...配电网参数受天气条件和负载条件等因素影响会发生变化。由于传感装置安装有限、数据延时传输等因素,无法实时获得配电网准确参数,进而给传统故障定位方法的精度带来影响。针对以上问题,通过建立配电网数字孪生模型,基于配电网数字孪生模型的参数自修正技术,提出了一种定位模型随参数变化动态校正的配电网故障定位方法。同时,搭建了基于数字孪生服务器和实时数字仿真系统(real time digital system, RTDS)的数字孪生平台,实现了配电网实时的物理模型和数字孪生模型的同步运行。在算例仿真中,利用该数字孪生平台,验证了基于数字孪生技术的配电网故障定法方法。结果表明,该方法可在各类系统运行条件下实时修正配电网参数,显著提高配电网故障定位的速度和精度。展开更多
采用新型化学酶法——开环易位聚合反应(ROMP)与酶促开环聚合反应(eROP)联用合成嵌段聚合物PCL-b-PB-b-PCL,用核磁共振氢谱(1 H NMR)、凝胶渗透色谱(GPC)和差示扫描量热法(DSC)表征产物的结构并进行性能测试.结果表明:GPC数据向高分子...采用新型化学酶法——开环易位聚合反应(ROMP)与酶促开环聚合反应(eROP)联用合成嵌段聚合物PCL-b-PB-b-PCL,用核磁共振氢谱(1 H NMR)、凝胶渗透色谱(GPC)和差示扫描量热法(DSC)表征产物的结构并进行性能测试.结果表明:GPC数据向高分子量移动,即成功合成了嵌段聚合物;嵌段聚合物可完全水解,且GPC数据向低分子量移动,表明该方法可行、有效.展开更多
In order to realize a metal containing nano-structure, a block-copolymer containing alkynyl groups in one block was designed and synthesized by living ring opening metathesis polymerization (ROMP) technique. The newly...In order to realize a metal containing nano-structure, a block-copolymer containing alkynyl groups in one block was designed and synthesized by living ring opening metathesis polymerization (ROMP) technique. The newly developed bis-3-bromopyridine complex of Grubbs catalyst was employed in the series of polymerization and it yielded the desired polymers with great molecular weight control and narrow polydispersities. The characteristics of the block copolymers were investigated by gel permeation chromatography, H- and 13H- NMR spectroscopy. Complexation of the alkynyl group containing block copolymers by treatment with dicobalt octacarbonyl occurred smoothly in 5 min at room temperature. GPC analysis before and after cobalt complexation indicated a significant increase of the hydrodynamic volume. AFM images of the films before and after the complexation also showed a noticeable change in its morphology where grain sizes become smaller and more regular upon complexation.展开更多
文摘配电网参数受天气条件和负载条件等因素影响会发生变化。由于传感装置安装有限、数据延时传输等因素,无法实时获得配电网准确参数,进而给传统故障定位方法的精度带来影响。针对以上问题,通过建立配电网数字孪生模型,基于配电网数字孪生模型的参数自修正技术,提出了一种定位模型随参数变化动态校正的配电网故障定位方法。同时,搭建了基于数字孪生服务器和实时数字仿真系统(real time digital system, RTDS)的数字孪生平台,实现了配电网实时的物理模型和数字孪生模型的同步运行。在算例仿真中,利用该数字孪生平台,验证了基于数字孪生技术的配电网故障定法方法。结果表明,该方法可在各类系统运行条件下实时修正配电网参数,显著提高配电网故障定位的速度和精度。
文摘采用新型化学酶法——开环易位聚合反应(ROMP)与酶促开环聚合反应(eROP)联用合成嵌段聚合物PCL-b-PB-b-PCL,用核磁共振氢谱(1 H NMR)、凝胶渗透色谱(GPC)和差示扫描量热法(DSC)表征产物的结构并进行性能测试.结果表明:GPC数据向高分子量移动,即成功合成了嵌段聚合物;嵌段聚合物可完全水解,且GPC数据向低分子量移动,表明该方法可行、有效.
文摘In order to realize a metal containing nano-structure, a block-copolymer containing alkynyl groups in one block was designed and synthesized by living ring opening metathesis polymerization (ROMP) technique. The newly developed bis-3-bromopyridine complex of Grubbs catalyst was employed in the series of polymerization and it yielded the desired polymers with great molecular weight control and narrow polydispersities. The characteristics of the block copolymers were investigated by gel permeation chromatography, H- and 13H- NMR spectroscopy. Complexation of the alkynyl group containing block copolymers by treatment with dicobalt octacarbonyl occurred smoothly in 5 min at room temperature. GPC analysis before and after cobalt complexation indicated a significant increase of the hydrodynamic volume. AFM images of the films before and after the complexation also showed a noticeable change in its morphology where grain sizes become smaller and more regular upon complexation.
