The main purpose of this study was to explore and master the optimal types and application methods of microelement fertilizers suitable for peanut cultivation in Linyi City.The results showed that the application of z...The main purpose of this study was to explore and master the optimal types and application methods of microelement fertilizers suitable for peanut cultivation in Linyi City.The results showed that the application of zinc,magnesium,sulfur,calcium and other microelement fertilizers to peanut plants had a certain yield-increasing effect,and zinc had the most significant yield-increasing effect.Compared with the control check(CK),the yield per unit area increased by 1431 kg/hm^(2),equivalent to an increase of 38.4%.Meanwhile,according to field investigation and observation,the treatment of increasing zinc fertilizer had a certain promotion effect on peanut emergence rate,seedling growth potential,and yield components.展开更多
[ Objective] To study the effects of different pretreatment methods on determination of microelement in feed and thus find the best pre treatment method for each microetement, t Method] The samples (concentrated feed...[ Objective] To study the effects of different pretreatment methods on determination of microelement in feed and thus find the best pre treatment method for each microetement, t Method] The samples (concentrated feeding stuff and fodder) were pretreated through throe methods, that is, dry incineration method, HNOs HCIO, wetdecomposition method and microwave digestion method. Then the content of seven kinds of mi croelement (AI, Ca, Cu, Fe, Mn, Se and Zn) was determined by inductively coupled plasma atomic emission spectrometer (ICPAES). I Result] These three methods were all suitable for the determination of Cu, Mn and Zn in concentrated feeding stuff and the determination of Cu and Ca in fodder. The content of Cu and Ca was higher in fodder detected by HNO3 HCIO, wetdecomposition method. The microwave digestion method was suitable for the determination of AI and Ca in concentrated feeding stuff and the determination of AI, Fe, Mn and Zn in fodder. The dry incinera tion method was fit for the determination of Fe in concentrated feeding stuff. [ Condusionl The content of different microelements should be deter mined after the feed is treated with different Ioretreatment methods.展开更多
[Objective]The aim was to analyze the primary speciation of 6 microelements in Glycyrrhiza uralensis Fisch. and provide theoretical basis for explaining pharmacodynamic principle of liquorice and discussing quality co...[Objective]The aim was to analyze the primary speciation of 6 microelements in Glycyrrhiza uralensis Fisch. and provide theoretical basis for explaining pharmacodynamic principle of liquorice and discussing quality control of liquorice planting. [Method]The 6 elements Cu,Zn,Ca,Fe,Mg and Mn in roots of G.uralensis were extracted based on traditional decoction method and were separated into water-soluble state and suspension state by micro porous filtering film. The elements in water-soluble state were detected by flame atomic adsorption spectrophotometry (FAAS). [Result]The results showed that extractive rates of the elements were in the range of 1.71%-60.06%,and immerse-residue ratio in 0.018 3-1.682 0; the results also indicated that the immerse-residue ratio of Zn was biggest (1.68),Zn played an important medical role and might be considered as the best characteristic element in G.uralensis; the recoveries of the elements were ranged from 95.72% to 103.15% and relative standard deviations (RSD) were less than 2.38%. [Conclusion]Because of its high accuracy,FAAS method is feasible for analyzing primary speciation of microelements in G.uralensis.展开更多
The distribution of microelement Fe, Si, Cu and Mg in the surface layer of aluminum foil annealed at 300℃ and 500℃ were determined by secondary ion mass spectrometer. The corrosion structure produced by electrochemi...The distribution of microelement Fe, Si, Cu and Mg in the surface layer of aluminum foil annealed at 300℃ and 500℃ were determined by secondary ion mass spectrometer. The corrosion structure produced by electrochemical etching was also observed. It was found that the Mg concentration at external surface was increased exponentially over the fourth degree and promoted by higher annealing temperature, which will increase the number of corrosion pits inside the large grains, and therefore the specific capacity of the foils for electrolytic capacitors. The similar effects of microelement Fe, Si and Cu were not so strong.展开更多
The objectives of this study were to explore the spatial distribution of soil available microelements and to provide a firm foundation for scientifically formulated fertilizer. 1 076 soil samples were collected from P...The objectives of this study were to explore the spatial distribution of soil available microelements and to provide a firm foundation for scientifically formulated fertilizer. 1 076 soil samples were collected from Pinggu County of Beijing, China, and the contents of available Cu, Zn, Fe, and Mn in topsoil (0-20 cm) and subsoil (20-40 cm) were analyzed respectively. Descriptive statistics and geostatistics were used to analyze the data. The mean values of topsoil available Cu, Zn, Fe, and Mn were 1.96, 2.51, 17.32, and 10.91 mg kg^-1, respectively, which were at medium or at slightly above medium level. The topsoil content of the soil available microelements was more than that of subsoil. The result of semivariance analysis showed that the topsoil available Fe and Mn were spatially correlated at a larger distance of 21.6 and 45.3 km, and the available Cu and Zn were at a shorter distance of 3.1 and 2.9 km, respectively. The subsoil spatial correlation distances were obviously different from the topsoil, which were in the order of available Mn 〉 Cu 〉 Zn = Fe. The Kriging method was applied to calculate the unobserved points and was used to generate the contour map. The results showed that the structural factors, such as topology, soil types, and soil properties, were the main factors influencing the spatial distribution of topsoil available Fe and Mn. Topsoil available Cu and Zn contents were mainly affected by land use, and their contents in orchard and in vegetable land were greatly higher than in field. The spatial distribution of subsoil microelements was similar to that of the topsoil, which exhibited vertical distribution patterns. Fertilizer and pesticide application resulted in the higher contents of available Cu and Zn in Pinggu County. The higher content of available Zn is potentially harmful to soil environmental quality, which should be inspected.展开更多
To provide scientific basis for appraising natural resources in Mt. Namjagbarwa area, the migration characteristics of geochemical microelements, such as Zn, V, Ti, Pb, Ni, Cu, Cr, Co, Be and Ba, in the landscape zone...To provide scientific basis for appraising natural resources in Mt. Namjagbarwa area, the migration characteristics of geochemical microelements, such as Zn, V, Ti, Pb, Ni, Cu, Cr, Co, Be and Ba, in the landscape zones of alpine scrub and meadow, the mountainous dark coniferous forest, the mountainous mixed broadleaf and coniferous forest, the mountainous quasi-subtropical semi-evergreen broadleaf forest, the mountainous subtropical evergreen broadleaf forest, and the valley quasi-tropical monsoon rainforest have been described in the paper.展开更多
Through field plot experiment,we research the influencing factors of cowpea yield and quality after applying boron and molybdenum microelement fertilizer. Results show that the application of boron and molybdenum micr...Through field plot experiment,we research the influencing factors of cowpea yield and quality after applying boron and molybdenum microelement fertilizer. Results show that the application of boron and molybdenum microelement fertilizer can significantly increase the yield and improve the quality of cowpea. Compared with the control,yield per mu increases by 5. 08- 18. 86%; N content increases by 4. 27%-11. 28%; P content increases by 2. 13%- 13. 57%; K content increases by 2. 00%- 18. 48%; crude protein increases by 4. 16%-19. 94%; vitamin C increases by 2. 71%- 11. 79%; nitrate content decreases by 5%- 15%. Besides,it is better to combine boron with molybdenum than to use each of them separately.展开更多
Objective: To study the clinical effect of Fuzheng Jiedu granule (扶正解毒颗粒,FJG) and its influence on serum nitric oxide (NO), nitric oxide synthase (NOS) and microelements in patients with coronary heart disease w...Objective: To study the clinical effect of Fuzheng Jiedu granule (扶正解毒颗粒,FJG) and its influence on serum nitric oxide (NO), nitric oxide synthase (NOS) and microelements in patients with coronary heart disease who are in long-term contact with nickel. Methods: Sixty patients were randomly divided into two groups, the treated group and the control group, 30 in each group. Conventional Western medicinal treatment was applied to both groups, but to the treated group, FJG was given additionally by oral intake, and the therapeutic course for both groups was 4 weeks. Besides, a health control group was set up with 15 healthy subjects selected from the same area, who had no history of contact with nickel. Clinical symptoms of the patients and changes in their electrocardiogram (ECG) and serum levels of NO, NOS and microelements were observed before and after treatment. Results: The total effective rate on clinical symptoms in the treated group was 93. 3% and that in the control group 63. 3% , comparison between the two showing significant difference (P<0.05); the total effective rate on ECG in the two groups was 90.0% and 56.7% respectively, which also showed significant difference (P<0.05). After treatment, levels of serum NO, NOS, Mg, Zn and Ca increased and those of Ni, Mn and Fe decreased significantly (P<0.05 or P<0.01) in the treated group, while in the control group, changes in these laboratory indexes were insignificant. Conclusion: FJG could lower the blood nickel level and regulate the unbalance of microelements, help restore serum NO and NOS in persons exposed to nickel and improve the clinical symptoms of patients with coronary heart disease and in long-term contact with nickel.展开更多
Numerous investigations on submarine hydrothermal ore-forming occurrence have been actively carried out in the last two decades with significant results.The Ag and Au enrichments in the sulfides from black smokers ofh...Numerous investigations on submarine hydrothermal ore-forming occurrence have been actively carried out in the last two decades with significant results.The Ag and Au enrichments in the sulfides from black smokers ofhydrothermal vent field Broken Spur(MAR) aroused our interest to study their mineral hosting forms.Samples were collected from seven hydrothermal chimneys within Broken Spur in the British-Russian BRAVEX(1994) and展开更多
It is worthy to mention that the two broad bean cultivars displayed a surprising situation during the fruiting stage of growth. The absolute amount of pods yield was higher in cv. Assiut 125 than in cv. Assiut 84. Thi...It is worthy to mention that the two broad bean cultivars displayed a surprising situation during the fruiting stage of growth. The absolute amount of pods yield was higher in cv. Assiut 125 than in cv. Assiut 84. This situation was in contrast with that in the vegetative stage, where cv. Assiut 84 produced greater vegetative growth than cv. Assiut 125. Although the cv. Assiut 84 was less affected by the highest dose of copper, the cv. Assiut 125 was greatly affected by this dose. However, another surprising situation was recorded when the absolute values of fresh and dry matter of cv. Assiut 125 were much higher than cv. Assiut 84 at any used copper concentration. The fresh matters of the pods of cv. Assiut 84 and cv. Assiut 125 were 7.24 and 10.16 gm at the level of control and 6.69 and 7.59 gm at the level of 350 ppm Cu, respectively. Their dry matters were 1.99 and 3.52 gm at the level of control and 1.77 and 2.13 gm at the level of 350 ppm Cu2+ in cv. Assiut 84 and cv. Assiut 125, respectively. This contradiction was also extended when these copper-affected cultivars were sprayed by IAA. The cv. Assiut 84 responded slightly to IAA treatment. On the other hand, a considerable increase in the dry matter yield was recorded in the pods of cv. Assiut 125 at any used level of copper when compared to the non-sprayed plants treated by the same copper concentration. At the level of 350 ppm Cu2+ , the pod yield was 2-fold that of plants treated only by 350 ppm Cu2+ , without IAA spraying. Thus, even IAA behaved differently in its effect on the crop yield of the two tested broad bean cultivars. There are big and surprising variations in the accumulation of microelements and heavy metals in pods among the two broad bean genotypes, whatever the treatments used. These variations seemed to be complicated which might need further studies. The concentration of amino acids and their individuals also varied among the two cultivars;they increased in cv. Assiut 84 and decreased in cv. Assiut 125. The increased amino acids in cv. Assiut 84 are mostly used as precursors for phytochelatins. For the previous studies, thus the present work was conducted to explain the effect of Cu and interactive effect with IAA on two selected broad bean cultivars Assiut 84 and Assiut 125 during yielding production.展开更多
In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The result...In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The results indicate that AAMP can notably reduce the diffusible hydrogen,economize the precious microelements microelements and improve the technological properties.Thus the microelements will play an important role in further developing the welding materials.This paper lays emphasis on the discussion of the mechanism of reducing hydrogen by microelements Y and Te.It is considered from the results that both Y and Te belong to surface active elements and can reduce the diffusible hydrogen in weld bead because they can change the surface properlies of molten pool metal and reduce the absorption of hydrogen atom in arc space of liquid metal surface.This research has a great significance in the development and utilization of microelements in welding.展开更多
The available contents of microelements in the topsoil can influence the yield and quality of flue-cured tobacco. Xuancheng is the dominant tobacco-planting region in Anhui province since 2008. In this paper, the tops...The available contents of microelements in the topsoil can influence the yield and quality of flue-cured tobacco. Xuancheng is the dominant tobacco-planting region in Anhui province since 2008. In this paper, the topsoil available Fe, Mn, Cu and Zn contents of 4197 farmlands mainly under rice-rice rotation and wheat-rice rotation in 2008 and of 124 typical farmlands under tobacco-rice rotation in 2015 in Xuancheng city were analyzed in order to disclose the changes and spatial distributions of these microelements and to instruct the reasonable application of the microelement fertilizers. The results showed that the topsoil average available contents in the farmlands under rice-rice rotation or wheat-rice rotation in 2008 were 105.9 mg·kg-1 for Fe, 19.6 mg·kg-1 for Mn, 4.5 mg·kg-1 for Cu, and 3.0 mg·kg-1 for Zn, respectively, increased by 33.14%, 64.29%, 51.11% and 36.67%, respectively, compared with those in the 2nd Soil Survey in 1980s, and the historic, once intensive and overall application of microelement fertilizers was attributed to the great increases. The topsoil average available contents in the farmlands under tobacco-rice rotation in 2015 were 31.1 mg·kg-1 for Fe, 9.8 mg·kg-1 for Mn, 2.1 mg·kg-1 for Cu, and 0.3 mg·kg-1 for Zn, respectively, decreased by 70.63%, 50.00%, 53.33% and 90.00%, respectively, compared with those of the farmlands under rice-rice rotation or wheat-rice rotation in 2008, and the net deficiencies in the input and output of microelements were attributed to the significant decreases in the topsoil microelements. It is necessary to monitor the farmlands under tobacco-rice rotation dynamically and in time in order to decide whether applying microelement fertilizers or not.展开更多
By the method of atomic emission spectrometry with inductively coupled plasma, the content of macro and microelements in the blood plasma of 35 practically healthy people living in the Northern region of Azerbaijan an...By the method of atomic emission spectrometry with inductively coupled plasma, the content of macro and microelements in the blood plasma of 35 practically healthy people living in the Northern region of Azerbaijan and in the Nizhny Novgorod region of the Russian Federation was studied as well as of 23 patients with pulmonary tuberculosis with different phases of the disease. The elemental homeostasis of the blood plasma did not significantly differ depending on the region of residence, except for the potassium level (by 1.3 times greater for Russians) and strontium (by 10 times higher among the inhabitants of the Northern region of Azerbaijan). In patients with focal pulmonary tuberculosis, there were no significant differences in the content of elements in the blood plasma. With pulmonary tuberculosis, accompanied by decomposition processes, the content of calcium, copper, zinc and iron in blood plasma significantly increases in comparison with healthy people. Analysis of the level of these macro- and microelements can be used to determine the transition of the early form of pulmonary tuberculosis to infiltrative and/or cavernous forms, in which the patient becomes epidemiologically dangerous to others.展开更多
The aim of the work is to evaluate the influence of physical activity character on concentration of macro-and microelements in hair of physically active students. 127 students of I-IV year of Physical Education progra...The aim of the work is to evaluate the influence of physical activity character on concentration of macro-and microelements in hair of physically active students. 127 students of I-IV year of Physical Education program at Lithuanian University of Educational Sciences participated in the research, aged from 20 to 24. They were split into three groups. The first (I) group (n = 48) consisted of endurance sport athletes (skiers, biathlon athletes, middle and long distance runners, rowers and cyclists). The second group (II) (n = 61) was made up of the basketball, football, handball and volleyball players. The third group (III) consisted of combat sports (wrestling and boxing) athletes (n = 18). For establishing the concentration of macro- and microelements in hair, x-ray fluorescence method was applied, using CEP-1 ELVAX (MP.MN 3730-2011) device. The results showed that the hair of the students of Physical Education program, practicing endurance sports possessed more calcium, copper, manganese in comparison to the athletes practicing other sports. Concentration of the main elements--zinc, iron, selenium and chromium in the hair of combat sports representatives was statistically significant. Concentration of potassium was also the greatest in this group of the investigated. However, this group of athletes also possessed the greatest values of toxic elements (plumbum, arsenic) in their hair, comparing to the athletes of endurance sport and players. In their hair, hydrargyrum concentration was significantly greater comparing to the values of this element in players' hair. The greatest mean values of cadmium were established in players' hair.展开更多
The contents of soil microelements can affect the growth, yield and quality of tobacco, but it is not clear of the status quo of soil microelements in tobacco fields in Liupanshui city. In this study, soil samples of ...The contents of soil microelements can affect the growth, yield and quality of tobacco, but it is not clear of the status quo of soil microelements in tobacco fields in Liupanshui city. In this study, soil samples of the plough layers (0 - 20 cm) were collected from January to March in 2021 from 500 typical tobacco fields in Liupanshui City (100, 180 and 220 fields in Zhongshan, Shuicheng and Panzhou, respectively), the particle size composition, pH, the contents of organic matter (OM), available boron (B), copper (Cu), iron (Fe), manganese (Mn), molybdenum (Mo) and zinc (Zn) were measured and discussed. the results show that the mean contents of B, Cu, Fe, Mn, Mo and Zn are 0.92, 2.55, 66.47, 47.26, 0.39 and 3.96 mg/kg, respectively, and among which, B, Cu and Zn are at the high grades while Fe, Mn and Mo are at the very-high grades. There are significant differences in B, Fe and Zn among the three regions, while Cu is significantly different between Zhongshan and Shuicheng, Mn is significantly different between Panzhou with Zhongshan and Shuicheng, and Mo is significantly different between Zhongshan and Panzhou. The proportions of fields deficient in microelements are relatively low, no field is Fe-deficient, and the fields deficient in Mo, B, Cu, Zn and Mn are only account for 10.40%, 9.40%, 7.40%, 2.80% and 2.00% of the total fields respectively. B-deficient fields (green and light green colors, the same below) are mainly scattered in the northwest of Zhongshan and in the north and south of Panzhou, Cu-deficient fields mainly in the middle of Shuicheng and Panzhou, Mn-deficient fields mainly in northern Zhongshan, central Shuicheng and north of Panzhou. Mo-deficient fields are mainly in the middle of Shuicheng and the middle and east of Panzhou, while Zn-deficient fields are mainly in the middle of Shuicheng and the middle and east of Panzhou. Altitude is negatively correlated with Mn (P < 0.05), pH is negatively correlated with B (P < 0.05), Fe and Mn (P < 0.01), and OM is positively correlated with Fe and Zn (P < 0.01). Sand is negatively correlated with B (P < 0.05), Mn and Mo (P < 0.01), but positively correlated with Zn (P < 0.01). Silt is positively correlated with Mo (P < 0.05);clay is positively correlated with B (P < 0.05) and Mn (P < 0.01), but negatively correlated with Zn (P < 0.01). In conclusion, most of the fields do not need to apply micro-fertilizers in Liupanshui, but the fields deficient in microelements should be considered to use the corresponding fertilizers.展开更多
Background: Moringa oleifera plant is popularly known for its rich phytoconstituents and nutritional value and important medicinal values in both traditional and modern systems of medicine. We explored the present stu...Background: Moringa oleifera plant is popularly known for its rich phytoconstituents and nutritional value and important medicinal values in both traditional and modern systems of medicine. We explored the present study for measurements of microelements, amino acid, phenolic content in hydro-al-coholic flower and leaf extracts of Moringa oleifera along with anti-diabetic activity in Streptozotocin (STZ)-induced diabetic male Wistar rats. Methodology: The micronutrients were determined by using atomic absorption spectrophotometer at 285 nm and 422 nm for Calcium (Ca), phosphorus (P), Iron (Fe), and Zinc (Zn), etc. The trace elements were also measured by spectrophotometer. The essential amino acid was determined by using Amino acid analyser. The total phenolic content in hydro-alcoholic extracts (flower and leaf) M. oleifera measured the absorbance at 760 nm by UV spectrophotometer. The screening of anti-diabetic activity HAFE and HALE of Moringa oleifera at two different dose of 100 and 200 mg/kg b.w. for 21 days were performed by determining the changes in biochemical parameters. Result and Discussion: The results revels that the presence of micronutrients, trace elements and amino acids in both flower and leaf of M. oleifera. The hydrolaocholic extracts of HAFE and HALE at 200 mg/kg b.w. showed significant antidiabetic activity compared with standard Glibenclamide. Whereas dose at 100 mg/kg b.w. showed moderate activity. Conclusion: In conclusion, the M. oleifera exhibits more effectiveness against STZ-induced diabetes. The HAFE and HALF extracts exhibited significant anti-diabetic property and active components may be isolated and clinical studies is required for further evaluation. Because of the rich source of phytoconstients, nutritional elements will be helpful in processed food products as dietary supplements especially for malnutrition in children in the current era.展开更多
Objective:To analyze the serum vitamin and microelement nutrition of children with pneumonia and explore their relationship with the inflammatory state and immune response. Methods:A total of 78 children with pneumoni...Objective:To analyze the serum vitamin and microelement nutrition of children with pneumonia and explore their relationship with the inflammatory state and immune response. Methods:A total of 78 children with pneumonia who were treated between May 2014 and May 2016 were collected as the observation group, and 50 health children who received vaccination in our hospital during the same period were collected as the normal control group. High performance liquid chromatography was used to determine serum vitamin A (VitA) content, atomic absorption spectrometry was used to determine serum Fe content, and the median VitA and Fe contents were used to further divide the observation group into high VitA group and low VitA group as well as high Fe group and low Fe group, 39 cases in each group. The inflammatory and immune response state in pneumonia children with different VitA and Fe contents were determined.Results:Serum VitA and Fe contents of observation group were lower than those of normal control group;serum inflammatory cytokines IL-6, PCT, sTREM-1 and CRP contents as well as humoral immunity indexes IgG, IgA and IgM contents of low VitA group and high VitA group were higher than those of normal control group, and as serum VitA content reduced, the inflammatory and immune response were enhanced;serum inflammatory cytokines IL-6, PCT, sTREM-1 and CRP contents as well as humoral immunity indexes IgG, IgA and IgM contents of low Fe group and high Fe group were higher than those of normal control group, and as serum Fe content reduced, the inflammatory and immune response were enhanced.Conclusion: Serum VitA and Fe contents were low in children with pneumonia, and their contents are negatively correlated with the inflammatory state and humoral immune response degree.展开更多
Objective: To study the changes of microelement content and erythrocyte immune function in patients with cerebral infarction complicated by pneumonia and their relationship with infection indexes. Methods: Patients wi...Objective: To study the changes of microelement content and erythrocyte immune function in patients with cerebral infarction complicated by pneumonia and their relationship with infection indexes. Methods: Patients with cerebral infarction complicated by pneumonia who were treated in Huangshi Central Hospital between April 2014 and February 2017 were selected as the infection group of the research, and patients with cerebral infarction who were treated in Huangshi Central Hospital during the same period were selected as the control group of the research. Serum was collected to determine the contents of trace elements Zn, Fe, Cu, Se and Ca as well as infection index PCT, and peripheral blood was collected to determine the erythrocyte immune function indexes. Results: Serum PCT content of infection group was greatly higher than that of control group. Serum zinc and Fe contents as well as peripheral blood RBC-ICR, RBC-C3bR, FEER, CD58 and CD59 levels of infection group were greatly lower than those of control group, FEIR level in peripheral blood was obviously higher than that of control group, and Cu, Se and Ca contents were not greatly different from those of control group;serum zinc and Fe contents as well as peripheral blood RBC-ICR, RBC-C3bR, FEER, CD58 and CD59 levels of infection group of patients with high PCT content were remarkably lower than those of patients with low PCT content, FEIR level in peripheral blood was significantly higher than that of patients with low PCT content, and Cu, Se and Ca contents were not greatly different from those of patients with low PCT content. Conclusion:The deficiency of microelements Zn and Fe as well as the weakening of erythrocyte immune function is closely related to the degree of infection in the patients with cerebral infarction complicated by pneumonia.展开更多
In order to search for sources of the raw material of the Qin’s terracotta warriors and horses, we selected 20 samples of pottery warriors and pottery horses of the Qin’s Mausoleum from pit No. 1,19 samples of potte...In order to search for sources of the raw material of the Qin’s terracotta warriors and horses, we selected 20 samples of pottery warriors and pottery horses of the Qin’s Mausoleum from pit No. 1,19 samples of pottery warriors and brick from pit No. 2, 20 samples of clays near the Qin’s Mausoleum and 2 samples of Yaozhou porcelain bodies. The 32 kinds of element content of each sample were measured by neutron activation analysis (NAA). These data were analyzed by fuzzy cluster analysis, the trend cluster analysis diagram was obtained. The results showed that samples of terracotta warriors and horses from pits No.1 and No. 2 were closely related to the loam layer near Qin’s Mausoleum, but their relations with the loess layers were not so close, and they were out of all relation to Yaozhou porcelain bodies. Thus, it could be deduced that the Li Mountain clay may be considered as the original place of the raw materials of the terracotta warriors and horses, the kiln sites might be located nearby the Qin’s展开更多
The article is devoted to the study of ecological and geochemical features of interlayer waters of the Dnieper–Donetsk aquifer system in Ukraine,used for the potable water supply of Kyiv.A wide range of methods was u...The article is devoted to the study of ecological and geochemical features of interlayer waters of the Dnieper–Donetsk aquifer system in Ukraine,used for the potable water supply of Kyiv.A wide range of methods was used,including Microsoft Excel,Statistica,and Attestat software packages,MapInfo Professional 6.5 and ArcGIS-ArcMap 9.3 programs;the method of mass spectrometry with inductively coupled plasma(ICP-MS)and GEMS software were performed.Monitoring study results(during 2007–2023)were analyzed for two interlayer aquifers—Cenomanian-Callovian groundwater complex and Bajocian aquifer.It was determined that the normalized value of mineralization increased with a decrease in water intake during 1980–2010,which indicates a relative increase in the content of mineral substances during longterm exploitation.A high negative correlation(Kcor.=-0.54 to-0.86)is also typical for normalized values of oxidizability,total hardness,pH,Ca,Mg,and Cl content.Comparative analysis of two different aquifers revealed that the macrocomponent composition of Bajocian aquifer remains stable,once for Cenomanian-Callovian groundwater complex,there is a tendency to decrease hydrogen carbonates and increase chlorides and sulfates,whereas the cation composition remains relatively stable.A significant increase(by 55%)of the total mineralization in the representative well located on the right bank of the Dnieper River was found.There is also a significant increase(by more than 5 times)in the iron content,which the authors associate with the unsatisfactory technical condition of the well casing pipes.Physico-chemical modeling of trace elements,performed for investigated aquifers,shows that both aquifers are characterized by the predominant migration of the following metals in the cationic form(aqua-ions):Ca,Mg,Na,Ba,Co,Cu,Mn,Ni,Sr,Zn.It was found that the predominant migration forms of metals in the studied interlayer waters are free uncomplexed ions,carbonate,and hydroxo complexes.展开更多
基金Supported by Peanut Innovation Team Project of Shandong Modern Agricultural Industry Technology System(SDAIT-05-022)Special Fund for Agricultural Technology Promotion in Shandong Province(SDTG-2016-08)。
文摘The main purpose of this study was to explore and master the optimal types and application methods of microelement fertilizers suitable for peanut cultivation in Linyi City.The results showed that the application of zinc,magnesium,sulfur,calcium and other microelement fertilizers to peanut plants had a certain yield-increasing effect,and zinc had the most significant yield-increasing effect.Compared with the control check(CK),the yield per unit area increased by 1431 kg/hm^(2),equivalent to an increase of 38.4%.Meanwhile,according to field investigation and observation,the treatment of increasing zinc fertilizer had a certain promotion effect on peanut emergence rate,seedling growth potential,and yield components.
文摘[ Objective] To study the effects of different pretreatment methods on determination of microelement in feed and thus find the best pre treatment method for each microetement, t Method] The samples (concentrated feeding stuff and fodder) were pretreated through throe methods, that is, dry incineration method, HNOs HCIO, wetdecomposition method and microwave digestion method. Then the content of seven kinds of mi croelement (AI, Ca, Cu, Fe, Mn, Se and Zn) was determined by inductively coupled plasma atomic emission spectrometer (ICPAES). I Result] These three methods were all suitable for the determination of Cu, Mn and Zn in concentrated feeding stuff and the determination of Cu and Ca in fodder. The content of Cu and Ca was higher in fodder detected by HNO3 HCIO, wetdecomposition method. The microwave digestion method was suitable for the determination of AI and Ca in concentrated feeding stuff and the determination of AI, Fe, Mn and Zn in fodder. The dry incinera tion method was fit for the determination of Fe in concentrated feeding stuff. [ Condusionl The content of different microelements should be deter mined after the feed is treated with different Ioretreatment methods.
基金Supported by National Natural Science Foundation of China(30600806)Science and Technology Project of Higher Education of Ningxia Hui Autonomous Region (NJ0626)~~
文摘[Objective]The aim was to analyze the primary speciation of 6 microelements in Glycyrrhiza uralensis Fisch. and provide theoretical basis for explaining pharmacodynamic principle of liquorice and discussing quality control of liquorice planting. [Method]The 6 elements Cu,Zn,Ca,Fe,Mg and Mn in roots of G.uralensis were extracted based on traditional decoction method and were separated into water-soluble state and suspension state by micro porous filtering film. The elements in water-soluble state were detected by flame atomic adsorption spectrophotometry (FAAS). [Result]The results showed that extractive rates of the elements were in the range of 1.71%-60.06%,and immerse-residue ratio in 0.018 3-1.682 0; the results also indicated that the immerse-residue ratio of Zn was biggest (1.68),Zn played an important medical role and might be considered as the best characteristic element in G.uralensis; the recoveries of the elements were ranged from 95.72% to 103.15% and relative standard deviations (RSD) were less than 2.38%. [Conclusion]Because of its high accuracy,FAAS method is feasible for analyzing primary speciation of microelements in G.uralensis.
基金The authors would like to acknowledge the financial supports from the National High Technology Research and Development Program of China(863 program,grant No.2003AA32X170)the Doctoral Foundation of the Eduction Ministry of China(grant No.20040008010).
文摘The distribution of microelement Fe, Si, Cu and Mg in the surface layer of aluminum foil annealed at 300℃ and 500℃ were determined by secondary ion mass spectrometer. The corrosion structure produced by electrochemical etching was also observed. It was found that the Mg concentration at external surface was increased exponentially over the fourth degree and promoted by higher annealing temperature, which will increase the number of corrosion pits inside the large grains, and therefore the specific capacity of the foils for electrolytic capacitors. The similar effects of microelement Fe, Si and Cu were not so strong.
基金Beijing Educatinal Com-mittee Technological Development Program Key Item (KM-200510020006)
文摘The objectives of this study were to explore the spatial distribution of soil available microelements and to provide a firm foundation for scientifically formulated fertilizer. 1 076 soil samples were collected from Pinggu County of Beijing, China, and the contents of available Cu, Zn, Fe, and Mn in topsoil (0-20 cm) and subsoil (20-40 cm) were analyzed respectively. Descriptive statistics and geostatistics were used to analyze the data. The mean values of topsoil available Cu, Zn, Fe, and Mn were 1.96, 2.51, 17.32, and 10.91 mg kg^-1, respectively, which were at medium or at slightly above medium level. The topsoil content of the soil available microelements was more than that of subsoil. The result of semivariance analysis showed that the topsoil available Fe and Mn were spatially correlated at a larger distance of 21.6 and 45.3 km, and the available Cu and Zn were at a shorter distance of 3.1 and 2.9 km, respectively. The subsoil spatial correlation distances were obviously different from the topsoil, which were in the order of available Mn 〉 Cu 〉 Zn = Fe. The Kriging method was applied to calculate the unobserved points and was used to generate the contour map. The results showed that the structural factors, such as topology, soil types, and soil properties, were the main factors influencing the spatial distribution of topsoil available Fe and Mn. Topsoil available Cu and Zn contents were mainly affected by land use, and their contents in orchard and in vegetable land were greatly higher than in field. The spatial distribution of subsoil microelements was similar to that of the topsoil, which exhibited vertical distribution patterns. Fertilizer and pesticide application resulted in the higher contents of available Cu and Zn in Pinggu County. The higher content of available Zn is potentially harmful to soil environmental quality, which should be inspected.
文摘To provide scientific basis for appraising natural resources in Mt. Namjagbarwa area, the migration characteristics of geochemical microelements, such as Zn, V, Ti, Pb, Ni, Cu, Cr, Co, Be and Ba, in the landscape zones of alpine scrub and meadow, the mountainous dark coniferous forest, the mountainous mixed broadleaf and coniferous forest, the mountainous quasi-subtropical semi-evergreen broadleaf forest, the mountainous subtropical evergreen broadleaf forest, and the valley quasi-tropical monsoon rainforest have been described in the paper.
基金Supported by Hainan Natural Science Foundation(311077)
文摘Through field plot experiment,we research the influencing factors of cowpea yield and quality after applying boron and molybdenum microelement fertilizer. Results show that the application of boron and molybdenum microelement fertilizer can significantly increase the yield and improve the quality of cowpea. Compared with the control,yield per mu increases by 5. 08- 18. 86%; N content increases by 4. 27%-11. 28%; P content increases by 2. 13%- 13. 57%; K content increases by 2. 00%- 18. 48%; crude protein increases by 4. 16%-19. 94%; vitamin C increases by 2. 71%- 11. 79%; nitrate content decreases by 5%- 15%. Besides,it is better to combine boron with molybdenum than to use each of them separately.
文摘Objective: To study the clinical effect of Fuzheng Jiedu granule (扶正解毒颗粒,FJG) and its influence on serum nitric oxide (NO), nitric oxide synthase (NOS) and microelements in patients with coronary heart disease who are in long-term contact with nickel. Methods: Sixty patients were randomly divided into two groups, the treated group and the control group, 30 in each group. Conventional Western medicinal treatment was applied to both groups, but to the treated group, FJG was given additionally by oral intake, and the therapeutic course for both groups was 4 weeks. Besides, a health control group was set up with 15 healthy subjects selected from the same area, who had no history of contact with nickel. Clinical symptoms of the patients and changes in their electrocardiogram (ECG) and serum levels of NO, NOS and microelements were observed before and after treatment. Results: The total effective rate on clinical symptoms in the treated group was 93. 3% and that in the control group 63. 3% , comparison between the two showing significant difference (P<0.05); the total effective rate on ECG in the two groups was 90.0% and 56.7% respectively, which also showed significant difference (P<0.05). After treatment, levels of serum NO, NOS, Mg, Zn and Ca increased and those of Ni, Mn and Fe decreased significantly (P<0.05 or P<0.01) in the treated group, while in the control group, changes in these laboratory indexes were insignificant. Conclusion: FJG could lower the blood nickel level and regulate the unbalance of microelements, help restore serum NO and NOS in persons exposed to nickel and improve the clinical symptoms of patients with coronary heart disease and in long-term contact with nickel.
文摘Numerous investigations on submarine hydrothermal ore-forming occurrence have been actively carried out in the last two decades with significant results.The Ag and Au enrichments in the sulfides from black smokers ofhydrothermal vent field Broken Spur(MAR) aroused our interest to study their mineral hosting forms.Samples were collected from seven hydrothermal chimneys within Broken Spur in the British-Russian BRAVEX(1994) and
文摘It is worthy to mention that the two broad bean cultivars displayed a surprising situation during the fruiting stage of growth. The absolute amount of pods yield was higher in cv. Assiut 125 than in cv. Assiut 84. This situation was in contrast with that in the vegetative stage, where cv. Assiut 84 produced greater vegetative growth than cv. Assiut 125. Although the cv. Assiut 84 was less affected by the highest dose of copper, the cv. Assiut 125 was greatly affected by this dose. However, another surprising situation was recorded when the absolute values of fresh and dry matter of cv. Assiut 125 were much higher than cv. Assiut 84 at any used copper concentration. The fresh matters of the pods of cv. Assiut 84 and cv. Assiut 125 were 7.24 and 10.16 gm at the level of control and 6.69 and 7.59 gm at the level of 350 ppm Cu, respectively. Their dry matters were 1.99 and 3.52 gm at the level of control and 1.77 and 2.13 gm at the level of 350 ppm Cu2+ in cv. Assiut 84 and cv. Assiut 125, respectively. This contradiction was also extended when these copper-affected cultivars were sprayed by IAA. The cv. Assiut 84 responded slightly to IAA treatment. On the other hand, a considerable increase in the dry matter yield was recorded in the pods of cv. Assiut 125 at any used level of copper when compared to the non-sprayed plants treated by the same copper concentration. At the level of 350 ppm Cu2+ , the pod yield was 2-fold that of plants treated only by 350 ppm Cu2+ , without IAA spraying. Thus, even IAA behaved differently in its effect on the crop yield of the two tested broad bean cultivars. There are big and surprising variations in the accumulation of microelements and heavy metals in pods among the two broad bean genotypes, whatever the treatments used. These variations seemed to be complicated which might need further studies. The concentration of amino acids and their individuals also varied among the two cultivars;they increased in cv. Assiut 84 and decreased in cv. Assiut 125. The increased amino acids in cv. Assiut 84 are mostly used as precursors for phytochelatins. For the previous studies, thus the present work was conducted to explain the effect of Cu and interactive effect with IAA on two selected broad bean cultivars Assiut 84 and Assiut 125 during yielding production.
文摘In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The results indicate that AAMP can notably reduce the diffusible hydrogen,economize the precious microelements microelements and improve the technological properties.Thus the microelements will play an important role in further developing the welding materials.This paper lays emphasis on the discussion of the mechanism of reducing hydrogen by microelements Y and Te.It is considered from the results that both Y and Te belong to surface active elements and can reduce the diffusible hydrogen in weld bead because they can change the surface properlies of molten pool metal and reduce the absorption of hydrogen atom in arc space of liquid metal surface.This research has a great significance in the development and utilization of microelements in welding.
文摘The available contents of microelements in the topsoil can influence the yield and quality of flue-cured tobacco. Xuancheng is the dominant tobacco-planting region in Anhui province since 2008. In this paper, the topsoil available Fe, Mn, Cu and Zn contents of 4197 farmlands mainly under rice-rice rotation and wheat-rice rotation in 2008 and of 124 typical farmlands under tobacco-rice rotation in 2015 in Xuancheng city were analyzed in order to disclose the changes and spatial distributions of these microelements and to instruct the reasonable application of the microelement fertilizers. The results showed that the topsoil average available contents in the farmlands under rice-rice rotation or wheat-rice rotation in 2008 were 105.9 mg·kg-1 for Fe, 19.6 mg·kg-1 for Mn, 4.5 mg·kg-1 for Cu, and 3.0 mg·kg-1 for Zn, respectively, increased by 33.14%, 64.29%, 51.11% and 36.67%, respectively, compared with those in the 2nd Soil Survey in 1980s, and the historic, once intensive and overall application of microelement fertilizers was attributed to the great increases. The topsoil average available contents in the farmlands under tobacco-rice rotation in 2015 were 31.1 mg·kg-1 for Fe, 9.8 mg·kg-1 for Mn, 2.1 mg·kg-1 for Cu, and 0.3 mg·kg-1 for Zn, respectively, decreased by 70.63%, 50.00%, 53.33% and 90.00%, respectively, compared with those of the farmlands under rice-rice rotation or wheat-rice rotation in 2008, and the net deficiencies in the input and output of microelements were attributed to the significant decreases in the topsoil microelements. It is necessary to monitor the farmlands under tobacco-rice rotation dynamically and in time in order to decide whether applying microelement fertilizers or not.
文摘By the method of atomic emission spectrometry with inductively coupled plasma, the content of macro and microelements in the blood plasma of 35 practically healthy people living in the Northern region of Azerbaijan and in the Nizhny Novgorod region of the Russian Federation was studied as well as of 23 patients with pulmonary tuberculosis with different phases of the disease. The elemental homeostasis of the blood plasma did not significantly differ depending on the region of residence, except for the potassium level (by 1.3 times greater for Russians) and strontium (by 10 times higher among the inhabitants of the Northern region of Azerbaijan). In patients with focal pulmonary tuberculosis, there were no significant differences in the content of elements in the blood plasma. With pulmonary tuberculosis, accompanied by decomposition processes, the content of calcium, copper, zinc and iron in blood plasma significantly increases in comparison with healthy people. Analysis of the level of these macro- and microelements can be used to determine the transition of the early form of pulmonary tuberculosis to infiltrative and/or cavernous forms, in which the patient becomes epidemiologically dangerous to others.
文摘The aim of the work is to evaluate the influence of physical activity character on concentration of macro-and microelements in hair of physically active students. 127 students of I-IV year of Physical Education program at Lithuanian University of Educational Sciences participated in the research, aged from 20 to 24. They were split into three groups. The first (I) group (n = 48) consisted of endurance sport athletes (skiers, biathlon athletes, middle and long distance runners, rowers and cyclists). The second group (II) (n = 61) was made up of the basketball, football, handball and volleyball players. The third group (III) consisted of combat sports (wrestling and boxing) athletes (n = 18). For establishing the concentration of macro- and microelements in hair, x-ray fluorescence method was applied, using CEP-1 ELVAX (MP.MN 3730-2011) device. The results showed that the hair of the students of Physical Education program, practicing endurance sports possessed more calcium, copper, manganese in comparison to the athletes practicing other sports. Concentration of the main elements--zinc, iron, selenium and chromium in the hair of combat sports representatives was statistically significant. Concentration of potassium was also the greatest in this group of the investigated. However, this group of athletes also possessed the greatest values of toxic elements (plumbum, arsenic) in their hair, comparing to the athletes of endurance sport and players. In their hair, hydrargyrum concentration was significantly greater comparing to the values of this element in players' hair. The greatest mean values of cadmium were established in players' hair.
文摘The contents of soil microelements can affect the growth, yield and quality of tobacco, but it is not clear of the status quo of soil microelements in tobacco fields in Liupanshui city. In this study, soil samples of the plough layers (0 - 20 cm) were collected from January to March in 2021 from 500 typical tobacco fields in Liupanshui City (100, 180 and 220 fields in Zhongshan, Shuicheng and Panzhou, respectively), the particle size composition, pH, the contents of organic matter (OM), available boron (B), copper (Cu), iron (Fe), manganese (Mn), molybdenum (Mo) and zinc (Zn) were measured and discussed. the results show that the mean contents of B, Cu, Fe, Mn, Mo and Zn are 0.92, 2.55, 66.47, 47.26, 0.39 and 3.96 mg/kg, respectively, and among which, B, Cu and Zn are at the high grades while Fe, Mn and Mo are at the very-high grades. There are significant differences in B, Fe and Zn among the three regions, while Cu is significantly different between Zhongshan and Shuicheng, Mn is significantly different between Panzhou with Zhongshan and Shuicheng, and Mo is significantly different between Zhongshan and Panzhou. The proportions of fields deficient in microelements are relatively low, no field is Fe-deficient, and the fields deficient in Mo, B, Cu, Zn and Mn are only account for 10.40%, 9.40%, 7.40%, 2.80% and 2.00% of the total fields respectively. B-deficient fields (green and light green colors, the same below) are mainly scattered in the northwest of Zhongshan and in the north and south of Panzhou, Cu-deficient fields mainly in the middle of Shuicheng and Panzhou, Mn-deficient fields mainly in northern Zhongshan, central Shuicheng and north of Panzhou. Mo-deficient fields are mainly in the middle of Shuicheng and the middle and east of Panzhou, while Zn-deficient fields are mainly in the middle of Shuicheng and the middle and east of Panzhou. Altitude is negatively correlated with Mn (P < 0.05), pH is negatively correlated with B (P < 0.05), Fe and Mn (P < 0.01), and OM is positively correlated with Fe and Zn (P < 0.01). Sand is negatively correlated with B (P < 0.05), Mn and Mo (P < 0.01), but positively correlated with Zn (P < 0.01). Silt is positively correlated with Mo (P < 0.05);clay is positively correlated with B (P < 0.05) and Mn (P < 0.01), but negatively correlated with Zn (P < 0.01). In conclusion, most of the fields do not need to apply micro-fertilizers in Liupanshui, but the fields deficient in microelements should be considered to use the corresponding fertilizers.
文摘Background: Moringa oleifera plant is popularly known for its rich phytoconstituents and nutritional value and important medicinal values in both traditional and modern systems of medicine. We explored the present study for measurements of microelements, amino acid, phenolic content in hydro-al-coholic flower and leaf extracts of Moringa oleifera along with anti-diabetic activity in Streptozotocin (STZ)-induced diabetic male Wistar rats. Methodology: The micronutrients were determined by using atomic absorption spectrophotometer at 285 nm and 422 nm for Calcium (Ca), phosphorus (P), Iron (Fe), and Zinc (Zn), etc. The trace elements were also measured by spectrophotometer. The essential amino acid was determined by using Amino acid analyser. The total phenolic content in hydro-alcoholic extracts (flower and leaf) M. oleifera measured the absorbance at 760 nm by UV spectrophotometer. The screening of anti-diabetic activity HAFE and HALE of Moringa oleifera at two different dose of 100 and 200 mg/kg b.w. for 21 days were performed by determining the changes in biochemical parameters. Result and Discussion: The results revels that the presence of micronutrients, trace elements and amino acids in both flower and leaf of M. oleifera. The hydrolaocholic extracts of HAFE and HALE at 200 mg/kg b.w. showed significant antidiabetic activity compared with standard Glibenclamide. Whereas dose at 100 mg/kg b.w. showed moderate activity. Conclusion: In conclusion, the M. oleifera exhibits more effectiveness against STZ-induced diabetes. The HAFE and HALF extracts exhibited significant anti-diabetic property and active components may be isolated and clinical studies is required for further evaluation. Because of the rich source of phytoconstients, nutritional elements will be helpful in processed food products as dietary supplements especially for malnutrition in children in the current era.
文摘Objective:To analyze the serum vitamin and microelement nutrition of children with pneumonia and explore their relationship with the inflammatory state and immune response. Methods:A total of 78 children with pneumonia who were treated between May 2014 and May 2016 were collected as the observation group, and 50 health children who received vaccination in our hospital during the same period were collected as the normal control group. High performance liquid chromatography was used to determine serum vitamin A (VitA) content, atomic absorption spectrometry was used to determine serum Fe content, and the median VitA and Fe contents were used to further divide the observation group into high VitA group and low VitA group as well as high Fe group and low Fe group, 39 cases in each group. The inflammatory and immune response state in pneumonia children with different VitA and Fe contents were determined.Results:Serum VitA and Fe contents of observation group were lower than those of normal control group;serum inflammatory cytokines IL-6, PCT, sTREM-1 and CRP contents as well as humoral immunity indexes IgG, IgA and IgM contents of low VitA group and high VitA group were higher than those of normal control group, and as serum VitA content reduced, the inflammatory and immune response were enhanced;serum inflammatory cytokines IL-6, PCT, sTREM-1 and CRP contents as well as humoral immunity indexes IgG, IgA and IgM contents of low Fe group and high Fe group were higher than those of normal control group, and as serum Fe content reduced, the inflammatory and immune response were enhanced.Conclusion: Serum VitA and Fe contents were low in children with pneumonia, and their contents are negatively correlated with the inflammatory state and humoral immune response degree.
文摘Objective: To study the changes of microelement content and erythrocyte immune function in patients with cerebral infarction complicated by pneumonia and their relationship with infection indexes. Methods: Patients with cerebral infarction complicated by pneumonia who were treated in Huangshi Central Hospital between April 2014 and February 2017 were selected as the infection group of the research, and patients with cerebral infarction who were treated in Huangshi Central Hospital during the same period were selected as the control group of the research. Serum was collected to determine the contents of trace elements Zn, Fe, Cu, Se and Ca as well as infection index PCT, and peripheral blood was collected to determine the erythrocyte immune function indexes. Results: Serum PCT content of infection group was greatly higher than that of control group. Serum zinc and Fe contents as well as peripheral blood RBC-ICR, RBC-C3bR, FEER, CD58 and CD59 levels of infection group were greatly lower than those of control group, FEIR level in peripheral blood was obviously higher than that of control group, and Cu, Se and Ca contents were not greatly different from those of control group;serum zinc and Fe contents as well as peripheral blood RBC-ICR, RBC-C3bR, FEER, CD58 and CD59 levels of infection group of patients with high PCT content were remarkably lower than those of patients with low PCT content, FEIR level in peripheral blood was significantly higher than that of patients with low PCT content, and Cu, Se and Ca contents were not greatly different from those of patients with low PCT content. Conclusion:The deficiency of microelements Zn and Fe as well as the weakening of erythrocyte immune function is closely related to the degree of infection in the patients with cerebral infarction complicated by pneumonia.
基金This work was supported by the National Natural Science Foundation of China (Grant Nos. 59872032 and 10175053) the Natural Science Foundation of Henan Province (Grant No. 004051500) the Youth Foundation of Zhengzhou University and Open Lab of Nuclear
文摘In order to search for sources of the raw material of the Qin’s terracotta warriors and horses, we selected 20 samples of pottery warriors and pottery horses of the Qin’s Mausoleum from pit No. 1,19 samples of pottery warriors and brick from pit No. 2, 20 samples of clays near the Qin’s Mausoleum and 2 samples of Yaozhou porcelain bodies. The 32 kinds of element content of each sample were measured by neutron activation analysis (NAA). These data were analyzed by fuzzy cluster analysis, the trend cluster analysis diagram was obtained. The results showed that samples of terracotta warriors and horses from pits No.1 and No. 2 were closely related to the loam layer near Qin’s Mausoleum, but their relations with the loess layers were not so close, and they were out of all relation to Yaozhou porcelain bodies. Thus, it could be deduced that the Li Mountain clay may be considered as the original place of the raw materials of the terracotta warriors and horses, the kiln sites might be located nearby the Qin’s
基金financially supported by budget thematic of M.P.Semenenko Institute of Geochemistry,Mineralogy and Ore Formation of the NAS of Ukraine and the State Institution‘‘The Institute of Environmental Geochemistry of the National Academy of Sciences of Ukraine’’。
文摘The article is devoted to the study of ecological and geochemical features of interlayer waters of the Dnieper–Donetsk aquifer system in Ukraine,used for the potable water supply of Kyiv.A wide range of methods was used,including Microsoft Excel,Statistica,and Attestat software packages,MapInfo Professional 6.5 and ArcGIS-ArcMap 9.3 programs;the method of mass spectrometry with inductively coupled plasma(ICP-MS)and GEMS software were performed.Monitoring study results(during 2007–2023)were analyzed for two interlayer aquifers—Cenomanian-Callovian groundwater complex and Bajocian aquifer.It was determined that the normalized value of mineralization increased with a decrease in water intake during 1980–2010,which indicates a relative increase in the content of mineral substances during longterm exploitation.A high negative correlation(Kcor.=-0.54 to-0.86)is also typical for normalized values of oxidizability,total hardness,pH,Ca,Mg,and Cl content.Comparative analysis of two different aquifers revealed that the macrocomponent composition of Bajocian aquifer remains stable,once for Cenomanian-Callovian groundwater complex,there is a tendency to decrease hydrogen carbonates and increase chlorides and sulfates,whereas the cation composition remains relatively stable.A significant increase(by 55%)of the total mineralization in the representative well located on the right bank of the Dnieper River was found.There is also a significant increase(by more than 5 times)in the iron content,which the authors associate with the unsatisfactory technical condition of the well casing pipes.Physico-chemical modeling of trace elements,performed for investigated aquifers,shows that both aquifers are characterized by the predominant migration of the following metals in the cationic form(aqua-ions):Ca,Mg,Na,Ba,Co,Cu,Mn,Ni,Sr,Zn.It was found that the predominant migration forms of metals in the studied interlayer waters are free uncomplexed ions,carbonate,and hydroxo complexes.