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Ce^(3+)/Eu^(2+)共掺Ca_3Si_2O_4N_2荧光粉的光学特性 被引量:2
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作者 陈鸿 李晨霞 +1 位作者 华有杰 徐时清 《发光学报》 EI CAS CSCD 北大核心 2013年第10期1324-1327,共4页
采用高温固相法制备了一种新型的白光LED用Ca3Si2O4N2∶Eu2+,Ce3+,K+荧光粉。利用X射线衍射仪对样品的物相结构进行了分析,结果表明:Ce3+和K+离子的掺杂没有改变Ca3Si2O4N2∶Eu2+荧光粉的主晶相。利用荧光光谱仪对样品的发光性能进行了... 采用高温固相法制备了一种新型的白光LED用Ca3Si2O4N2∶Eu2+,Ce3+,K+荧光粉。利用X射线衍射仪对样品的物相结构进行了分析,结果表明:Ce3+和K+离子的掺杂没有改变Ca3Si2O4N2∶Eu2+荧光粉的主晶相。利用荧光光谱仪对样品的发光性能进行了测试,发现样品在355 nm激发下得到的发射光谱为峰值位于505 nm的单峰,是Eu2+离子5d-4f电子跃迁引起的。Ca3Si2O4N2∶Eu2+荧光粉通过Ce3+和K+离子的掺杂,发光明显增强。当Ce3+的摩尔分数为1%时,荧光粉的发光强度达到最大值,是单掺Eu2+离子荧光粉发光强度的168%。通过光谱重叠的方法计算Ce3+→Eu2+能量传递临界的距离为2.535 nm。 展开更多
关键词 Ca3Si2O4N2∶Eu2+ ce3+ 荧光粉 能量转移
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Effect of sintering temperature on luminescence properties of borosilicate matrix blue–green emitting color conversion glass ceramics 被引量:1
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作者 Qiao-Yu Zheng Yang Li +3 位作者 Wen-Juan Wu Ming-Ming Shi Bo-Bo Yang Jun Zou 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第10期550-555,共6页
The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence propert... The color conversion glass ceramics which were made of borosilicate matrix co-doped(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors were prepared by two-step method in co-sintering. The change in luminescence properties and the drift of chromaticity coordinates(CIE) of the(SrBaSm)Si2O2N2:(Eu^3+Ce^3+) blue-green phosphors and the color conversion glass ceramics were studied in the sintering temperature range from 600℃ to 800℃. The luminous intensity and internal quantum yield(QY) of the blue-green phosphors and glass ceramics decreased with the sintering temperature increasing. When the sintering temperature increased beyond 750℃, the phosphors and the color conversion glass ceramics almost had no peak in photoluminescence(PL) and excitation(PLE) spectra. The results showed that the blue-green phosphors had poor thermal stability at higher temperature. The lattice structure of the phosphors was destroyed by the glass matrix and the Ce^3+ in the phosphors was oxidized to Ce^4+, which further caused a decrease in luminescent properties of the color conversion glass ceramics. 展开更多
关键词 (srbasm)si2o2n2:(Eu^3+Ce^3+) phosphors blue-green color conversion glass ceramic luminescent intensity thermal quenching effects sintering temperature
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CaAl2Si2O8∶Eu荧光粉发光性能及自还原现象的研究
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作者 靳天雨 崔瑞瑞 +1 位作者 张弛 邓朝勇 《人工晶体学报》 EI CAS CSCD 北大核心 2018年第8期1637-1641,1646,共6页
采用高温固相法制备了Ca(1-x)Al2Si2O8∶x Eu2+(x=0.005,0.02,0.04,0.06,0.08,0.10,0.20)和加入过量SiO_2的Ca Al2Si2O8∶0.04Eu,x SiO_2(x=0,0.05,0.100,0.200,0.300)。利用X射线衍射(XRD)对样品的晶体结构进行了表征,利用荧光光谱仪... 采用高温固相法制备了Ca(1-x)Al2Si2O8∶x Eu2+(x=0.005,0.02,0.04,0.06,0.08,0.10,0.20)和加入过量SiO_2的Ca Al2Si2O8∶0.04Eu,x SiO_2(x=0,0.05,0.100,0.200,0.300)。利用X射线衍射(XRD)对样品的晶体结构进行了表征,利用荧光光谱仪对样品的发光性能进行了分析。XRD结果表明,所生成的Ca Al2Si2O8∶0.04Eu,x SiO_2样品除了因反应未完全的氧化铝杂质相外基本是纯相。Ca(1-x)Al2Si2O8∶x Eu2+样品的激发和发射光谱表明,随着掺杂浓度的增加会出现红移现象。当Eu2+的掺杂浓度为超过4mol%时,出现浓度猝灭。当在空气气氛下烧结时,样品出现现了自还原现象。当过量SiO_2的加入,Eu2+的发光强度会逐渐减弱,而Eu3+的发光强度会逐渐增强,SiO_2的过量添加可以抑制自还原现象的产生。 展开更多
关键词 CaAl2Si2O8∶Eu2+/3+荧光粉 高温固相法 自还原 SIO2
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Synthesis of a Novel Bluish-Green Emitting Oxynitride Ca<sub>3</sub>Al<sub>8</sub>Si<sub>4</sub>O<sub>17</sub>N<sub>4</sub>:Eu<sup>2+</sup>Phosphor in a CaAl<sub>4-x</sub>Si<sub>x</sub>O<sub>7-x</sub>N<sub>x</sub>Solid Solution System
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作者 Jihae Kim Hideki Kato +2 位作者 Makoto Kobayashi Yasushi Sato Masato Kakihana 《Optics and Photonics Journal》 2013年第6期29-33,共5页
Synthesis of oxynitride solid solutions CaAl4-xSixO7-xNx:Eu2+ (x = 0 - 4) was attempted by the solid state reaction (SSR) methods using Si3N4 and AlN as nitrogen sources. The Ca3Al8Si4O17N4 (x = 4/3) sample with the h... Synthesis of oxynitride solid solutions CaAl4-xSixO7-xNx:Eu2+ (x = 0 - 4) was attempted by the solid state reaction (SSR) methods using Si3N4 and AlN as nitrogen sources. The Ca3Al8Si4O17N4 (x = 4/3) sample with the high phase purity was obtained when AlN was used as a nitrogen source whereas the sample synthesized using Si3N4 as another nitrogen source contained a Ca2Al2SiO7 impurity. Thus, it was revealed that AlN was a preferable nitrogen source for the synthesis of Ca3Al8Si4O17N4 by the SSR method. The solid solutions around x = 4/3 activated with Eu2+ exhibited bluish-green luminescence with emission maxima at 480 nm by the excitation at 250 - 450 nm. Thus, the CaAl4-xSixO7-xNx: Eu2+ solid solutions especially for Ca3Al8Si4O17N4:Eu2+ (x = 4/3) were developed as novel 展开更多
关键词 OXYNITRIDE PHOSPHOR Eu2+ Activator Ca3Al8Si4O17N4:Eu2+ Solid Solution
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Effects of Eu3+ and Dy3+ doping or co-doping on optical and structural properties of BaB2Si2O8 phosphor for white LED applications 被引量:4
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作者 廖侹乔 刘宏 +4 位作者 R. HUSSIN Z. IBRAHIM K. DERAMAN H.O. LINTANG W.N.W SHAMSURI 《Journal of Rare Earths》 SCIE EI CAS CSCD 2016年第1期21-29,共9页
A series of Eu3+ and Dy3+ doped/co-doped as well as un-doped BaB2Si2Os phosphors were synthesized via solid state reaction method. The PL result showed typical blue and green emission from Dy3+ and red emission fro... A series of Eu3+ and Dy3+ doped/co-doped as well as un-doped BaB2Si2Os phosphors were synthesized via solid state reaction method. The PL result showed typical blue and green emission from Dy3+ and red emission from Eu3+. The f-f transitions in- volving the lanthanide ions along with dopant site occupancy were discussed thoroughly. Phonon assisted energy transfer process was observed from Eu3+ to Dy3+, which enhanced the emissions of Dy3+. Combinations of the emissions from Eu3+ and Dy3+ showed a possible white to red tuneable emission on the CIE diagram. The white warmth emissions of the phosphor were revealed to be ad- justable through designing the dopant concentration and excitation wavelengths. An unusual energy transfer that originated from Eu3+ to Dy3+ was also discovered and the energy transfer mechanism was discussed. Proposed energy transfer mechanism was investigated using luminescence decay lifetime. All the phosphor exhibited efficient excitation in the UV range which matched well with the emissions from GaN-based LED chips. This presented the BaB2Si208 phosphor as a promising candidate for white LED applications. The effects of doping on the structural properties and the optical band gap of BaB2Si208 phosphor were also discussed in this study. 展开更多
关键词 BaB2Si2O8:eu3+/Dy3+ PHOSPHOR energy transfer rare earths
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