DNA analysis is the core of biotechnology applied in petroleum resources and engineering. Traditionally accurate determination of DNA purity and concentration by spectrometer is the first and critical step for downstr...DNA analysis is the core of biotechnology applied in petroleum resources and engineering. Traditionally accurate determination of DNA purity and concentration by spectrometer is the first and critical step for downstream molecular biology research. In this study, three different spectrophotometry methods, BPM, NDTT and NPMTTZ were compared for their performance in determining DNA concentration and purity in 32 oil samples, and molecule methods like quantitative real-time PCR (qPCR) and high-throughput sequence were also performed to help assess the accuracy of the three methods in determining DNA concentration and purity. For ordinary heavy oil (OHO), extra heavy oil (EHO) and super heavy oil (SHO), the characteristics of high viscosity (η), density (ρ) and resin plus asphaltene content will affect the DNA extraction and UV determination. The DNA concentration was decreased as density increased: OHO (11.46 ± 18.34 ng/μL), EHO (6.68 ± 9.67 ng/μL) and SHO (6.20 ± 7.83 ng/μL), and the DNA purity was on the reverse: OHO (1.31 ± 0.27), EHO (1.54 ± 0.20), and SHO (1.83 ± 0.32). The results suggest that spectrophotometry such as BPM and NPMTTZ are qualitatively favorite methods as the quick non-consumable methods in determining DNA concentration and purity of medium oil and heavy oil.展开更多
In this study,the effects of Al addition on the corrosion behavior of pure Mg with controlled impurity contents were systematically analyzed according to the processing history.The results revealed that the corrosion ...In this study,the effects of Al addition on the corrosion behavior of pure Mg with controlled impurity contents were systematically analyzed according to the processing history.The results revealed that the corrosion behavior of high-purity Mg-Al alloys is strongly related to changes in the microstructure,including theβphase and Al-Mn or Al-Fe phases,and the protectiveness of the surface film according to the Al content and processing history.In the as-cast alloys,the corrosion rate increased due to the increase ofβphase as the Al content increased,but in the as-extruded alloys,the corrosion rate,which was high due to intermetallic compounds caused by impurities in the low Al alloy,decreased as the Al content increased,and then increased again.This is due to the combined effect of the increase of theβphase and decrease of the impurity effect,and the increase of the dissolved Al content.The results suggest that it is necessary to analyze the effect of alloying elements on the corrosion behavior of pure Mg with information concerning the impurity content and processing history.展开更多
A quantum steering ellipsoid(QSE)is a visual characterization for bipartite qubit systems,and it is also a novel avenue for describing and detecting quantum correlations.Herein,by using a QSE,we visualize and witness ...A quantum steering ellipsoid(QSE)is a visual characterization for bipartite qubit systems,and it is also a novel avenue for describing and detecting quantum correlations.Herein,by using a QSE,we visualize and witness the first-order coherence(FOC),Bell nonlocality(BN)and purity under non-inertial frames.Also,the collective influences of the depolarizing channel and the non-coherence-generating channel(NCGC)on the FOC,BN and purity are investigated in the QSE formalism.The results reveal that the distance from the center of the QSE to the center of the Bloch sphere visualizes the FOC of a bipartite system,the lengths of the QSE semiaxis visualize the BN,and the QSE's shape and position dominate the purity of the system.One can capture the FOC,BN and purity via the shape and position of the QSE in the non-inertial frame.The depolarizing channel(the NCGC)gives rise to the shrinking and degradation(the periodical oscillation)of the QSE.One can use these traits to visually characterize and detect the FOC,BN and purity under the influence of external noise.Of particular note is that the condition for the QSE to achieve the center of the Bloch sphere cannot be influenced by the depolarizing channel and the NCGC.The characterization shows that the conditions for the disappearance of the FOC are invariant under the additional influences of the depolarizing channel and NCGC.展开更多
Bronze phase titanium dioxide(TiO_(2)(B))could be a promising high-power anode for lithium ion battery.However,TiO_(2)(B)is a metastable material,so the as-synthesized samples are inevitably accompanied by the existen...Bronze phase titanium dioxide(TiO_(2)(B))could be a promising high-power anode for lithium ion battery.However,TiO_(2)(B)is a metastable material,so the as-synthesized samples are inevitably accompanied by the existence of anatase phases.It has been found that the TiO_(2)(B)'s purity is positively correlated with its electrochemical performance.Herein,we have established an accurate quantification of the TiO_(2)(B)/anatase ratio,by figuring out the function between the purity of TiO_(2)(B)phase in the high purity range and its Raman spectra features in combination of the calibration by the synchrotron radiation X-ray diffraction(XRD).Compared with the time-consuming electrochemical method,the rapid,sensitive and non-destructive features of Raman spectroscopy have made it a promising candidate for determining the purity of TiO_(2)(B).Further,the correlations developed in this work should be instructive in synthesizing pure TiO_(2)(B)and furthermore optimizing its electrochemical charge storage properties.展开更多
Modifying effect and mechanism of trace rare earth on Fe(Si) rich impurity phases in commercial purity aluminum were studied with the aids of SEM, EDAX, TEM, etc. It is found that Ce rich mixed rare earth (RE) is an...Modifying effect and mechanism of trace rare earth on Fe(Si) rich impurity phases in commercial purity aluminum were studied with the aids of SEM, EDAX, TEM, etc. It is found that Ce rich mixed rare earth (RE) is an effective modifying agent, which makes the coarse Fe rich impurity phases transform into complex compounds of tiny, sphere/short stick form, thus improving mechanical properties of this material; its modifying mechanism is in that RE gathering in front of solid/liquid interface enters into the impurity phases, forming complex (AlFeSiRE) compounds; or is adsorbed in the impurity phases surface, impeding the growth of impurity phases; however, excessive RE will result in the increasing of RE compounds (secondary phases), and plasticity reduction of this material. Therefore, its addition amount should be less than 0 07% (mass fraction).展开更多
High purity silicon carbide (SIC) powder was synthesized in-situ by chemical reaction between silicon and carbon powder. In order to ensure that the impurity concentration of the resulting SiC powder is suitable for...High purity silicon carbide (SIC) powder was synthesized in-situ by chemical reaction between silicon and carbon powder. In order to ensure that the impurity concentration of the resulting SiC powder is suitable for high-resistivity SiC single crystal growth, the preparation technology of SiC powder is different from that of SiC ceramic. The influence of the shape and size of carbon particles on the morphology and phase composition of the obtained SiC powder were discussed. The phase composition and morphology of the products were investigated by X-ray diffraction, Raman microspectroscopy and scanning electron microscopy. The results show that the composition of resulting SiC by in-situ synthesis from Si/C mixture strongly depends on the nature of the carbon source, which corresponds to the particle size and shape, as well as the preparation temperature. In the experimental conditions, flake graphite is more suitable for the synthesis of SiC powder than activated carbon because of its relatively smaller particle size and flake shape, which make the conversion more complete. The major phase composition of the full conversion products is β-SiC, with traces of α-SiC. Glow discharge mass spectroscopy measurements indicated that SiC powder synthesized with this chemical reaction method can meet the purity demand for the growth of high-resistivity SiC single crystals.展开更多
A An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of 24 elements (Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, ...A An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of 24 elements (Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn Sb, Ba, Pt, Au, and Pb) in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCI. The matrix effects because of the presence of excess HCI and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits were 0.016-1.50 ].tg·g^-1, the recovery ratios were 92.2%-111.2%, and the RSD was less than 3.6%. The method was accurate, quick, and convenient. It was applied to the determination of trace impurities in high purity cobalt with satisfactory results.展开更多
Five super hybrid rice combinations, i.e. HYS-1/R105, Pei'ai 64S/E32, Liangyoupeijiu (Pei'ai 64S/9311), 88S/0293, and J23A/Q611, and their parental lines were tested by means of SSR analysis. A total of 144 SS...Five super hybrid rice combinations, i.e. HYS-1/R105, Pei'ai 64S/E32, Liangyoupeijiu (Pei'ai 64S/9311), 88S/0293, and J23A/Q611, and their parental lines were tested by means of SSR analysis. A total of 144 SSR primer pairs distributed on 12 rice chromosomes were used, out of which 47 detected polymorphism among the tested rice lines. Among all these primers, RM337 and RM154 produced polymorphic patterns in four or more of the tested experimental materials respectively, and they could distinguish among most rice genotypes tested. Twenty-four primer pairs, two on each rice chromosome, were selected to make a reference SSR marker-based fingerprinting for the rice lines. For most of the primer pairs, F1 hybrids mainly showed complementary pattern of both parents, which could be very useful to distinguish the F1 from its parental lines. In addition, 5 primer pairs were selected as special primer pairs for five hybrid rice combinations respectively. By combining the rapid, simple method on DNA extraction, it is suggested that SSR technique has wide prospective in variety authentication and purity identification.展开更多
TiClx (x=2.17) was prepared by using titanium sponge to reduce the concentration of TiCl4 in a NaCl-KCl melt under negative pressure. The as-prepared NaCl-KCl-TiClx melt was employed as the electrolyte, and two para...TiClx (x=2.17) was prepared by using titanium sponge to reduce the concentration of TiCl4 in a NaCl-KCl melt under negative pressure. The as-prepared NaCl-KCl-TiClx melt was employed as the electrolyte, and two parallel crude titanium plates and one high-purity titanium plate were used as the anode and cathode, respectively. A series of electrochemical tests were performed to investigate the influence of electrolytic parameters on the current efficiency and quality of cathodic products. The results indicated that the quality of cathodic products was related to the current efficiency, which is significantly dependent on the current density and the initial concentration of titanium ions. The significance of this study is the attainment of high-purity titanium with a low oxygen content of 30× 10^-6.展开更多
Using SEM and EDS some particles containing La and P were discovered in low oxygen and sulfur purity steel with lanthanum. In these particles low melting point elements such as As and Sb also were detected. According ...Using SEM and EDS some particles containing La and P were discovered in low oxygen and sulfur purity steel with lanthanum. In these particles low melting point elements such as As and Sb also were detected. According to the result of simulative calculation of segregation, it is shown that La and P enrich so strongly in the process of solidification that their concentrations can satisfy thermodynamic condition to forme LaP compound or meet the requirements to forme eutectic phase in the last stage of solidification. Therefore, the particles are concluded as LaP compound or eutectics, which exist on grain boundary mainly.展开更多
An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, ...An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, Sb, Ba, Pt, Au and Pb in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCl. The matrix effects due to the presence of excess HCl and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination was tested and discussed. Correction for matrix effects, Sc, Rh and Bi were used as internal standards. The detection limits is 0.003-0.57 μg/g, the recovery ratio is 92.2%-111.2%, and the RSD is less than 3.6%. The method is accurate, quick and convenient. It has been applied to the determination of trace impurities in high purity cobalt with satisfactory results.展开更多
High purity anatase nano-TiO2 powders with high photocatalytic activity were prepared by a hydrothermal synthesis method. X-ray diffraction (XRD), field emission transmission electron microscopy (FETEM), ultraviol...High purity anatase nano-TiO2 powders with high photocatalytic activity were prepared by a hydrothermal synthesis method. X-ray diffraction (XRD), field emission transmission electron microscopy (FETEM), ultraviolet-visible (UV-Vis) light absorption spectrum and photoluminescence (PL) spectrum were adopted to characterize the catalyst. Effects of temperature, time and sol concentration of hydrothermal synthesis on particle size and phases were investigated. Photocatalytic activities in the degradation of Rhodamine B Dye were studied. The experimental results indicated that photocatalytic activity of the nano-TiO2 powers was much higher than that of P25 (Degussa).展开更多
This article describes a new method for the simultaneous determination of trace rare earth elements (REEs) and non rare earth elements (NREEs) in high purity terbium oxide by ICP-AES after HPLC separation using P507 r...This article describes a new method for the simultaneous determination of trace rare earth elements (REEs) and non rare earth elements (NREEs) in high purity terbium oxide by ICP-AES after HPLC separation using P507 resin. The chromatographic separation of the analytes from the matrix using dilute nitric acid as mobile phase was studied. The experimental results showed that a favorable separation of trace metals (Cu and Gd) from the matrix (Tb) can easily be achieved by elution with dilute nitric acid within 25 min. The proposed method was applied to the determination of trace metals (Ca, Cu, Mg, Mn, Ni, Si, La, Ce, Pr, Nd, Sm, Eu and Gd) in high purity terbium oxide. The detection limits (DLs) for the analytes ranged from 0.4-4.0 μg\5g -1, and the recoveries are from 78%-105%.展开更多
The effects of two types of magnetic fields,namely harmonic magnetic field(HMF)and pulse magnetic field(PMF)on magnetic flux density,Lorentz force,temperature field,and microstructure of high purity Cu were studied by...The effects of two types of magnetic fields,namely harmonic magnetic field(HMF)and pulse magnetic field(PMF)on magnetic flux density,Lorentz force,temperature field,and microstructure of high purity Cu were studied by numerical simulation and experiment during electromagnetic direct chill casting.The magnetic field is induced by a magnetic generation system including an electromagnetic control system and a cylindrical crystallizer of 300 mm in diameter equipped with excitation coils.A comprehensive mathematical model for high purity Cu electromagnetic casting was established in finite element method.The distributions of magnetic flux density and Lorentz force generated by the two magnetic fields were acquired by simulation and experimental measurement.The microstructure of billets produced by HMF and PMF casting was compared.Results show that the magnetic flux density and penetrability of PMF are significantly higher than those of HMF,due to its faster variation in transient current and higher peak value of magnetic flux density.In addition,PMF drives a stronger Lorentz force and deeper penetration depth than HMF does,because HMF creates higher eddy current and reverse electromagnetic field which weakens the original electromagnetic field.The microstructure of a billet by HMF is composed of columnar structure regions and central fine grain regions.By contrast,the billet by PMF has a uniform microstructure which is characterized by ultra-refined and uniform grains because PMF drives a strong dual convection,which increases the uniformity of the temperature field,enhances the impact of the liquid flow on the edge of the liquid pool and reduces the curvature radius of liquid pool.Eventually,PMF shows a good prospect for industrialization.展开更多
The determination of trace impurities in high purity zinc oxide by high resolution inductively coupled plasma mass spectrometry ( HR-ICP-MS ) was investigated. To overcome some poteutially problematic spectral iuter...The determination of trace impurities in high purity zinc oxide by high resolution inductively coupled plasma mass spectrometry ( HR-ICP-MS ) was investigated. To overcome some poteutially problematic spectral iuterference, measurements were acquired in both middle and high resolution modes. The matrix effects due to the presence of excess HCl and zinc were evaluated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits ranged from 0.02μg/ g to 6 μg/ g depending on the elements. The experimental resalts for the determination of Na, Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Mo, Cd, Sb and Pb in several high purity zinc oxide powders were presented.展开更多
Betulin(BE)can be obtained from many plants,such as those belonging Betulaceae family,and pharmacological investigations showed its notable biological properties and good potential for food and pharmaceutical developm...Betulin(BE)can be obtained from many plants,such as those belonging Betulaceae family,and pharmacological investigations showed its notable biological properties and good potential for food and pharmaceutical development.We investigated the homogeneity,stability,purity,and uncertainty of a newly certified reference material(CRM)of BE.The certified purity value for the CRM of BE was 99.56%with an extended uncertainty of 0.07%(k=2,P=0.95),as determined by differential scanning calorimetry(DSC).In this study,DSC was used for the first time for purity determination of BE.Given its high accuracy,precision,and reproducibility,DSC can be used as an alternative technique for purity determination of CRMs in the pharmaceutical and food industry.展开更多
Determination of trace rare earth elements(REEs)in 99. 999% purity yttrium oxide using the inductively coupled plasma mass spectrometric technique (ICPMS) has been developed. Instrumental parameters and factors affeci...Determination of trace rare earth elements(REEs)in 99. 999% purity yttrium oxide using the inductively coupled plasma mass spectrometric technique (ICPMS) has been developed. Instrumental parameters and factors affecitng analytical results have been studied and then optimized.Samples are analyzed directly following an acid digestion without separation or preconcentration and with limit of detection of 0. 003~0. 02 ng/ml, precision of ±5. 4%(cofficient of variation)and recovery of 90~115%. Correction for isobaric interferences from oxide ions and hydroxide ions is made mathematically. Special internal standard procedures are used to compensate drift in metal:metal oxide ratios and sensitivity. The analytical results of several samples are accurate as compared with inductively coupled plasma atomic emission spectrometry (ICPAES) and spark source mass spectrometry (SSMS).展开更多
Purification is a primary application of zone melting, in which the improvement of efficiency, production yield and minimum achievable impurity level are always the research focus due to the increasing demand for high...Purification is a primary application of zone melting, in which the improvement of efficiency, production yield and minimum achievable impurity level are always the research focus due to the increasing demand for high purity metals. This paper has systematically outlined the whole development of related research on zone refining of metals including basic theories, variants of zone refining, parametric optimization, numerical models, and high purity analytical methods. The collection of this information could be of good value to improve the refining efficiency and the production of high purity metals by zone refining.展开更多
Inorganic perovskites(Cs Pb X3(X=I,Br,Cl))have broad prospection in the field of high-definition displaying due to its excellent optoelectronic characteristics.The vacuum deposition process possesses advantages and co...Inorganic perovskites(Cs Pb X3(X=I,Br,Cl))have broad prospection in the field of high-definition displaying due to its excellent optoelectronic characteristics.The vacuum deposition process possesses advantages and competitiveness in the industrialized production.However,the performance of light emitting diodes(LEDs)based on vacuum-deposited is incredibly low.Herein,we proposed a heating-assisted vacuum deposition(HAVD)method to construct inorganic perovskite LEDs(Pe LEDs)with enhanced performance.The roughness and crystallinity of perovskite film were improved by regulating the heating treatment of substrates.And the perovskite film exhibited largely rise in luminescence,with decreasing defect density.Consequently,with the optimized temperature,the green Pe LEDs exhibited 100-fold improvement of external quantum efficiency(EQE)with the luminance of up to 11941 cd/m2,and the full width at half-maximum(FWHM)of the electroluminescence(EL)spectra was decreased from 25 to 17 nm.At the same time,the red and blue Pe LEDs also exhibited obvious enhancement in EQE and luminance by HAVD method,and both the FWHM of EL spectra dropped below 20 nm,exhibiting excellent high color purity.HAVD strategy has a huge potential to be a new commonly used method for low-cost fabrication of displays and lighting.展开更多
基金supported by grants from the PetroChina-CUP Major Strategic Cooperation Projects(ZLZX2020010805,ZLZX2020020405)National Natural Science Foundation of China(41373086)+3 种基金National Science and Technology Major Project(No.2016ZX05050011,2016ZX05040002)Beijing Nova Program and Leading Talent Culturing Cooperative Projects(No.Z161100004916033)Beijing Higher Education Young Elite Teacher Project(No.YETP0670)Outstanding Young Excellent Teachers Foundation of China University of Petroleum(Beijing)(KYJJ2012-01-10).
文摘DNA analysis is the core of biotechnology applied in petroleum resources and engineering. Traditionally accurate determination of DNA purity and concentration by spectrometer is the first and critical step for downstream molecular biology research. In this study, three different spectrophotometry methods, BPM, NDTT and NPMTTZ were compared for their performance in determining DNA concentration and purity in 32 oil samples, and molecule methods like quantitative real-time PCR (qPCR) and high-throughput sequence were also performed to help assess the accuracy of the three methods in determining DNA concentration and purity. For ordinary heavy oil (OHO), extra heavy oil (EHO) and super heavy oil (SHO), the characteristics of high viscosity (η), density (ρ) and resin plus asphaltene content will affect the DNA extraction and UV determination. The DNA concentration was decreased as density increased: OHO (11.46 ± 18.34 ng/μL), EHO (6.68 ± 9.67 ng/μL) and SHO (6.20 ± 7.83 ng/μL), and the DNA purity was on the reverse: OHO (1.31 ± 0.27), EHO (1.54 ± 0.20), and SHO (1.83 ± 0.32). The results suggest that spectrophotometry such as BPM and NPMTTZ are qualitatively favorite methods as the quick non-consumable methods in determining DNA concentration and purity of medium oil and heavy oil.
基金the main research program of the Korea Institute of Materials Science(Grant No.PNK8150)for financially supporting this study
文摘In this study,the effects of Al addition on the corrosion behavior of pure Mg with controlled impurity contents were systematically analyzed according to the processing history.The results revealed that the corrosion behavior of high-purity Mg-Al alloys is strongly related to changes in the microstructure,including theβphase and Al-Mn or Al-Fe phases,and the protectiveness of the surface film according to the Al content and processing history.In the as-cast alloys,the corrosion rate increased due to the increase ofβphase as the Al content increased,but in the as-extruded alloys,the corrosion rate,which was high due to intermetallic compounds caused by impurities in the low Al alloy,decreased as the Al content increased,and then increased again.This is due to the combined effect of the increase of theβphase and decrease of the impurity effect,and the increase of the dissolved Al content.The results suggest that it is necessary to analyze the effect of alloying elements on the corrosion behavior of pure Mg with information concerning the impurity content and processing history.
基金Project supported by the National Natural Science Foundation of China(Grant No.12175001)the Natural Science Research Key Project of the Education Department of Anhui Province of China(Grant No.KJ2021A0943)+3 种基金the Research Start-up Funding Project of High Level Talent of West Anhui University(Grant No.WGKQ2021048)an Open Project of the Key Laboratory of Functional Materials and Devices for Informatics of Anhui Higher Education Institutes(Grant No.FMDI202106)the University Synergy Innovation Program of Anhui Province(Grant No.GXXT-2021-026)the Anhui Provincial Natural Science Foundation(Grant Nos.2108085MA18 and 2008085MA20)。
文摘A quantum steering ellipsoid(QSE)is a visual characterization for bipartite qubit systems,and it is also a novel avenue for describing and detecting quantum correlations.Herein,by using a QSE,we visualize and witness the first-order coherence(FOC),Bell nonlocality(BN)and purity under non-inertial frames.Also,the collective influences of the depolarizing channel and the non-coherence-generating channel(NCGC)on the FOC,BN and purity are investigated in the QSE formalism.The results reveal that the distance from the center of the QSE to the center of the Bloch sphere visualizes the FOC of a bipartite system,the lengths of the QSE semiaxis visualize the BN,and the QSE's shape and position dominate the purity of the system.One can capture the FOC,BN and purity via the shape and position of the QSE in the non-inertial frame.The depolarizing channel(the NCGC)gives rise to the shrinking and degradation(the periodical oscillation)of the QSE.One can use these traits to visually characterize and detect the FOC,BN and purity under the influence of external noise.Of particular note is that the condition for the QSE to achieve the center of the Bloch sphere cannot be influenced by the depolarizing channel and the NCGC.The characterization shows that the conditions for the disappearance of the FOC are invariant under the additional influences of the depolarizing channel and NCGC.
基金This work was financially supported by the National Natural Science Foundation of China(22075074)Outstanding Young Scientists Research Funds from Hunan Province(2020JJ2004)+3 种基金Major Science and Technology Program of Hunan Province(2020WK2013)Natural Science Foundation of Hunan Province(2020JJ5035)National Natural Science Foundation of China(Grant No.11704185)the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure(SKL201802SIC).
文摘Bronze phase titanium dioxide(TiO_(2)(B))could be a promising high-power anode for lithium ion battery.However,TiO_(2)(B)is a metastable material,so the as-synthesized samples are inevitably accompanied by the existence of anatase phases.It has been found that the TiO_(2)(B)'s purity is positively correlated with its electrochemical performance.Herein,we have established an accurate quantification of the TiO_(2)(B)/anatase ratio,by figuring out the function between the purity of TiO_(2)(B)phase in the high purity range and its Raman spectra features in combination of the calibration by the synchrotron radiation X-ray diffraction(XRD).Compared with the time-consuming electrochemical method,the rapid,sensitive and non-destructive features of Raman spectroscopy have made it a promising candidate for determining the purity of TiO_(2)(B).Further,the correlations developed in this work should be instructive in synthesizing pure TiO_(2)(B)and furthermore optimizing its electrochemical charge storage properties.
文摘Modifying effect and mechanism of trace rare earth on Fe(Si) rich impurity phases in commercial purity aluminum were studied with the aids of SEM, EDAX, TEM, etc. It is found that Ce rich mixed rare earth (RE) is an effective modifying agent, which makes the coarse Fe rich impurity phases transform into complex compounds of tiny, sphere/short stick form, thus improving mechanical properties of this material; its modifying mechanism is in that RE gathering in front of solid/liquid interface enters into the impurity phases, forming complex (AlFeSiRE) compounds; or is adsorbed in the impurity phases surface, impeding the growth of impurity phases; however, excessive RE will result in the increasing of RE compounds (secondary phases), and plasticity reduction of this material. Therefore, its addition amount should be less than 0 07% (mass fraction).
文摘High purity silicon carbide (SIC) powder was synthesized in-situ by chemical reaction between silicon and carbon powder. In order to ensure that the impurity concentration of the resulting SiC powder is suitable for high-resistivity SiC single crystal growth, the preparation technology of SiC powder is different from that of SiC ceramic. The influence of the shape and size of carbon particles on the morphology and phase composition of the obtained SiC powder were discussed. The phase composition and morphology of the products were investigated by X-ray diffraction, Raman microspectroscopy and scanning electron microscopy. The results show that the composition of resulting SiC by in-situ synthesis from Si/C mixture strongly depends on the nature of the carbon source, which corresponds to the particle size and shape, as well as the preparation temperature. In the experimental conditions, flake graphite is more suitable for the synthesis of SiC powder than activated carbon because of its relatively smaller particle size and flake shape, which make the conversion more complete. The major phase composition of the full conversion products is β-SiC, with traces of α-SiC. Glow discharge mass spectroscopy measurements indicated that SiC powder synthesized with this chemical reaction method can meet the purity demand for the growth of high-resistivity SiC single crystals.
基金the Natural Science Foundation of Hunan Province, China (No. 05JJ40017).
文摘A An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of 24 elements (Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn Sb, Ba, Pt, Au, and Pb) in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCI. The matrix effects because of the presence of excess HCI and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits were 0.016-1.50 ].tg·g^-1, the recovery ratios were 92.2%-111.2%, and the RSD was less than 3.6%. The method was accurate, quick, and convenient. It was applied to the determination of trace impurities in high purity cobalt with satisfactory results.
文摘Five super hybrid rice combinations, i.e. HYS-1/R105, Pei'ai 64S/E32, Liangyoupeijiu (Pei'ai 64S/9311), 88S/0293, and J23A/Q611, and their parental lines were tested by means of SSR analysis. A total of 144 SSR primer pairs distributed on 12 rice chromosomes were used, out of which 47 detected polymorphism among the tested rice lines. Among all these primers, RM337 and RM154 produced polymorphic patterns in four or more of the tested experimental materials respectively, and they could distinguish among most rice genotypes tested. Twenty-four primer pairs, two on each rice chromosome, were selected to make a reference SSR marker-based fingerprinting for the rice lines. For most of the primer pairs, F1 hybrids mainly showed complementary pattern of both parents, which could be very useful to distinguish the F1 from its parental lines. In addition, 5 primer pairs were selected as special primer pairs for five hybrid rice combinations respectively. By combining the rapid, simple method on DNA extraction, it is suggested that SSR technique has wide prospective in variety authentication and purity identification.
基金the National Science Foundation of China(Nos.50934001 and 51322402)the National High-Tech Research and Development Program of China (No.2012AA062302)+2 种基金the Program of the Co-construction with Beijing Municipal Commission of Education of China (Nos.00012047 and 00012085)the Program for New Century Excellent Talents in Universities(NCET-11-0577)the Fundamental Research Funds for the Central Universities(No.FRF-AS-11-003A)
文摘TiClx (x=2.17) was prepared by using titanium sponge to reduce the concentration of TiCl4 in a NaCl-KCl melt under negative pressure. The as-prepared NaCl-KCl-TiClx melt was employed as the electrolyte, and two parallel crude titanium plates and one high-purity titanium plate were used as the anode and cathode, respectively. A series of electrochemical tests were performed to investigate the influence of electrolytic parameters on the current efficiency and quality of cathodic products. The results indicated that the quality of cathodic products was related to the current efficiency, which is significantly dependent on the current density and the initial concentration of titanium ions. The significance of this study is the attainment of high-purity titanium with a low oxygen content of 30× 10^-6.
基金Project supported by the Ministry of Science and Technology of China (2002BA315A-5)
文摘Using SEM and EDS some particles containing La and P were discovered in low oxygen and sulfur purity steel with lanthanum. In these particles low melting point elements such as As and Sb also were detected. According to the result of simulative calculation of segregation, it is shown that La and P enrich so strongly in the process of solidification that their concentrations can satisfy thermodynamic condition to forme LaP compound or meet the requirements to forme eutectic phase in the last stage of solidification. Therefore, the particles are concluded as LaP compound or eutectics, which exist on grain boundary mainly.
基金supported by the Natural Science Foundation of Hunan Province(No.05JJ40017)Education Department of Hunan Province(No.05B064).
文摘An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, Sb, Ba, Pt, Au and Pb in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCl. The matrix effects due to the presence of excess HCl and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination was tested and discussed. Correction for matrix effects, Sc, Rh and Bi were used as internal standards. The detection limits is 0.003-0.57 μg/g, the recovery ratio is 92.2%-111.2%, and the RSD is less than 3.6%. The method is accurate, quick and convenient. It has been applied to the determination of trace impurities in high purity cobalt with satisfactory results.
基金Funded by the Academic Leader Program of Wuhan City(201150530146)the Foundamental Research Funds for the Central Universities(2010-11-020)
文摘High purity anatase nano-TiO2 powders with high photocatalytic activity were prepared by a hydrothermal synthesis method. X-ray diffraction (XRD), field emission transmission electron microscopy (FETEM), ultraviolet-visible (UV-Vis) light absorption spectrum and photoluminescence (PL) spectrum were adopted to characterize the catalyst. Effects of temperature, time and sol concentration of hydrothermal synthesis on particle size and phases were investigated. Photocatalytic activities in the degradation of Rhodamine B Dye were studied. The experimental results indicated that photocatalytic activity of the nano-TiO2 powers was much higher than that of P25 (Degussa).
基金SupportedbytheNationalScienceFoundationofChina (No .2 0 0 0 70 10 10 8)andWuhanMunicipalScience&TechnologyCommission (No .995 0 0 40 80 )
文摘This article describes a new method for the simultaneous determination of trace rare earth elements (REEs) and non rare earth elements (NREEs) in high purity terbium oxide by ICP-AES after HPLC separation using P507 resin. The chromatographic separation of the analytes from the matrix using dilute nitric acid as mobile phase was studied. The experimental results showed that a favorable separation of trace metals (Cu and Gd) from the matrix (Tb) can easily be achieved by elution with dilute nitric acid within 25 min. The proposed method was applied to the determination of trace metals (Ca, Cu, Mg, Mn, Ni, Si, La, Ce, Pr, Nd, Sm, Eu and Gd) in high purity terbium oxide. The detection limits (DLs) for the analytes ranged from 0.4-4.0 μg\5g -1, and the recoveries are from 78%-105%.
基金financially supported by the National Key Research and Development Program of China(Grant No.2017YFB0305504)。
文摘The effects of two types of magnetic fields,namely harmonic magnetic field(HMF)and pulse magnetic field(PMF)on magnetic flux density,Lorentz force,temperature field,and microstructure of high purity Cu were studied by numerical simulation and experiment during electromagnetic direct chill casting.The magnetic field is induced by a magnetic generation system including an electromagnetic control system and a cylindrical crystallizer of 300 mm in diameter equipped with excitation coils.A comprehensive mathematical model for high purity Cu electromagnetic casting was established in finite element method.The distributions of magnetic flux density and Lorentz force generated by the two magnetic fields were acquired by simulation and experimental measurement.The microstructure of billets produced by HMF and PMF casting was compared.Results show that the magnetic flux density and penetrability of PMF are significantly higher than those of HMF,due to its faster variation in transient current and higher peak value of magnetic flux density.In addition,PMF drives a stronger Lorentz force and deeper penetration depth than HMF does,because HMF creates higher eddy current and reverse electromagnetic field which weakens the original electromagnetic field.The microstructure of a billet by HMF is composed of columnar structure regions and central fine grain regions.By contrast,the billet by PMF has a uniform microstructure which is characterized by ultra-refined and uniform grains because PMF drives a strong dual convection,which increases the uniformity of the temperature field,enhances the impact of the liquid flow on the edge of the liquid pool and reduces the curvature radius of liquid pool.Eventually,PMF shows a good prospect for industrialization.
文摘The determination of trace impurities in high purity zinc oxide by high resolution inductively coupled plasma mass spectrometry ( HR-ICP-MS ) was investigated. To overcome some poteutially problematic spectral iuterference, measurements were acquired in both middle and high resolution modes. The matrix effects due to the presence of excess HCl and zinc were evaluated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits ranged from 0.02μg/ g to 6 μg/ g depending on the elements. The experimental resalts for the determination of Na, Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Mo, Cd, Sb and Pb in several high purity zinc oxide powders were presented.
基金supported by National Key R&D Program of China(Grant No.2016YFC1000900)National Science and Technology Major Project of China(Grant Nos.2017ZX09101001003,2018ZX09711001-003-022,2018ZX09711001-010)+1 种基金National Natural Science Foundation of China(NSFC)(Grant No.81703473)CAMS Innovation Fund for Medical Sciences(Grant No.2017-I2M-3-010).
文摘Betulin(BE)can be obtained from many plants,such as those belonging Betulaceae family,and pharmacological investigations showed its notable biological properties and good potential for food and pharmaceutical development.We investigated the homogeneity,stability,purity,and uncertainty of a newly certified reference material(CRM)of BE.The certified purity value for the CRM of BE was 99.56%with an extended uncertainty of 0.07%(k=2,P=0.95),as determined by differential scanning calorimetry(DSC).In this study,DSC was used for the first time for purity determination of BE.Given its high accuracy,precision,and reproducibility,DSC can be used as an alternative technique for purity determination of CRMs in the pharmaceutical and food industry.
文摘Determination of trace rare earth elements(REEs)in 99. 999% purity yttrium oxide using the inductively coupled plasma mass spectrometric technique (ICPMS) has been developed. Instrumental parameters and factors affecitng analytical results have been studied and then optimized.Samples are analyzed directly following an acid digestion without separation or preconcentration and with limit of detection of 0. 003~0. 02 ng/ml, precision of ±5. 4%(cofficient of variation)and recovery of 90~115%. Correction for isobaric interferences from oxide ions and hydroxide ions is made mathematically. Special internal standard procedures are used to compensate drift in metal:metal oxide ratios and sensitivity. The analytical results of several samples are accurate as compared with inductively coupled plasma atomic emission spectrometry (ICPAES) and spark source mass spectrometry (SSMS).
文摘Purification is a primary application of zone melting, in which the improvement of efficiency, production yield and minimum achievable impurity level are always the research focus due to the increasing demand for high purity metals. This paper has systematically outlined the whole development of related research on zone refining of metals including basic theories, variants of zone refining, parametric optimization, numerical models, and high purity analytical methods. The collection of this information could be of good value to improve the refining efficiency and the production of high purity metals by zone refining.
基金financially supported by NSFC(51922049,61604074)the National Key Research and Development Program of China(2016YFB0401701)+1 种基金the Natural Science Foundation of Jiangsu Province(BK20180020)PAPD of Jiangsu Higher Education Institutions.
文摘Inorganic perovskites(Cs Pb X3(X=I,Br,Cl))have broad prospection in the field of high-definition displaying due to its excellent optoelectronic characteristics.The vacuum deposition process possesses advantages and competitiveness in the industrialized production.However,the performance of light emitting diodes(LEDs)based on vacuum-deposited is incredibly low.Herein,we proposed a heating-assisted vacuum deposition(HAVD)method to construct inorganic perovskite LEDs(Pe LEDs)with enhanced performance.The roughness and crystallinity of perovskite film were improved by regulating the heating treatment of substrates.And the perovskite film exhibited largely rise in luminescence,with decreasing defect density.Consequently,with the optimized temperature,the green Pe LEDs exhibited 100-fold improvement of external quantum efficiency(EQE)with the luminance of up to 11941 cd/m2,and the full width at half-maximum(FWHM)of the electroluminescence(EL)spectra was decreased from 25 to 17 nm.At the same time,the red and blue Pe LEDs also exhibited obvious enhancement in EQE and luminance by HAVD method,and both the FWHM of EL spectra dropped below 20 nm,exhibiting excellent high color purity.HAVD strategy has a huge potential to be a new commonly used method for low-cost fabrication of displays and lighting.