The promoting effect of introducing Zn into nano-ZSM-5 zeolites by conventional impregnation method and isomorphous substitution on the performance of 1-hexene aromatization was investigated. The nano-ZSM-5 zeolite wa...The promoting effect of introducing Zn into nano-ZSM-5 zeolites by conventional impregnation method and isomorphous substitution on the performance of 1-hexene aromatization was investigated. The nano-ZSM-5 zeolite was synthesized by a seed-induced method without organic templates. The Zn-modified nano-ZSM-5 zeolite catalysts, xZ n/HNZ5 and y Zn/Al-HNZ5, were prepared by the conventional impregnation method and isomorphous substitution, respectively. The structure, chemical composition and acidity of the catalysts were characterized by XRD, XRF, N2 adsorption, SEM, NH3-TPD and Py-IR, while the catalytic properties were evaluated at 480 °C and a weight hourly space velocity（WHSV） of 2.0 h-1 in the aromatization procedure of 1-hexene. Compared with xZ n/HNZ5, y Zn/Al-HNZ5 exhibited smaller particles and higher dispersion of Zn species, which led to greater intergranular mesopore and homogeneous acidity distribution. Experimental results indicated that the synergy effect between the Brnsted and Lewis acid sites of the isomorphously substituted nano-ZSM-5 zeolites could significantly increase aromatics yield and improve catalytic stability in the 1-hexene aromatization.展开更多
In this paper, the character matrix x n is studied, fast construction method of matrix X 2m is provided. And it is proved that the lower bound estimate of the number of an Latin squares matrix D[X m] is2m(2m)!+...In this paper, the character matrix x n is studied, fast construction method of matrix X 2m is provided. And it is proved that the lower bound estimate of the number of an Latin squares matrix D[X m] is2m(2m)!+∑mi=2[(2m)!] 2∏ij=1K j!∏rj=1b j!.展开更多
This paper presents a general approach for determining the configuration number for any linkage: A kinematic cham (KC) can be divided into some basic kinematic chains (BKCs) and driving joints; there are only 33 kinds...This paper presents a general approach for determining the configuration number for any linkage: A kinematic cham (KC) can be divided into some basic kinematic chains (BKCs) and driving joints; there are only 33 kinds of BKCs with υ =1-4 independent loop, containing only R (revolute) joints and their configuration numbers are given; the configuration number of a KC equals to the multiplication of the configuration numbers of BKCs contained in the KC.展开更多
In the study, the methods of applied histology and histochemistry were used to determine intestinal villus length, crypt depth, the ratio of intestinal villus length to crypt depth, mucous membrane thickness and intes...In the study, the methods of applied histology and histochemistry were used to determine intestinal villus length, crypt depth, the ratio of intestinal villus length to crypt depth, mucous membrane thickness and intestinal wall thickness of duodenum, jejunum and ileum of 42-day-old broilers, so as to study the effects of different conncentrations of homologous probiottcs on small intestinal mucosa struc- ture of the broilers. The results showed that the effect of 0.3% probiotics on small intestine mucosal structures was the best, such as the length of intestinal villus was the longest, the ratio of villus length to crypt depth was the largest, the thins of mucous membrane and intestinal wall was the thickest. These showed that 0,3% probiotics had best effect on improving and enhancing the digestion-absorption func- tion of the small intestine of the broilers.展开更多
In this paper, the character matrix x n is studied, fast construction method of matrix X 2m is provided. And it is proved that the lower bound estimate of the number of an Latin squares matrix D[X m] is2m(2m)!+...In this paper, the character matrix x n is studied, fast construction method of matrix X 2m is provided. And it is proved that the lower bound estimate of the number of an Latin squares matrix D[X m] is2m(2m)!+∑mi=2[(2m)!] 2∏ij=1K j!∏rj=1b j!.展开更多
All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable performance.However,their atomically precise structures remain undefined,...All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable performance.However,their atomically precise structures remain undefined,complicating their optimization and limiting the understanding of their enhanced performance.Here,the underlying structure-property correlation is explored by using a well-defined cobalt-phosphate polyoxometalate cluster [{(Co4)(OH)3(PO4)}4(SiW9 O34)4]^32-(1),which may serve as a molecular model of multimetal hydr(oxy)oxides.The catalytic activity is enhanced upon replacing Co by Fe in 1,resulting in a reduced overpotential(385 mV) for oxygen evolution(by 66 mV) compared to that of the parent 1 at 10 mA cm^-2 in an acidic medium;this overpotential is comparable to that for the IrO2 catalyst These abundant-metal-based polyoxometalates exhibit high stability,with no evidence of degradation even after 24 h of operation.展开更多
For any additive subgroup M of a field F and α∈F such that 2α∈M ,there are two classes of generalized super-Virasoro algebras denoted by SVir [M,α] and SVir [M,α] by Su and Zhao. The latter is in fact a tr...For any additive subgroup M of a field F and α∈F such that 2α∈M ,there are two classes of generalized super-Virasoro algebras denoted by SVir [M,α] and SVir [M,α] by Su and Zhao. The latter is in fact a trivial extension of the former. In this paper,based on the discussion on isomorphisms,the Verma modules of Svir [ M,α] are studied,and the irreducibility of these modules are obtained.展开更多
In the paper we obtain two infinite classes of p-groups, calculate the orders of their automorphism groups and correct a mistake（perhaps misprinted） of Rodney James＇ paper in 1980.
A mechanics system consisting of three mass points on sphere S 2 is considered. The configuration space of the system is a fibre bundle over S 2 . It is proved that first Chern class of the bundle is -2 c 1...A mechanics system consisting of three mass points on sphere S 2 is considered. The configuration space of the system is a fibre bundle over S 2 . It is proved that first Chern class of the bundle is -2 c 1(γ) where γ is the canonical line bundle over the complex projective space CP 1=S 2 , which shows the bundle is non trivial. The information about the first Chern class makes the cohomology groups and homotopy groups of the configuration space worked out. In addition the effects of these topolo gical properties of the configuration space on the behavior in large scale of the system, as the number of equilibrium positions, periodic orbits and reduced phase space, are discussed.展开更多
基金Project(21276067)supported by the National Natural Science Foundation of China
文摘The promoting effect of introducing Zn into nano-ZSM-5 zeolites by conventional impregnation method and isomorphous substitution on the performance of 1-hexene aromatization was investigated. The nano-ZSM-5 zeolite was synthesized by a seed-induced method without organic templates. The Zn-modified nano-ZSM-5 zeolite catalysts, xZ n/HNZ5 and y Zn/Al-HNZ5, were prepared by the conventional impregnation method and isomorphous substitution, respectively. The structure, chemical composition and acidity of the catalysts were characterized by XRD, XRF, N2 adsorption, SEM, NH3-TPD and Py-IR, while the catalytic properties were evaluated at 480 °C and a weight hourly space velocity（WHSV） of 2.0 h-1 in the aromatization procedure of 1-hexene. Compared with xZ n/HNZ5, y Zn/Al-HNZ5 exhibited smaller particles and higher dispersion of Zn species, which led to greater intergranular mesopore and homogeneous acidity distribution. Experimental results indicated that the synergy effect between the Brnsted and Lewis acid sites of the isomorphously substituted nano-ZSM-5 zeolites could significantly increase aromatics yield and improve catalytic stability in the 1-hexene aromatization.
文摘In this paper, the character matrix x n is studied, fast construction method of matrix X 2m is provided. And it is proved that the lower bound estimate of the number of an Latin squares matrix D[X m] is2m(2m)!+∑mi=2[(2m)!] 2∏ij=1K j!∏rj=1b j!.
文摘This paper presents a general approach for determining the configuration number for any linkage: A kinematic cham (KC) can be divided into some basic kinematic chains (BKCs) and driving joints; there are only 33 kinds of BKCs with υ =1-4 independent loop, containing only R (revolute) joints and their configuration numbers are given; the configuration number of a KC equals to the multiplication of the configuration numbers of BKCs contained in the KC.
基金Supported by the Project of Beijing Vocational College of Agriculture(XY-YF-14-18XYYF-14-16)~~
文摘In the study, the methods of applied histology and histochemistry were used to determine intestinal villus length, crypt depth, the ratio of intestinal villus length to crypt depth, mucous membrane thickness and intestinal wall thickness of duodenum, jejunum and ileum of 42-day-old broilers, so as to study the effects of different conncentrations of homologous probiottcs on small intestinal mucosa struc- ture of the broilers. The results showed that the effect of 0.3% probiotics on small intestine mucosal structures was the best, such as the length of intestinal villus was the longest, the ratio of villus length to crypt depth was the largest, the thins of mucous membrane and intestinal wall was the thickest. These showed that 0,3% probiotics had best effect on improving and enhancing the digestion-absorption func- tion of the small intestine of the broilers.
文摘In this paper, the character matrix x n is studied, fast construction method of matrix X 2m is provided. And it is proved that the lower bound estimate of the number of an Latin squares matrix D[X m] is2m(2m)!+∑mi=2[(2m)!] 2∏ij=1K j!∏rj=1b j!.
文摘All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable performance.However,their atomically precise structures remain undefined,complicating their optimization and limiting the understanding of their enhanced performance.Here,the underlying structure-property correlation is explored by using a well-defined cobalt-phosphate polyoxometalate cluster [{(Co4)(OH)3(PO4)}4(SiW9 O34)4]^32-(1),which may serve as a molecular model of multimetal hydr(oxy)oxides.The catalytic activity is enhanced upon replacing Co by Fe in 1,resulting in a reduced overpotential(385 mV) for oxygen evolution(by 66 mV) compared to that of the parent 1 at 10 mA cm^-2 in an acidic medium;this overpotential is comparable to that for the IrO2 catalyst These abundant-metal-based polyoxometalates exhibit high stability,with no evidence of degradation even after 24 h of operation.
基金TheNationalNaturalScienceFoundationofChina (No .10 1710 64 )
文摘For any additive subgroup M of a field F and α∈F such that 2α∈M ,there are two classes of generalized super-Virasoro algebras denoted by SVir [M,α] and SVir [M,α] by Su and Zhao. The latter is in fact a trivial extension of the former. In this paper,based on the discussion on isomorphisms,the Verma modules of Svir [ M,α] are studied,and the irreducibility of these modules are obtained.
基金Supported by NNSF of China(60574052)Supported by NSF(05001820)Supported by PST of Guangdong(2005B33301008)
文摘In the paper we obtain two infinite classes of p-groups, calculate the orders of their automorphism groups and correct a mistake（perhaps misprinted） of Rodney James＇ paper in 1980.
文摘A mechanics system consisting of three mass points on sphere S 2 is considered. The configuration space of the system is a fibre bundle over S 2 . It is proved that first Chern class of the bundle is -2 c 1(γ) where γ is the canonical line bundle over the complex projective space CP 1=S 2 , which shows the bundle is non trivial. The information about the first Chern class makes the cohomology groups and homotopy groups of the configuration space worked out. In addition the effects of these topolo gical properties of the configuration space on the behavior in large scale of the system, as the number of equilibrium positions, periodic orbits and reduced phase space, are discussed.
