1 Introduction The investigation on the reflection of low energy light ions from the solid surface is very important for the fusion research, surface analysis and ion beam implantation technology. The Monte-Carlo simu...1 Introduction The investigation on the reflection of low energy light ions from the solid surface is very important for the fusion research, surface analysis and ion beam implantation technology. The Monte-Carlo simulation is the main method for calculating the reflection coefficient of light ions with low energy, but it costs too much computer time.展开更多
Almost all experimental and theoretical studies on regenerative cryocoolers at temperatures below 20 K mention the use of 4He as working fluid.A preliminary qualitative evaluation indicates that because of the superfl...Almost all experimental and theoretical studies on regenerative cryocoolers at temperatures below 20 K mention the use of 4He as working fluid.A preliminary qualitative evaluation indicates that because of the superfluid phase transition,a working fluid of 3 He would overcome the cooling temperature limitation set by 4He.Starting with a comparison of the thermophysical properties of 3He and 4He,cryogenic regenerator simulations applied to the third/last stage of a pulse tube refrigerator,with 3He and 4He separately,were implemented to quantitatively analyze performance differences of the regenerator with respect to regenerator loss, cooling power and COP.Results conclude that 3He could significantly improve the performance of a regenerative cryocooler.展开更多
Along both sides of the Tancheng-Lujiang Fracture Zone in eastern China, a series of mantle source gas pools constitute a massive-scale tectonic accumulation zone in NNE direction, with the mantle geochemical characte...Along both sides of the Tancheng-Lujiang Fracture Zone in eastern China, a series of mantle source gas pools constitute a massive-scale tectonic accumulation zone in NNE direction, with the mantle geochemical characteristics of high concentrations of CO2 and He, high 3He/4He-40Ar/36Ar ratio system and high δ13Coo2 ratios (the mainfrequency, -3.4‰-4.6‰), showing no difference from the tectonic framework of the area. In the area, thetectonic environment is a rift formed as a result of diapiric mantle injection and crust thinning to form graben-type basins and lithospheric fractures. The mantle-derived volcanic rocks and inclusions are well-developed and a high geothermal zone (mantlesource) exists in the area. The characteristics of the three components (solid, liquid and gas) of mantle, concentrated all over the same tectonic space zone, show that the rift system is of a good tectonic environment or passage for mantle degassing and gas migration. The main types of the gas pools are volcano, fault-block, anticline, buried hill and so on, but most of them are combination traps closely related with fracture. For the mantle source gas pools, rift is an optimum tectonic region, and nearby lithospheric fracture, mantle source volcanic rocks or basement uplifts are a favourable structural location when reservoir-caprock association develops.展开更多
Changkeng Au-Ag deposit is a newly-discovered new type precious metal deposit. N2-Ar-He systematics studies and 3He/4He and δD-δ180 composition analyses show that the ore-forming fluid of the deposit is composed mai...Changkeng Au-Ag deposit is a newly-discovered new type precious metal deposit. N2-Ar-He systematics studies and 3He/4He and δD-δ180 composition analyses show that the ore-forming fluid of the deposit is composed mainly of formation water (sedimentary brine) but not of meteoric water, which was thought to be source of the ore-forming fluid by most previous researchers. The content of mantle-derived magmatic water in the ore-forming fluid is quite low, usually lower than 10% . According to the source of the ore-forming fluid, the Changkeng Au-Ag deposit should belong to sedimentary brine transformed deposits. From the Late Jurassic to the Early Cretaceous Period, with deposition and accumulation of thick sediments in Sanzhou Basin, the formation water in the sedimentary layers was expelled from the basin because of overburden pressure and increasing temperature. The expelled fluid moved laterally along sedimentary layers to the margin of the basin, and finally moved upward along a gently-dipping interlayer fault. Because of a decline in pressure and temperature, ore minerals were deposited in the fault.展开更多
In this paper a comprehensive tracing study is conducted on mantle degassing and deep-seated geological structures in different types of fault zones in the continent of China based on the helium isotope data, coupled ...In this paper a comprehensive tracing study is conducted on mantle degassing and deep-seated geological structures in different types of fault zones in the continent of China based on the helium isotope data, coupled with some indices such as CO2/3He, CH4/3He and 40Ar/36Ar, and geological tectonics data. There are four representative types of fault zones: (1) Lithospheric fault zones in the extensional tectonic environment are characterized by a small Earth’s crust thickness, a lower CH4/3He-high R and lower CO2/3He-high R system, the strongest mantle de- gassing, and the dominance of mantle fluid, as is represented by the Tancheng-Lujiang fault zone. (2) The lithospheric fault zones or the subduction zone in the strongly compresso-tectonic envi- ronment, for instance, the Bangonghu-Nujiang fault zone, are characterized by a huge thick Earth’s crust, with the R/Ra values within the range of 0.43―1.13, and weak mantle degassing with mantle-source helium accounting for 5%―14% of the total. (3) The deep-seated fault zones at the basinal margins of an orogenic belt are characterized by R values being on order of mag- nitude of 10?7, and the CH4/3He values, 109―1010, CO2/3He values, 106―108; as well as much weak mantle degassing. (4) The crustal fault zones in the orogenic belt, such as the Yaojie fault zone (F19), possess a high CH4/3He-low R (10?8) and high CO2/3He-low R system, with no obvi- ous sign of mantle degassing. Studies have shown that the deep-seated huge fault zones are the major channel ways for mantle degassing, the main factors controlling the intensity of mantle degassing are fault depth, tectonic environment and crust thickness; the intensity of mantle de- gassing can reflect the depth and the status of deep-seated tectonic environment of fault, while the geochemical tracing studies of gases can open up a new research approach; upwelling ac- tivity of hydrothermal fluids from the deep interior of the Earth may be one of the driving forces for the formation and evolution of the huge deep fault zones. Piedmont fault zones are the locations where deep-seated tectonic activity and crust/mantle structure are transformed, which are of great significance in understanding the mechanisms of formation of orogenic belts and basins.展开更多
Thermal karst groundwaters with temperatures ranging from 32.8 to 62.5 ℃ were found at Taiyuan（太原） City,the capital of Shanxi（山西） Province.To identify the origin of the thermal groundwater,the following trace...Thermal karst groundwaters with temperatures ranging from 32.8 to 62.5 ℃ were found at Taiyuan（太原） City,the capital of Shanxi（山西） Province.To identify the origin of the thermal groundwater,the following tracers were used in this study：δD,δ18O,4He,3He/4He,and major chemical constituents in water.Hydrochemical and isotopic data indicate that the thermal groundwaters in the basin area are a mixture of thermal waters from the West Mountain and those from the East Mountain.Furthermore,the 4He and 4Heexc concentrations of the thermal groundwater samples are usually lower than those of the cold groundwater samples,and there is an evidently negative correlation between the temperature and the 4He concentration in thermal groundwaters from the West Mountain and the ba-sin,which means that with the increase in temperature,the He concentration increases in the vapor phase and decreases in the aqueous phase.In the plot of 3He/4He vs.4He/20Ne of all water samples：air,crust,and mantle,all thermal groundwater samples are distributed near the line between the point of air and that of crust,suggesting that atmospheric and crustal helium is the main source for that in thermal groundwaters.In other words,there are no mantle-derived fluids mixed in the thermal groundwaters.展开更多
CO2-rich cold springs occur near the active volcanoes at Wudalianchi （五大连池）, Northeast China. The springs are rich in CO2, with HCO3-as the predominant anion and have elevated contents of total dissolved solid ...CO2-rich cold springs occur near the active volcanoes at Wudalianchi （五大连池）, Northeast China. The springs are rich in CO2, with HCO3-as the predominant anion and have elevated contents of total dissolved solid （TDS） （〉1 000 mg/L）, Fe^2＋ （〉20 mg/L）, Sr （〉1 mg/L）, and dissolved Si （〉20 mg/L）. The compositions of escaped and dissolved gases of the springs are similar. The δ^13C values of escaped gases and dissolved gases in mineral springs at Wudalianchi vary from -8.77‰ to -4.53‰ and -8.24‰ to -5.26‰, while δ^18O values vary from -10.68‰ to -7.65‰ and -10.30‰ to -8.84‰, respectively, indicating the same upper mantle origin of CO2 of escaped gases and dissolved gases in the springs. Carbon and oxygen isotope fractionations and water-CO2 exchange were weak in the process of groundwater flow. The 4He content exceeds 5 000×10-6 cm^3·STP/mL in escaped gases of the mineral springs, and the 3He/4He ratios of the escaped and dissolved gases vary from 2.64Ra to 3.87Ra and 1.18Ra to 3.30Ra, respectively. It can be postulated that the CO2 of mineral springs deriving from the magma chamber of the upper mantle moves upward to the surface, to increase the content of 4He in the mineral springs and decrease the ratio of 3He/4He. The helium origin of escaped gases in springs can be calculated with the MORB-crust mixing model, but that in the north spring can be better explained with the MORB-crust-air mixing model due to the effect of mixing with surface water. However, dissolved helium in springs, except the north spring, is better explained with the MORB-crust-ASW mixing model.展开更多
A series of marginal-sea basins and fault-depression basins were formed in eastern China under the background of subduction of the West Pacific plate.Different types of helium-rich natural gas reservoirs(He>1000 pp...A series of marginal-sea basins and fault-depression basins were formed in eastern China under the background of subduction of the West Pacific plate.Different types of helium-rich natural gas reservoirs(He>1000 ppm,1 ppm=1μmol mol^(-1))have been found in these basins:helium-rich CO_(2)gas reservoirs,helium-rich N_(2)gas reservoirs,and helium-rich hydrocarbon gas reservoirs.Based on the analysis of gas geochemical data,the source and accumulation mechanism of helium in these heliumrich natural gas reservoirs were discussed.Helium-rich natural gas has relatively high 3He/4He ratios(0.88-4.91 Ra,average 2.82 Ra).The ^(3)He/^(4)He ratio characteristics of mantle xenoliths and mantle-derived CO_(2)gas reservoirs indicate that the helium in these helium-rich natural gas reservoirs is mainly mantle-derived(>70%).The original mantle volatile is mainly CO_(2)with a low helium concentration(He<200 ppm),and the enrichment of mantle-derived helium in the gas reservoir is mainly related to the dissolution and mineralization of CO_(2).During this process,the CO_(2)/3He ratio decreases from 2×10^(9)to approximately 2×10^(6).As CO_(2)dissolves and mineralizes,the concentration of conservative gases(He and N_(2))increases in the remaining CO_(2)gas proportionally to the loss of CO_(2).Large amounts of carbonate minerals,such as dawsonite,which are relatively enriched in 13C,are found in CO_(2)reservoirs in eastern China.The relative enrichment of^(12)C in residual CO_(2)gas is important evidence of the dissolution and mineralization of CO_(2).The relative abundance of mantle-derived helium and N_(2)gas increases thousands of times during the dissolution and mineralization of CO_(2),which is the main accumulation mechanism of mantle-derived helium-rich CO_(2)gas reservoirs and helium-rich N_(2)gas reservoirs.Helium-rich gas from the mantle is mixed with alkane gas generated by organic matter in the sedimentary basin to form helium-rich hydrocarbon gas reservoirs.展开更多
The isotopic compositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula, China. The 3He/ 4He ratios range from 0.14 Ra (0.14 times the atmospheric 3He/ 4He ratio of 1.40×...The isotopic compositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula, China. The 3He/ 4He ratios range from 0.14 Ra (0.14 times the atmospheric 3He/ 4He ratio of 1.40×10 -6) to 0.72 Ra. 3He/ 4He versus 4He/ 20Ne ratios and He contents suggest that a small amount of mantle-derived helium reaches the earth’s surface. Helium isotope ratios of the hot spring gases show a distribution pattern similar to the regional heat flow values, indicating that the positive thermal anomaly occurring in the area is closely associated with the presence of mantle-derived helium. The observations described above provide some significant evidence that the molten magma originating from partial melting of the upper mantle may have intruded into the continental crust along the activity fault. The coupling of the presence of mantle He and heat flow anomalies to seismic activity in studied region seem to imply that there is an internal relationship between mantle degassing and seismic展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘1 Introduction The investigation on the reflection of low energy light ions from the solid surface is very important for the fusion research, surface analysis and ion beam implantation technology. The Monte-Carlo simulation is the main method for calculating the reflection coefficient of light ions with low energy, but it costs too much computer time.
基金the support from the National Natural Science Foundation of China (50806047)the Shanghai Pujiang Program
文摘Almost all experimental and theoretical studies on regenerative cryocoolers at temperatures below 20 K mention the use of 4He as working fluid.A preliminary qualitative evaluation indicates that because of the superfluid phase transition,a working fluid of 3 He would overcome the cooling temperature limitation set by 4He.Starting with a comparison of the thermophysical properties of 3He and 4He,cryogenic regenerator simulations applied to the third/last stage of a pulse tube refrigerator,with 3He and 4He separately,were implemented to quantitatively analyze performance differences of the regenerator with respect to regenerator loss, cooling power and COP.Results conclude that 3He could significantly improve the performance of a regenerative cryocooler.
文摘Along both sides of the Tancheng-Lujiang Fracture Zone in eastern China, a series of mantle source gas pools constitute a massive-scale tectonic accumulation zone in NNE direction, with the mantle geochemical characteristics of high concentrations of CO2 and He, high 3He/4He-40Ar/36Ar ratio system and high δ13Coo2 ratios (the mainfrequency, -3.4‰-4.6‰), showing no difference from the tectonic framework of the area. In the area, thetectonic environment is a rift formed as a result of diapiric mantle injection and crust thinning to form graben-type basins and lithospheric fractures. The mantle-derived volcanic rocks and inclusions are well-developed and a high geothermal zone (mantlesource) exists in the area. The characteristics of the three components (solid, liquid and gas) of mantle, concentrated all over the same tectonic space zone, show that the rift system is of a good tectonic environment or passage for mantle degassing and gas migration. The main types of the gas pools are volcano, fault-block, anticline, buried hill and so on, but most of them are combination traps closely related with fracture. For the mantle source gas pools, rift is an optimum tectonic region, and nearby lithospheric fracture, mantle source volcanic rocks or basement uplifts are a favourable structural location when reservoir-caprock association develops.
基金Project supported by the National Natural Science Foundation of China (Grant No. 49502029)the Natural Science Foundation of Zhongshan University Research Foundation of National Key Laboratory of Metallogenesis in Nanjing University (Grant No. 039
文摘Changkeng Au-Ag deposit is a newly-discovered new type precious metal deposit. N2-Ar-He systematics studies and 3He/4He and δD-δ180 composition analyses show that the ore-forming fluid of the deposit is composed mainly of formation water (sedimentary brine) but not of meteoric water, which was thought to be source of the ore-forming fluid by most previous researchers. The content of mantle-derived magmatic water in the ore-forming fluid is quite low, usually lower than 10% . According to the source of the ore-forming fluid, the Changkeng Au-Ag deposit should belong to sedimentary brine transformed deposits. From the Late Jurassic to the Early Cretaceous Period, with deposition and accumulation of thick sediments in Sanzhou Basin, the formation water in the sedimentary layers was expelled from the basin because of overburden pressure and increasing temperature. The expelled fluid moved laterally along sedimentary layers to the margin of the basin, and finally moved upward along a gently-dipping interlayer fault. Because of a decline in pressure and temperature, ore minerals were deposited in the fault.
基金the State "973" Program(Grant No.G2002CB211701) the National Natural Science Foundation of China(Grant No.40372065).
文摘In this paper a comprehensive tracing study is conducted on mantle degassing and deep-seated geological structures in different types of fault zones in the continent of China based on the helium isotope data, coupled with some indices such as CO2/3He, CH4/3He and 40Ar/36Ar, and geological tectonics data. There are four representative types of fault zones: (1) Lithospheric fault zones in the extensional tectonic environment are characterized by a small Earth’s crust thickness, a lower CH4/3He-high R and lower CO2/3He-high R system, the strongest mantle de- gassing, and the dominance of mantle fluid, as is represented by the Tancheng-Lujiang fault zone. (2) The lithospheric fault zones or the subduction zone in the strongly compresso-tectonic envi- ronment, for instance, the Bangonghu-Nujiang fault zone, are characterized by a huge thick Earth’s crust, with the R/Ra values within the range of 0.43―1.13, and weak mantle degassing with mantle-source helium accounting for 5%―14% of the total. (3) The deep-seated fault zones at the basinal margins of an orogenic belt are characterized by R values being on order of mag- nitude of 10?7, and the CH4/3He values, 109―1010, CO2/3He values, 106―108; as well as much weak mantle degassing. (4) The crustal fault zones in the orogenic belt, such as the Yaojie fault zone (F19), possess a high CH4/3He-low R (10?8) and high CO2/3He-low R system, with no obvi- ous sign of mantle degassing. Studies have shown that the deep-seated huge fault zones are the major channel ways for mantle degassing, the main factors controlling the intensity of mantle degassing are fault depth, tectonic environment and crust thickness; the intensity of mantle de- gassing can reflect the depth and the status of deep-seated tectonic environment of fault, while the geochemical tracing studies of gases can open up a new research approach; upwelling ac- tivity of hydrothermal fluids from the deep interior of the Earth may be one of the driving forces for the formation and evolution of the huge deep fault zones. Piedmont fault zones are the locations where deep-seated tectonic activity and crust/mantle structure are transformed, which are of great significance in understanding the mechanisms of formation of orogenic belts and basins.
基金supported by the National Natural Science Foundation of China (Nos. 40872157 and 40830748)the China-Russia International Cooperation and Exchange Project of NSFC-RFBR (No. 40711120189)+1 种基金Program for New Century Excellent Talents in University (No. NCET-07-0773)the Aid Project of the Ministry of Science and Technology of China to Developing Countries (No. 2008041012)
文摘Thermal karst groundwaters with temperatures ranging from 32.8 to 62.5 ℃ were found at Taiyuan（太原） City,the capital of Shanxi（山西） Province.To identify the origin of the thermal groundwater,the following tracers were used in this study：δD,δ18O,4He,3He/4He,and major chemical constituents in water.Hydrochemical and isotopic data indicate that the thermal groundwaters in the basin area are a mixture of thermal waters from the West Mountain and those from the East Mountain.Furthermore,the 4He and 4Heexc concentrations of the thermal groundwater samples are usually lower than those of the cold groundwater samples,and there is an evidently negative correlation between the temperature and the 4He concentration in thermal groundwaters from the West Mountain and the ba-sin,which means that with the increase in temperature,the He concentration increases in the vapor phase and decreases in the aqueous phase.In the plot of 3He/4He vs.4He/20Ne of all water samples：air,crust,and mantle,all thermal groundwater samples are distributed near the line between the point of air and that of crust,suggesting that atmospheric and crustal helium is the main source for that in thermal groundwaters.In other words,there are no mantle-derived fluids mixed in the thermal groundwaters.
基金supported by the National Natural Science Foundation of China(Nos.40425001,40602031,40830748),and Russian Fund for Basic Research
文摘CO2-rich cold springs occur near the active volcanoes at Wudalianchi （五大连池）, Northeast China. The springs are rich in CO2, with HCO3-as the predominant anion and have elevated contents of total dissolved solid （TDS） （〉1 000 mg/L）, Fe^2＋ （〉20 mg/L）, Sr （〉1 mg/L）, and dissolved Si （〉20 mg/L）. The compositions of escaped and dissolved gases of the springs are similar. The δ^13C values of escaped gases and dissolved gases in mineral springs at Wudalianchi vary from -8.77‰ to -4.53‰ and -8.24‰ to -5.26‰, while δ^18O values vary from -10.68‰ to -7.65‰ and -10.30‰ to -8.84‰, respectively, indicating the same upper mantle origin of CO2 of escaped gases and dissolved gases in the springs. Carbon and oxygen isotope fractionations and water-CO2 exchange were weak in the process of groundwater flow. The 4He content exceeds 5 000×10-6 cm^3·STP/mL in escaped gases of the mineral springs, and the 3He/4He ratios of the escaped and dissolved gases vary from 2.64Ra to 3.87Ra and 1.18Ra to 3.30Ra, respectively. It can be postulated that the CO2 of mineral springs deriving from the magma chamber of the upper mantle moves upward to the surface, to increase the content of 4He in the mineral springs and decrease the ratio of 3He/4He. The helium origin of escaped gases in springs can be calculated with the MORB-crust mixing model, but that in the north spring can be better explained with the MORB-crust-air mixing model due to the effect of mixing with surface water. However, dissolved helium in springs, except the north spring, is better explained with the MORB-crust-ASW mixing model.
基金supported by the National Key R&D Program of China(Grant No.2021YFA0719002)the National Natural Science Foundation of China(Grant Nos.42141021 and 42141022).
文摘A series of marginal-sea basins and fault-depression basins were formed in eastern China under the background of subduction of the West Pacific plate.Different types of helium-rich natural gas reservoirs(He>1000 ppm,1 ppm=1μmol mol^(-1))have been found in these basins:helium-rich CO_(2)gas reservoirs,helium-rich N_(2)gas reservoirs,and helium-rich hydrocarbon gas reservoirs.Based on the analysis of gas geochemical data,the source and accumulation mechanism of helium in these heliumrich natural gas reservoirs were discussed.Helium-rich natural gas has relatively high 3He/4He ratios(0.88-4.91 Ra,average 2.82 Ra).The ^(3)He/^(4)He ratio characteristics of mantle xenoliths and mantle-derived CO_(2)gas reservoirs indicate that the helium in these helium-rich natural gas reservoirs is mainly mantle-derived(>70%).The original mantle volatile is mainly CO_(2)with a low helium concentration(He<200 ppm),and the enrichment of mantle-derived helium in the gas reservoir is mainly related to the dissolution and mineralization of CO_(2).During this process,the CO_(2)/3He ratio decreases from 2×10^(9)to approximately 2×10^(6).As CO_(2)dissolves and mineralizes,the concentration of conservative gases(He and N_(2))increases in the remaining CO_(2)gas proportionally to the loss of CO_(2).Large amounts of carbonate minerals,such as dawsonite,which are relatively enriched in 13C,are found in CO_(2)reservoirs in eastern China.The relative enrichment of^(12)C in residual CO_(2)gas is important evidence of the dissolution and mineralization of CO_(2).The relative abundance of mantle-derived helium and N_(2)gas increases thousands of times during the dissolution and mineralization of CO_(2),which is the main accumulation mechanism of mantle-derived helium-rich CO_(2)gas reservoirs and helium-rich N_(2)gas reservoirs.Helium-rich gas from the mantle is mixed with alkane gas generated by organic matter in the sedimentary basin to form helium-rich hydrocarbon gas reservoirs.
文摘The isotopic compositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula, China. The 3He/ 4He ratios range from 0.14 Ra (0.14 times the atmospheric 3He/ 4He ratio of 1.40×10 -6) to 0.72 Ra. 3He/ 4He versus 4He/ 20Ne ratios and He contents suggest that a small amount of mantle-derived helium reaches the earth’s surface. Helium isotope ratios of the hot spring gases show a distribution pattern similar to the regional heat flow values, indicating that the positive thermal anomaly occurring in the area is closely associated with the presence of mantle-derived helium. The observations described above provide some significant evidence that the molten magma originating from partial melting of the upper mantle may have intruded into the continental crust along the activity fault. The coupling of the presence of mantle He and heat flow anomalies to seismic activity in studied region seem to imply that there is an internal relationship between mantle degassing and seismic
