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基于Depth-wise卷积和视觉Transformer的图像分类模型 被引量:2
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作者 张峰 黄仕鑫 +1 位作者 花强 董春茹 《计算机科学》 CSCD 北大核心 2024年第2期196-204,共9页
图像分类作为一种常见的视觉识别任务,有着广阔的应用场景。在处理图像分类问题时,传统的方法通常使用卷积神经网络,然而,卷积网络的感受野有限,难以建模图像的全局关系表示,导致分类精度低,难以处理复杂多样的图像数据。为了对全局关... 图像分类作为一种常见的视觉识别任务,有着广阔的应用场景。在处理图像分类问题时,传统的方法通常使用卷积神经网络,然而,卷积网络的感受野有限,难以建模图像的全局关系表示,导致分类精度低,难以处理复杂多样的图像数据。为了对全局关系进行建模,一些研究者将Transformer应用于图像分类任务,但为了满足Transformer的序列化和并行化要求,需要将图像分割成大小相等、互不重叠的图像块,破坏了相邻图像数据块之间的局部信息。此外,由于Transformer具有较少的先验知识,模型往往需要在大规模数据集上进行预训练,因此计算复杂度较高。为了同时建模图像相邻块之间的局部信息并充分利用图像的全局信息,提出了一种基于Depth-wise卷积的视觉Transformer(Efficient Pyramid Vision Transformer,EPVT)模型。EPVT模型可以实现以较低的计算成本提取相邻图像块之间的局部和全局信息。EPVT模型主要包含3个关键组件:局部感知模块(Local Perceptron Module,LPM)、空间信息融合模块(Spatial Information Fusion,SIF)和“+卷积前馈神经网络(Convolution Feed-forward Network,CFFN)。LPM模块用于捕获图像的局部相关性;SIF模块用于融合相邻图像块之间的局部信息,并利用不同图像块之间的远距离依赖关系,提升模型的特征表达能力,使模型学习到输出特征在不同维度下的语义信息;CFFN模块用于编码位置信息和重塑张量。在图像分类数据集ImageNet-1K上,所提模型优于现有的同等规模的视觉Transformer分类模型,取得了82.6%的分类准确度,证明了该模型在大规模数据集上具有竞争力。 展开更多
关键词 深度学习 图像分类 depth-wise卷积 视觉Transformer 注意力机制
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基于改进FeatDepth的足球运动场景无监督单目图像深度预测
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作者 傅荟璇 徐权文 王宇超 《实验技术与管理》 CAS 北大核心 2024年第10期74-84,共11页
为了在降低成本的同时提高图像深度信息预测的精确度,并将深度估计应用于足球运动场景,提出一种基于改进FeatDepth的足球运动场景无监督单目图像深度预测方法。首先,对原FeatDepth引入注意力机制,使模型更加关注有效的特征信息;其次,将F... 为了在降低成本的同时提高图像深度信息预测的精确度,并将深度估计应用于足球运动场景,提出一种基于改进FeatDepth的足球运动场景无监督单目图像深度预测方法。首先,对原FeatDepth引入注意力机制,使模型更加关注有效的特征信息;其次,将FeatDepth中的PoseNet网络和DepthNet网络分别嵌入GAM全局注意力机制模块,为网络添加额外的上下文信息,在基本不增加计算成本的情况下提升FeatDepth模型深度预测性能;再次,为在低纹理区域和细节上获得更好的深度预测效果,由单视图重构损失与交叉视图重构损失组合而成最终的损失函数。选取KITTI数据集中Person场景较多的部分进行数据集制作并进行仿真实验,结果表明,改进后的FeatDepth模型不仅在精确度上有所提升,且在低纹理区域及细节处拥有更好的深度预测效果。最后,对比模型在足球场景下的推理效果后得出,改进后的模型在低纹理区域(足球、球门等)及细节处(肢体等)有更好的深度预测效果,实现了将基于无监督的单目深度估计模型应用于足球运动场景的目的。 展开更多
关键词 足球运动场景 无监督单目深度估计 Featdepth 注意力机制 GAM 图像重构
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Hemorrhagic transformation in patients with large-artery atherosclerotic stroke is associated with the gut microbiota and lipopolysaccharide 被引量:1
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作者 Qin Huang Minping Wei +3 位作者 Xianjing Feng Yunfang Luo Yunhai Liu Jian Xia 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第7期1532-1540,共9页
Hemorrhagic transformation is a major complication of large-artery atheroscle rotic stroke(a major ischemic stro ke subtype)that wo rsens outcomes and increases mortality.Disruption of the gut microbiota is an importa... Hemorrhagic transformation is a major complication of large-artery atheroscle rotic stroke(a major ischemic stro ke subtype)that wo rsens outcomes and increases mortality.Disruption of the gut microbiota is an important feature of stroke,and some specific bacteria and bacterial metabolites may contribute to hemorrhagic transformation pathogenesis.We aimed to investigate the relationship between the gut microbiota and hemorrhagic transformation in largearte ry atheroscle rotic stro ke.An observational retrospective study was conducted.From May 2020 to September 2021,blood and fecal samples were obtained upon admission from 32 patients with first-ever acute ischemic stroke and not undergoing intravenous thrombolysis or endovascular thrombectomy,as well as 16 healthy controls.Patients with stro ke who developed hemorrhagic transfo rmation(n=15)were compared to those who did not develop hemorrhagic transformation(n=17)and with healthy controls.The gut microbiota was assessed through 16S ribosomal ribonucleic acid sequencing.We also examined key components of the lipopolysaccharide pathway:lipopolysaccharide,lipopolysaccharide-binding protein,and soluble CD14.We observed that bacterial diversity was decreased in both the hemorrhagic transformation and non-hemorrhagic transfo rmation group compared with the healthy controls.The patients with ischemic stro ke who developed hemorrhagic transfo rmation exhibited altered gut micro biota composition,in particular an increase in the relative abundance and dive rsity of members belonging to the Enterobacteriaceae family.Plasma lipopolysaccharide and lipopolysaccharide-binding protein levels were higher in the hemorrhagic transformation group compared with the non-hemorrhagic transfo rmation group.lipopolysaccharide,lipopolysaccharide-binding protein,and soluble CD14 concentrations were associated with increased abundance of Enterobacte riaceae.Next,the role of the gut microbiota in hemorrhagic transformation was evaluated using an experimental stroke rat model.In this model,transplantation of the gut microbiota from hemorrhagic transformation rats into the recipient rats triggered higher plasma levels of lipopolysaccharide,lipopolysaccharide-binding protein,and soluble CD14.Ta ken togethe r,our findings demonstrate a noticeable change in the gut microbiota and lipopolysaccharide-related inflammatory response in stroke patients with hemorrhagic transformation.This suggests that maintaining a balanced gut microbiota may be an important factor in preventing hemorrhagic transfo rmation after stro ke. 展开更多
关键词 gut microbiota hemorrhagic transformation INFLAMMATION LIPOPOLYSACCHARIDE STROKE
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Defect Detection Model Using Time Series Data Augmentation and Transformation 被引量:1
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作者 Gyu-Il Kim Hyun Yoo +1 位作者 Han-Jin Cho Kyungyong Chung 《Computers, Materials & Continua》 SCIE EI 2024年第2期1713-1730,共18页
Time-series data provide important information in many fields,and their processing and analysis have been the focus of much research.However,detecting anomalies is very difficult due to data imbalance,temporal depende... Time-series data provide important information in many fields,and their processing and analysis have been the focus of much research.However,detecting anomalies is very difficult due to data imbalance,temporal dependence,and noise.Therefore,methodologies for data augmentation and conversion of time series data into images for analysis have been studied.This paper proposes a fault detection model that uses time series data augmentation and transformation to address the problems of data imbalance,temporal dependence,and robustness to noise.The method of data augmentation is set as the addition of noise.It involves adding Gaussian noise,with the noise level set to 0.002,to maximize the generalization performance of the model.In addition,we use the Markov Transition Field(MTF)method to effectively visualize the dynamic transitions of the data while converting the time series data into images.It enables the identification of patterns in time series data and assists in capturing the sequential dependencies of the data.For anomaly detection,the PatchCore model is applied to show excellent performance,and the detected anomaly areas are represented as heat maps.It allows for the detection of anomalies,and by applying an anomaly map to the original image,it is possible to capture the areas where anomalies occur.The performance evaluation shows that both F1-score and Accuracy are high when time series data is converted to images.Additionally,when processed as images rather than as time series data,there was a significant reduction in both the size of the data and the training time.The proposed method can provide an important springboard for research in the field of anomaly detection using time series data.Besides,it helps solve problems such as analyzing complex patterns in data lightweight. 展开更多
关键词 Defect detection time series deep learning data augmentation data transformation
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A new insight into LPSO phase transformation and mechanical properties uniformity of large-scale Mg-Gd-Y-Zn-Zr alloy prepared by multi-pass friction stir processing 被引量:1
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作者 Xiaohu Guan Wen Wang +7 位作者 Ting Zhang Pai Peng Qiang Liu Peng Han Ke Qiao Jun Cai Liqiang Wang Kuaishe Wang 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第5期2041-2056,共16页
A large-scale fine-grained Mg-Gd-Y-Zn-Zr alloy plate with high strength and ductility was successfully prepared by multi-pass friction stir processing(MFSP)technology in this work.The structure of grains and long peri... A large-scale fine-grained Mg-Gd-Y-Zn-Zr alloy plate with high strength and ductility was successfully prepared by multi-pass friction stir processing(MFSP)technology in this work.The structure of grains and long period stacking ordered(LPSO)phase were characterized,and the mechanical properties uniformity was investigated.Moreover,a quantitative relationship between the microstructure and tensile yield strength was established.The results showed that the grains in the processed zone(PZ)and interfacial zone(IZ)were refined from 50μm to 3μm and 4μm,respectively,and numerous original LPSO phases were broken.In IZ,some block-shaped 18R LPSO phases were transformed into needle-like 14H LPSO phases due to stacking faults and the short-range diffusion of solute atoms.The severe shear deformation in the form of kinetic energy caused profuse stacking fault to be generated and move rapidly,greatly increasing the transformation rate of LPSO phase.After MFSP,the ultimate tensile strength,yield strength and elongation to failure of the large-scale plate were 367 MPa,305 MPa and 18.0% respectively.Grain refinement and LPSO phase strengthening were the major strengthening mechanisms for the MFSP sample.In particularly,the strength of IZ was comparable to that of PZ because the strength contribution of the 14H LPSO phase offsets the lack of grain refinement strengthening in IZ.This result opposes the widely accepted notion that IZ is a weak region in MFSP-prepared large-scale fine-grained plate. 展开更多
关键词 Friction stir processing MULTI-PASS Mg-Gd-Y-Zn-Zr alloy LPSO phase transformation Mechanical properties
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Intrahepatic portal venous systems in adult patients with cavernous transformation of portal vein: Imaging features and a new classification 被引量:1
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作者 Xin Huang Qian Lu +5 位作者 Yue-Wei Zhang Lin Zhang Zhi-Zhong Ren Xiao-Wei Yang Ying Liu Rui Tang 《Hepatobiliary & Pancreatic Diseases International》 SCIE CAS CSCD 2024年第5期481-486,共6页
Background: Cavernous transformation of the portal vein(CTPV) due to portal vein obstruction is a rare vascular anomaly defined as the formation of multiple collateral vessels in the hepatic hilum. This study aimed to... Background: Cavernous transformation of the portal vein(CTPV) due to portal vein obstruction is a rare vascular anomaly defined as the formation of multiple collateral vessels in the hepatic hilum. This study aimed to investigate the imaging features of intrahepatic portal vein in adult patients with CTPV and establish the relationship between the manifestations of intrahepatic portal vein and the progression of CTPV. Methods: We retrospectively analyzed 14 CTPV patients in Beijing Tsinghua Changgung Hospital. All patients underwent both direct portal venography(DPV) and computed tomography angiography(CTA) to reveal the manifestations of the portal venous system. The vessels measured included the left portal vein(LPV), right portal vein(RPV), main portal vein(MPV) and the portal vein bifurcation(PVB). Results: Nine males and 5 females, with a median age of 40.5 years, were included in the study. No significant difference was found in the diameters of the LPV or RPV measured by DPV and CTA. The visualization in terms of LPV, RPV and PVB measured by DPV was higher than that by CTA. There was a significant association between LPV/RPV and PVB/MPV in term of visibility revealed with DPV( P = 0.01), while this association was not observed with CTA. According to the imaging features of the portal vein measured by DPV, CTPV was classified into three categories to facilitate the diagnosis and treatment. Conclusions: DPV was more accurate than CTA for revealing the course of the intrahepatic portal vein in patients with CTPV. The classification of CTPV, that originated from the imaging features of the portal vein revealed by DPV, may provide a new perspective for the diagnosis and treatment of CTPV. 展开更多
关键词 Cavernous transformation of the portal vein CLASSIFICATION Direct portal venography Intrahepatic portal venous system
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Three-dimensional crystal defect imaging by STEM depth sectioning
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作者 Ryo Ishikawa Naoya Shibata Yuichi Ikuhara 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期2-7,共6页
One of the major innovations awaiting in electron microscopy is full three-dimensional imaging at atomic resolution.Despite the success of aberration correction to deep sub-angstrom lateral resolution,spatial resoluti... One of the major innovations awaiting in electron microscopy is full three-dimensional imaging at atomic resolution.Despite the success of aberration correction to deep sub-angstrom lateral resolution,spatial resolution in depth is still far from atomic resolution.In scanning transmission electron microscopy(STEM),this poor depth resolution is due to the limitation of the illumination angle.To overcome this physical limitation,it is essential to implement a next-generation aberration corrector in STEM that can significantly improve the depth resolution.This review discusses the capability of depth sectioning for three-dimensional imaging combined with large-angle illumination STEM.Furthermore,the statistical analysis approach remarkably improves the depth resolution,making it possible to achieve three-dimensional atomic resolution imaging at oxide surfaces.We will also discuss the future prospects of three-dimensional imaging at atomic resolution by STEM depth sectioning. 展开更多
关键词 atomic-resolution STEM STEM depth sectioning depth resolution DOPANTS surface topography
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Investigation of Groundwater Quality with Borehole Depth in the Basin Granitoids of the Ashanti Region of Ghana
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作者 Bernard Ofosu Augustine Kofi Asante +2 位作者 Festus Anane Mensah Umar-Farouk Usman Naa Korkoi Ayeh 《Journal of Water Resource and Protection》 CAS 2024年第5期381-394,共14页
The dependence of groundwater quality on borehole depth is usually debatable in groundwater studies, especially in complex geological formations where aquifer characteristics vary spatially with depth. This study ther... The dependence of groundwater quality on borehole depth is usually debatable in groundwater studies, especially in complex geological formations where aquifer characteristics vary spatially with depth. This study therefore seeks to investigate the relationship between borehole depth and groundwater quality across the granitoid aquifers within the Birimian Supergroup in the Ashanti Region. Physicochemical analysis records of groundwater quality data were collected from 23 boreholes of public and private institutions in the Ashanti Region of Ghana, and the parametric values of iron, fluoride, total hardness, pH, nitrate, and nitrite were used to study the groundwater quality-depth relationship. The results showed that the depth-to-groundwater quality indicated a marginal increase in water quality in the range of 30 to 50 m, which is mathematically represented by the low-value correlation coefficient (r<sup>2</sup> = 0.026). A relatively significant increase occurs in the depth range of 50 to 80 m, which is given by a correlation coefficient of r<sup>2</sup> = 0.298. The mean percent parameter compatibility was 74%, 82%, 89%, and 97% at 50, 60, 70, and 80 m depths, respectively. The variations in groundwater quality per depth ratio ranged from 1.48, 1.37, 1.27, and 1.21 for 50, 60, 70, and 80 m depth, respectively. The recommended minimum borehole depth for excellent groundwater quality is suggested with a compatibility per meter depth ratio of 1.37. This results in a range between 50 and 70 m as the most desirable drilling depth for excellent groundwater quality within the granitoids of the Birimian Supergroup of the Ashanti Region in Ghana. 展开更多
关键词 Groundwater Quality Borehole depth Birimian Supergroup Granitoid Aquifers Ashanti Region
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Perpendicular-Cutdepth:Perpendicular Direction Depth Cutting Data Augmentation Method
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作者 Le Zou Linsong Hu +2 位作者 Yifan Wang Zhize Wu Xiaofeng Wang 《Computers, Materials & Continua》 SCIE EI 2024年第4期927-941,共15页
Depth estimation is an important task in computer vision.Collecting data at scale for monocular depth estimation is challenging,as this task requires simultaneously capturing RGB images and depth information.Therefore... Depth estimation is an important task in computer vision.Collecting data at scale for monocular depth estimation is challenging,as this task requires simultaneously capturing RGB images and depth information.Therefore,data augmentation is crucial for this task.Existing data augmentationmethods often employ pixel-wise transformations,whichmay inadvertently disrupt edge features.In this paper,we propose a data augmentationmethod formonocular depth estimation,which we refer to as the Perpendicular-Cutdepth method.This method involves cutting realworld depth maps along perpendicular directions and pasting them onto input images,thereby diversifying the data without compromising edge features.To validate the effectiveness of the algorithm,we compared it with existing convolutional neural network(CNN)against the current mainstream data augmentation algorithms.Additionally,to verify the algorithm’s applicability to Transformer networks,we designed an encoder-decoder network structure based on Transformer to assess the generalization of our proposed algorithm.Experimental results demonstrate that,in the field of monocular depth estimation,our proposed method,Perpendicular-Cutdepth,outperforms traditional data augmentationmethods.On the indoor dataset NYU,our method increases accuracy from0.900 to 0.907 and reduces the error rate from0.357 to 0.351.On the outdoor dataset KITTI,our method improves accuracy from 0.9638 to 0.9642 and decreases the error rate from 0.060 to 0.0598. 展开更多
关键词 PERPENDICULAR depth estimation data augmentation
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Extraction of Acoustic Normal Mode Depth Functions Using Range-Difference Method with Vertical Linear Array Data
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作者 GAO Siyu LI Weilu +2 位作者 ZHANG Yinquan LI Xiaolei WANG Ning 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第4期871-882,共12页
Data-derived normal mode extraction is an effective method for extracting normal mode depth functions in the absence of marine environmental data.However,when the corresponding singular vectors become nonunique when t... Data-derived normal mode extraction is an effective method for extracting normal mode depth functions in the absence of marine environmental data.However,when the corresponding singular vectors become nonunique when two or more singular values obtained from the cross-spectral density matrix diagonalization are nearly equal,this results in unsatisfactory extraction outcomes for the normal mode depth functions.To address this issue,we introduced in this paper a range-difference singular value decomposition method for the extraction of normal mode depth functions.We performed the mode extraction by conducting singular value decomposition on the individual frequency components of the signal's cross-spectral density matrix.This was achieved by using pressure and its range-difference matrices constructed from vertical line array data.The proposed method was validated using simulated data.In addition,modes were successfully extracted from ambient noise. 展开更多
关键词 range difference depth function extraction normal mode
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Unraveling the nexus between cellular senescence and malignant transformation:a paradigm shift in cancer research
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作者 Xiaoyu Song Xiyan Liu +2 位作者 Qiqiang Guo Hongde Xu Liu Cao 《Cancer Biology & Medicine》 SCIE CAS CSCD 2024年第7期541-546,共6页
Cellular senescence, a natural process wherein cells cease division and undergo irreversible growth arrest, has long captivated the curiosity of scientists because of its many implications in aging and disease. Recent... Cellular senescence, a natural process wherein cells cease division and undergo irreversible growth arrest, has long captivated the curiosity of scientists because of its many implications in aging and disease. Recent research has shed light on the nexus between cellular senescence and malignant transformation, thus leading to a paradigm shift in understanding cancer development and progression. 展开更多
关键词 MALIGNANT CANCER transformation
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Effects of Biochar Inoculation with Bacillus megaterium on Rice Soil Phosphorus Fraction Transformation and Bacterial Community Dynamics
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作者 YU Keru XUE Zhaokun +4 位作者 FANG Xianzhi MA Jiawei WANG Yongjun LIU Dan YE Zhengqian 《Rice science》 SCIE CSCD 2024年第4期361-365,I0001-I0003,共8页
Rice husk biochar inoculated with Bacillus megaterium(BM)(referred to as BM-inoculated biochar, BMB) and uninoculated rice husk biochar(RHB) were added to soil at two rates(0.5%, as BMB1 and RHB1, respectively, and 1.... Rice husk biochar inoculated with Bacillus megaterium(BM)(referred to as BM-inoculated biochar, BMB) and uninoculated rice husk biochar(RHB) were added to soil at two rates(0.5%, as BMB1 and RHB1, respectively, and 1.0%, as BMB2 and RHB2, respectively) in an incubation experiment to comprehensively evaluate their effects on basic soil properties, phosphorus(P) fractions, bacterial community composition, and P-cycling genes. 展开更多
关键词 soil comprehensive transformation
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The penetration depth of atomic radicals in tubes with catalytic surface properties
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作者 Domen PAUL Miran MOZETIC +3 位作者 Rok ZAPLOTNIK Alenka VESEL Gregor PRIMC Denis DONLAGIC 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第7期157-164,共8页
Catalysis of molecular radicals is often performed in interesting experimental configurations.One possible configuration is tubular geometry.The radicals are introduced into the tubes on one side,and stable molecules ... Catalysis of molecular radicals is often performed in interesting experimental configurations.One possible configuration is tubular geometry.The radicals are introduced into the tubes on one side,and stable molecules are exhausted on the other side.The penetration depth of radicals depends on numerous parameters,so it is not always feasible to calculate it.This article presents systematic measurements of the penetration depth of oxygen atoms along tubes made from nickel,cobalt,and copper.The source of O atoms was a surfatron-type microwave plasma.The initial density of O atoms depended on the gas flow and was 0.7×10^(21)m^(-3),2.4×10^(21)m^(-3),and 4.2×10^(21)m^(-3)at the flow rates of 50,300,and 600 sccm,and pressures of 10,35,and 60 Pa,respectively.The gas temperature remained at room temperature throughout the experiments.The dissociation fraction decreased exponentially along the length of the tubes in all cases.The penetration depths for well-oxidized nickel were 1.2,1.7,and 2.4 cm,respectively.For cobalt,they were slightly lower at 1.0,1.3,and 1.6 cm,respectively,while for copper,they were 1.1,1.3,and 1.7 cm,respectively.The results were explained by gas dynamics and heterogeneous surface association.These data are useful in any attempt to estimate the loss of molecular fragments along tubes,which serve as catalysts for the association of various radicals to stable molecules. 展开更多
关键词 oxygen plasma penetration depth CATALYSIS heterogeneous surface recombination atom loss
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HVSR analysis of pumice sands for sediment depth characterization:A case study for Guadalajara,Mexico
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作者 Hafid Salgado M. Alejandro Ramírez-Gaytan +1 位作者 Adolfo Preciado Christian R.Escudero 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第3期577-591,共15页
The horizontal to vertical spectral ratio(HVSR)methodology is used here to characterize pumice soils and to image the three-dimensional surface geometry of Guadalajara,Mexico.Similar to other Latin American cities,Gua... The horizontal to vertical spectral ratio(HVSR)methodology is used here to characterize pumice soils and to image the three-dimensional surface geometry of Guadalajara,Mexico.Similar to other Latin American cities,Guadalajara is exposed to high seismic risk,with the particularity of being the largest urban settlement in Latin America built on pumice soils.Methodology has not yet been tested to characterize subsoil depths in pumice sands.Due to the questionable use of traditional geotechnical tests for the analysis of pumice soils,HVSR provides an alternative for its characterization without altering its fragile and porous structure.In this work,resonance frequency(F0)and peak amplitude(A0)are used to constrain the depth of the major impedance contrast that represents the interface between bedrock and pumice soil.Results were compared with borehole depths and other available geotechnical and geophysical data and show good agreement.One of the profiles estimated on the riverbanks that cross the city,reveals different subsoil thickness that could have an impact on different site responses on riverine areas to an eventual earthquake.Government and academic efforts are combined in this work to characterize depth sediments,an important parameter that impacts the regulations for construction in the city. 展开更多
关键词 subsoil of Guadalajara shallow soil thickness bedrock depth pumice soil characterization
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Hydrogen-based mineral phase transformation mechanism investigation of pyrolusite ore
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作者 Ruofeng Wang Shuai Yuan +2 位作者 Yanjun Li Peng Gao Ru Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第11期2445-2457,共13页
Pyrolusite comprises the foremost manganese oxides and is a major source of manganese production.An innovative hydrogenbased mineral phase transformation technology to pyrolusite was proposed,where a 96.44%distributio... Pyrolusite comprises the foremost manganese oxides and is a major source of manganese production.An innovative hydrogenbased mineral phase transformation technology to pyrolusite was proposed,where a 96.44%distribution rate of divalent manganese(Mn^(2+))was observed at an optimal roasting temperature of 650℃,a roasting time of 25 min,and an H2 concentration of 20vol%;under these conditions.The manganese predominantly existed in the form of manganosite.This study investigated the generation mechanism of manganosite based on the reduction kinetics,phase transformation,and structural evolution of pyrolusite and revealed that high temperature improved the distribution rate,and the optimal kinetic model for the reaction was the random nucleation and growth model(reaction order,n=3/2)with an activation energy(E_(a))of 24.119 kJ·mol^(−1).Throughout the mineral phase transformation,manganese oxide from the outer layer of particles moves inward to the core.In addition,pyrolusite follows the reduction sequence of MnO_(2)→Mn_(2)O_(3)→Mn_(3)O_(4)→MnO,and the reduction of manganese oxides in each valence state simultaneously proceeds.These findings provide significant insight into the efficient and clean utilization of pyrolusite. 展开更多
关键词 REDUCTION PYROLUSITE phase transformation microstructural evolution
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Effect of burial depth of a new tunnel on the seismic response of an existing tunnel
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作者 Ma Runbo Cao Qikun +3 位作者 Lu Shasha Zhao Dongxu Zhang Yanan Xu Hong 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第4期863-882,共20页
Burial depth is a crucial factor affecting the forces and deformation of tunnels during earthquakes.One key issue is a lack of understanding of the effect of a change in the buried depth of a single-side tunnel on the... Burial depth is a crucial factor affecting the forces and deformation of tunnels during earthquakes.One key issue is a lack of understanding of the effect of a change in the buried depth of a single-side tunnel on the seismic response of a double-tunnel system.In this study,shaking table tests were designed and performed based on a tunnel under construction in Dalian,China.Numerical models were established using the equivalent linear method combined with ABAQUS finite element software to analyze the seismic response of the interacting system.The results showed that the amplification coefficient of the soil acceleration did not change evidently with the burial depth of the new tunnel but decreased as the seismic amplitude increased.In addition,the existing tunnel acceleration,earth pressure,and internal force were hardly affected by the change in the burial depth;for the new tunnel,the acceleration and internal force decreased as the burial depth increased,while the earth pressure increased.This shows that the earth pressure distribution in a double-tunnel system is relatively complex and mainly concentrated on the arch spandrel and arch springing of the relative area.Overall,when the horizontal clearance between the center of the two tunnels was more than twice the sum of the radius of the outer edges of the two tunnels,the change in the burial depth of the new tunnel had little effect on the existing one,and the tunnel structure was deemed safe.These results provide a preliminary understanding and reference for the seismic performance of a double-tunnel system. 展开更多
关键词 burial depth new tunnel existing tunnel seismic response shaking table tests numerical simulations
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The nitrogen transformation behavior based on the pyrolysis products of wheat straw
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作者 Shun Guo Yunfei Li +1 位作者 Shengwei Tang Tao Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第7期58-65,共8页
In order to provide basic design parameters for the industrial pyrolysis process,the transformation behavior of nitrogen was investigated using wheat straw as raw material.The distributions of nitrogen in pyrolysis ch... In order to provide basic design parameters for the industrial pyrolysis process,the transformation behavior of nitrogen was investigated using wheat straw as raw material.The distributions of nitrogen in pyrolysis char,oil,and gas were obtained and the nitrogenous components in the products were analyzed systematically by X-ray photoelectron spectroscopy(XPS),pyrolysis-gas chromatography/mass spectrometry(Py-GC/MS)and thermogravimetric-Fourier transform infrared spectrometry(TG-FTIR).The nitrogen distribution ranges of the pyrolysis char,oil,and gas were 37.34%–54.82%,32.87%–40.94%and 10.20%–28.83%,respectively.More nitrogen was retained in char at lower pyrolysis temperature and the nitrogen distribution of oil was from rise to decline with increasing temperature.The most abundant N-containing compounds in three-phase products were pyrrole-N,amines,and HCN,respectively.In addition,the transformation mechanism of nitrogen from wheat straw to pyrolysis products was concluded. 展开更多
关键词 PYROLYSIS Nitrogen transformation Wheat straw Py-GC/MS TG-FTIR
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Quantitative prediction model for the depth limit of oil accumulation in the deep carbonate rocks:A case study of Lower Ordovician in Tazhong area of Tarim Basin
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作者 Wen-Yang Wang Xiong-Qi Pang +3 位作者 Ya-Ping Wang Zhang-Xin Chen Fu-Jie Jiang Ying Chen 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期115-124,共10页
With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can b... With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can be extended,and the prediction of the depth limit of oil accumulation(DLOA),are issues that have attracted significant attention in petroleum geology.Since it is difficult to characterize the evolution of the physical properties of the marine carbonate reservoir with burial depth,and the deepest drilling still cannot reach the DLOA.Hence,the DLOA cannot be predicted by directly establishing the relationship between the ratio of drilling to the dry layer and the depth.In this study,by establishing the relationships between the porosity and the depth and dry layer ratio of the carbonate reservoir,the relationships between the depth and dry layer ratio were obtained collectively.The depth corresponding to a dry layer ratio of 100%is the DLOA.Based on this,a quantitative prediction model for the DLOA was finally built.The results indicate that the porosity of the carbonate reservoir,Lower Ordovician in Tazhong area of Tarim Basin,tends to decrease with burial depth,and manifests as an overall low porosity reservoir in deep layer.The critical porosity of the DLOA was 1.8%,which is the critical geological condition corresponding to a 100%dry layer ratio encountered in the reservoir.The depth of the DLOA was 9,000 m.This study provides a new method for DLOA prediction that is beneficial for a deeper understanding of oil accumulation,and is of great importance for scientific guidance on deep oil drilling. 展开更多
关键词 Deep layer Tarim Basin Hydrocarbon accumulation depth limit of oil accumulation Prediction model
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Critical approaches in the catalytic transformation of sugar isomerization and epimerization after Fischer-History,challenges,and prospects
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作者 Da-Ming Gao Xun Zhang +5 位作者 Haichao Liu Hidemi Fujino Tingzhou Lei Fuan Sun Jie Zhu Taoli Huhe 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第3期435-453,共19页
The transformation of aldose to ketose or common sugars into rare saccharides,including rare ketoses and aldoses,is of great value and interest to the food industry and for saccharidic biomass utilization,medicine,and... The transformation of aldose to ketose or common sugars into rare saccharides,including rare ketoses and aldoses,is of great value and interest to the food industry and for saccharidic biomass utilization,medicine,and the synthesis of drugs.Nowadays,high-fructose corn syrup(HFCS)is industrially produced in more than 10 million tons annually using immobilized glucose isomerase.Some low-calorie saccharides such as tagatose and psicose,which are becoming popular sweeteners,have also been produced on a pilot scale in order to replace sucrose and HFCS.However,current catalysts and catalytic processes are still difficult to utilize in biomass conversion and also have strong substrate dependence in producing high-value,rare sugars.Considering the specific reaction properties of saccharides and catalysts,since the pioneering discovery by Fischer,various catalysts and catalytic systems have been discovered or developed in attempts to extend the reaction pathways,improve the reaction efficiency,and to potentially produce commercial products.In this review,we trace the history of sugar isomerization/epimerization reactions and summarize the important breakthroughs for each reaction as well as the difficulties that remain unresolved to date. 展开更多
关键词 Rare sugars ISOMERIZATION KETONIZATION EPIMERIZATION Catalytic transformation
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Three-dimensional constrained gravity inversion of Moho depth and crustal structural characteristics at Mozambique continental margin
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作者 Shihao Yang Zhaocai Wu +3 位作者 Yinxia Fang Mingju Xu Jialing Zhang Fanlin Yang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第2期120-129,共10页
Mozambique's continental margin in East Africa was formed during the break-off stage of the east and west Gondwana lands. Studying the geological structure and division of continent-ocean boundary(COB) in Mozambiq... Mozambique's continental margin in East Africa was formed during the break-off stage of the east and west Gondwana lands. Studying the geological structure and division of continent-ocean boundary(COB) in Mozambique's continental margin is considered of great significance to rebuild Gondwana land and understand its movement mode. Along these lines, in this work, the initial Moho was fit using the known Moho depth from reflection seismic profiles, and a 3D multi-point constrained gravity inversion was carried out. Thus, highaccuracy Moho depth and crustal thickness in the study area were acquired. According to the crustal structure distribution based on the inversion results, the continental crust at the narrowest position of the Mozambique Channel was detected. According to the analysis of the crustal thickness, the Mozambique ridge is generally oceanic crust and the COB of the whole Mozambique continental margin is divided. 展开更多
关键词 3D constrained gravity inversion continent-ocean boundary Mozambique continental margin Moho depth
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